The magnetism of micro-sized hematite explained

Physics of the Earth and Planetary Interiors

Volumn 183, Issue 3-4, 2010, Pages 387-397

  Liu, Qingsong ^a   Barrón, Vidal ^b   Torrent, José ^b   Qin, Huafeng ^a   Yu, Yongjae ^c  

^a INSTITUTE OF GEOLOGY AND GEOPHYSICS   (China)

^b UNIVERSITY OF CÓRDOBA   (Spain)

^c Chungnam National University   (South Korea)

Author keywords

Coercivity; Hematite; Magnetism; Morin transition; Morphology

Indexed keywords

COERCIVITIES; FIRST-ORDER REVERSAL CURVES; LOW TEMPERATURES; MAGNETIC ANALYSIS; MAGNETIC COERCIVITIES; MAGNETOCRYSTALLINE; MAGNETOELASTIC ANISOTROPY; MORIN TRANSITIONS; NATURAL ENVIRONMENTS; PSEUDOCUBIC; SHAPE FACTOR; SYNTHETIC HEMATITE; VACANCY CONTENT;

ABSORPTION SPECTROSCOPY; COERCIVE FORCE; IRON ORES; MAGNETISM; MAGNETOCRYSTALLINE ANISOTROPY; MORPHOLOGY; THERMOGRAVIMETRIC ANALYSIS; VACANCIES; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

HEMATITE;

GEOMAGNETISM; HEMATITE; HYDROXYL RADICAL; INFRARED SPECTROSCOPY; LOW TEMPERATURE; MAGNETIC ANISOTROPY; MAGNETIC PROPERTY; ROCK MICROSTRUCTURE; THERMOGRAVIMETRY; X-RAY DIFFRACTION;

EID: 78649690537     PISSN: 00319201     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.pepi.2010.08.008     Document Type: Article

References (58)

1. 3. J. Phys. C: Solid State Phys. 1988, 21:2229. 10.1088/0022-3719/21/11/014.
2. Baldridge A.M., Calvin W.M. Hydration state of the Martian coarse-grained hematite exposures: implications for their origin and evolution. J. Geophys. Res. 2004, 109:E04S90. 10.1029/2003JE002066.
3. 3 fine particles. J. Phys. Soc. Jpn. 1965, 20:2086.
4. Banerjee S.K. New grain size limits for paleomagnetic stability in hematite. Nat. Phys. Sci. 1971, 232:15-16.
5. Barrón V., Rendón J.L., Torrent J., Serna C.J. Relation of infrared, crystallochemical, and morphological properties of Al-substituted hematites. Clay Clay Miner. 1984, 32:475-479.
6. Barrón V., Herruzo M., Torrent J. Phosphate adsorption by aluminous hematites of different shapes. Soil. Soc. Am. J. 1988, 52:647-651.
7. Catling D.C., Moore J.M. The nature of coarse-grained crystalline hematite and its implications for the early environment of Mars. Icarus 2003, 165:277-300.
8. Chevallier R., Mathieu S. Proprietes magnetiques des poudres hematite-influence des dimensions des grains. Ann. Phys. 1943, 18:258-288.
9. Dankers P.H.M. Relationship between the median destructive field and remanence coercivity forces for dispersed magnetite, titanomagnetite and hematite. Geophys. J. Roy. Astron. Soc. 1981, 64:447-461.
10. de Boer C.B., Mullender T.A.T., Dekkers M.J. Low-temperature behaviour of haematite: susceptibility and magnetization increase on cycling through the Morin transition. Geophys. J. Int. 2001, 146:201-216.
11. de Boer C.B., Dekkers M.J. Thermomagnetic behaviour of hematite and goethite as a function of grain size in various nonsaturating magnetic fields. Geophys. J. Int. 1998, 133:541-552.
12. de Grave E., Bowen L.H., Weed S.B. Mössbauer study of aluminum-substituted hematites. J. Magn. Magn. Mater. 1982, 27:98-108.
13. de Grave E., Chamebaere D.G., Bowen L.H. Nature of the Morin transition in Al-substituted hematite. J. Magn. Magn. Mater. 1983, 30:349-354.
14. Dekkers, M.J., 1988. Some rockmagnetic parameters for natural goethite, pyrrhotite and fine-grained hematite. (PhD Thesis, University of Utrecht). Geologica Ultraiectina, 51, 231 pp.
15. Dekkers M.J., Linssen J.H. Rock magnetic properties of fine-grained natural low-temperature hematite with reference to remanence acquisition mechanisms in red beds. Geophys. J. Int. 1989, 99:1-18.
16. Dunlop D.J., Argyle K.S. Thermoremanence, anhysteretic remanence and susceptibility of submicron magnetites: nonlinear field dependence and variation with grain size. J. Geophys. Res. 1997, 102:20199-20210.
17. Dunlop D.J., Kletetschka G. Multidomain hematite: a source of planetary magnetic anomalies?. Geophys. Res. Lett. 2001, 28:3345-3348.
18. Dunlop D.J., Özdemir Ö. Rock Magnetism: Fundamentals and Frontiers 1997, Cambridge Press, p. 573.
19. Flanders P.J., Remeika J.P. Magnetic properties of hematite single crystals. Philos. Mag. 1965, 11:1271-1288.
20. Flanders P.J., Schuele W.J. Temperature dependent magnetic properties of hematite single crystals. Proc. Int. Conf. Magnetism, Nottingham 1964, pp. 594-596.
21. Hamada S., Matijević E. Formation of monodispersed colloidal pseudocubic haematite particles in ethanol+water solutions. J. Chem. Soc. Faraday Trans. 1982, 1:2147-2156.
22. Heider F., Dunlop D.J., Sugiura N. Magnetic properties of hydrothermally re-crystallized magnetite crystals. Science 1987, 236:1287-1290.
23. Iglesias J.E., Serna C.J. The IR spectra of hematite-type compounds with different particle shapes. Miner. Petrogr. Acta 1985, 29:363-370.
24. Kletetschka G., Wasilewski P.J. Grain size limit for SD hematite. Phys. Earth Planet. Inter. 2002, 129:173-179.
25. Kletetschka G., Wasilewski P.J., Taylor P.T. Hematite versus magnetite as the signature for planetary magnetic anomalies. Phys. Earth Planet. Inter. 2000, 119:259-267.
26. Kraus W., Nolze G. POWDER CELL (a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns). J. Appl. Crystallogr. 1996, 29:301-303.
27. Larrasoaña J.C., Roberts A.P., Rohling E.J., Winklhofer M., Wehausen R. Three million years of monsoon variability over the northern Sahara. Clim. Dyn. 2003, 21:689-698.
28. Larrasoaña J.C., Roberts A.P., Hayes A., Wehausen R., Rohling E.J. Detecting missing beats in the Mediterranean climate rhythm from magnetic identification of oxidized sapropels (Ocean Drilling Program Leg 160). Phys. Earth Planet. Inter. 2006, 156:283-293.
29. Liu Q.S., Roberts A.P., Torrent J., Horng C.-S., Larrasoaña J.C. What do the HIRM and S-ratio really measure in environmental magnetism?. Geochem. Geophys. Geosys. 2007, 8:Q09011. 10.1029/2007GC001717.
30. 2. Nature 2001, 411:176-180.
31. 3. J. Magn. Magn. Mater. 2009, 321:2925-2931.
32. 3 with added titanium. Phys. Rev. 1950, 78:819-820.
33. Morish A.H. Canted Antiferromagnetism: Hematite 1994, World Scientific, Singapore.
34. 3 particles. Phys. State Solid (a) 1985, 92:187-192.
35. Özdemir Ö., Dunlop D.J. Magnetic memory and coupling between spin-canted and defect magnetism in hematite. J. Geophys. Res. 2006, 111:B12S03. 10.1029/2006JB004555.
36. Özdemir Ö., Dunlop D.J., Moskowitz B.M. Changes in remanence, coercivity and domain state at low temperature in magnetite. Earth Planet. Sci. Lett. 2002, 194:343-358.
37. Özdemir Ö., Dunlop D.J. Thermoremanent magnetization of multidomain hematite. J. Geophys. Res. 2005, 110:B09104. 10.1029/2005JB003820.
38. Pastrana J.M., Hopstock D.M. Magnetic properties of natural hematite and goethite. Trans. SME/AIME 1977, 262:1-5.
39. Prasada P.S.R., Shiva Prasada K., Krishna Chaitany V., Babua E.V.S.S.K., Sreedharc B., Ramana Murthyd S. In situ FTIR study on the dehydration of natural goethite. J. Asian Earth Sci. 2006, 27:503-511.
40. Rendón J.L., Serna C.J. IR spectra of powder hematite: effects of particle size and shape. Clay Miner. 1981, 16:375-381.
41. 8) using first-order reversal curve diagrams. J. Geophys. Res. 2006, 111(B12):B12S35. 10.1029/2006JB004715.
42. Rösler, H.J., 1983. Lehrbuch der Mineralogie. Verlag für Grundstoffindustrie, Leipzig, 832 pp.
43. Schwertmann U., Cornell R.M. Iron Oxides in the Laboratory, Preparation and Characterization 2000, Wiley-VCH, Weinheim, 188 pp.
44. Schwertmann U., Taylor R.M. Iron oxides. Minerals in Soil Environments 1977, Soil Science Society of America, Madison, WI, pp. 145-180.
45. Scott E.R.D., Fuller M. A possible source for the Martian crustal magnetic field. Earth Planet. Sci. Lett. 2004, 220:83-90.
46. Sugimoto T., Muramatsu A., Sakata K., Shindo D. Characterization of hematites particles of different shapes. J. Colloid Interface Sci. 1993, 158:420-428.
47. Sunagawa I., Flanders P.J. Structural and magnetic studies in hematite single crystals. Philos. Mag. 1965, 11:747-761.
48. Tauxe L., Kent D.V. Properties of a detrital remanence carried by hematite from study of modern river deposits and laboratory redeposition experiments. Geophys. J. Roy. Astron. Soc. 1984, 76:543-561.
49. Thompson R., Oldfield F. Environmental Magnetism 1986, Allen & Unwin, London, 227 pp.
50. Torrent J., Schwertmann U. Influence of hematite on the colour of red beds. J. Sed. Petrol. 1987, 57:682-686.
51. Van de Hulst H.C. Light Scattering by Small Particles 1957, John Wiley & Sons, New York, pp. 70-72.
52. 4) and its transition point at low temperatures. Nature 1939, 144:327-328.
53. Wells M.A., Fitzpatrick R.W., Gilkes R.J., Dobson J. Magnetic properties of metal-substituted haematite. Geophys. J. Int. 1999, 138:571-580.
54. Wolska E. The structure of hydrohematite. Kristallogr. Z. 1981, 154:69-75.
55. Wolska E., Schwertmann U. Nonstoichiometric structures during dehydroxylation of goethite. Kristallogr. Z. 1989, 189:223-237.
56. Yamazaki T., Ioka N. Environmental rock-magnetism of pelagic clay: implications for Asian eolian input to the North Pacific since the Pliocene. Paleoceanography 1997, 12:111-124.
57. Zhao Y.M., Dunnill C.W., Zhu Y.Q., Gregory D.H., Kockenberger W., Li Y.H., Hu W.B., Ahmad I., McCartney D.G. Low-temperature magnetic properties of hematite nanorods. Chem. Mater. 2007, 19:916-921.
58. Zysler R.D., Vasquez-Mansilla M., Arciprete C., Dimitrijewits M., Rodriguez-Sierra D., Saragovi C. Structure and magnetic properties of thermally treated nanohematite. J. Magn. Magn. Mater. 2001, 224:39-48.