A novel dewar-like reactor for maintaining constant heat and enhancing product yields during microwave-assisted organic syntheses

Organic Process Research and Development

Volumn 14, Issue 6, 2010, Pages 1453-1456

  Horikoshi, Satoshi ^a   Osawa, Atsushi ^a   Suttisawat, Yindee ^a   Abe, Masahiko ^a   Serpone, Nick ^b  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

^b UNIVERSITY OF PAVIA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS MEDIA; CHEMICAL DEVICES; DIELECTRIC SUBSTRATES; DOUBLE-WALLED; HETEROGENEOUS MEDIA; HOMOGENEOUS MEDIA; MICROWAVE REACTIONS; MICROWAVE-ASSISTED; NON-POLAR SOLVENTS; ORGANIC SYNTHESIS; PRODUCT YIELDS; REACTOR VESSEL; SINGLE-WALLED; SUZUKI-MIYAURA COUPLING REACTION;

CHEMICAL BONDS; MICROWAVES; NUCLEAR REACTORS;

SYNTHESIS (CHEMICAL);

EID: 78649663720     PISSN: 10836160     EISSN: 1520586X     Source Type: Journal    
DOI: 10.1021/op100181u     Document Type: Article

References (14)

1. Jolly, W. L. The Synthesis and Characterization of Inorganic Compounds; Prentice Hall: New York, 1970.
2. Giguere, R. J.; Bray, T. L.; Duncan, S. M.; Majctich, G. Application of commercial microwave ovens to organic synthesis Tetrahedron Lett. 1986, 27, 4945-4948
3. Kappe, C. O.; Dallinger, D.; Murphree, S. S. Practical Microwave Synthesis for Organic Chemists; Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim, 2009.
4. Horikoshi, S.; Hidaka, H.; Serpone, N. Environmental remediation by an integrated microwave/UV illumination technique VI. A simple modified domestic microwave oven integrating an electrodeless UV-Vis lamp to photodegrade environmental pollutants in aqueous media J. Photochem. Photobiol., A 2004, 161, 221-225
5. Matuslewlcz, H. Development of a high pressure/temperature focused microwave heated Teflon bomb for sample preparation Anal. Chem. 1994, 66, 751-755
6. Strauss, C. R. On scale up of organic reactions in closed vessel microwave systems Org. Process. Res. Dev. 2009, 13, 915-923
7. He, P.; Haswell, S. J.; Fletcher, P. D. I. Microwave-assisted Suzuki reactions in a continuous flow capillary reactor Appl. Catal., A 2004, 274, 111-114
8. Schanche, J.-S. Microwave synthesis solutions from personal chemistry Mol. Diversity 2003, 7, 293-300
9. Horikoshi, S.; Abe, H.; Torigoe, K.; Abe, M.; Serpone, N. Access to small size distributions of nanoparticles by microwave-assisted synthesis. Formation of Ag nanoparticles in aqueous carboxymethylcellulose solutions in batch and continuous-flow reactors Nanoscale, 2010, 2, 1441-1447
10. Herrero, M. A.; Kremsner, J. M.; Kappe, C. O. Nonthermal microwave effects revisited: On the importance of internal temperature monitoring and agitation in microwave chemistry J. Org. Chem. 2008, 73, 36-47
11. Fargher, R. G.; Perkin, A. G.; Armstrong, H. E. Obituary notices: Lucy Higginbotham, 1896-1927; Edwin Roy Watson, 1880-1926; Horace Brown, 1848-1925; Sir James Dewar, 1842-1923 J. Chem. Soc. 1928, 1056-1076
12. 3 Materials (M = Mn, Cd) Using a Dewar-Ampoule Device Eur. J. Inorg. Chem. 2004, 949-952
13. Guillén, E.; Rico, R.; López-Romero, J. M.; Bedia, J.; Rosas, J. M.; Rodríguez-Mirasol, J.; Cordero, T. Pd-activated carbon catalysts for hydrogenation and Suzuki reactions Appl. Catal., A 2009, 368, 113-120
14. McGill, S. L.; Walkiewicz, J. W. Symposium Proceedings J. Microwave Power Electromagn. Energy 1987, 175-177