Solid-acid-catalyzed esterification of oleic acid assisted by microwave heating

Industrial and Engineering Chemistry Research

Volumn 49, Issue 23, 2010, Pages 12135-12139

  Melo Júnior, Carlos A R ^a   Albuquerque, Carlos E R ^a   Carneiro, Juliana S A ^a   Dariva, Claudio ^a   Fortuny, Montserrat ^a   Santos, Alexandre F ^a   Egues, Silvia M S ^a   Ramos, André L D ^b  

^a TIRADENTES UNIVERSITY   (Brazil)

^b FEDERAL UNIVERSITY OF SERGIPE   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

ALTERNATIVE ROUTES; CONVENTIONAL HEATING; HIGH TEMPERATURE; METHYL ESTERIFICATION; MOLAR RATIO; REACTION CONVERSION; SOLID ACID CATALYSTS; SULFATED ZIRCONIA; TRANSESTERIFICATION REACTION;

CATALYSIS; CATALYST DEACTIVATION; ESTERIFICATION; ESTERS; HEATING; METHANOL; MICROWAVE HEATING; MICROWAVE IRRADIATION; NIOBIUM; NIOBIUM OXIDE; OLEIC ACID;

ZIRCONIA;

EID: 78649603615     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie100501d     Document Type: Article

References (47)

1. Marchetti, J. M.; Miguel, V. U.; Errazu, A. F. Possible methods for biodiesel production Renewable Sustainable Energy Rev. 2007, 11, 1300
2. Barnwal, B. K.; Sharma, M. P. Prospects of biodiesel production from vegetable oils in India Renewable Sustainable Energy Rev. 2005, 9, 363
3. Zabeti, M.; Daud, W. M. A. W.; Aroua, M. K. Activity of solid catalysts for biodiesel production: A review Fuel Process. Technol. 2009, 90, 770
4. Ma, F.; Hanna, M. A. Biodiesel production: A review Bioresour. Technol. 1999, 70, 1
5. Di Serio, M.; Tesser, R.; Dimiccoli, M.; Cammarota, F.; Nastasi, M.; Santacesaria, E. Synthesis of biodiesel via homogeneous Lewis acid catalyst J. Mol. Catal. A: Chem. 2005, 239, 111
6. Van Gerpen, J. Biodiesel processing and production Fuel Process. Technol. 2005, 86, 1097
7. Kusdiana, D.; Saka, S. Two-step preparation for catalyst-free biodiesel fuel production Appl. Biochem. Biotechnol. 2004, 115, 781
8. Minami, E.; Saka, S. Kinetics of hydrolysis and methyl esterification for biodiesel production in two-step supercritical methanol process Fuel 2006, 85, 2479
9. Suwannakarn, K.; Lotero, E.; Ngaosuwan, K.; Goodwin, J. G., Jr. Simultaneous free fatty acid esterification and triglyceride transesterification using a solid acid catalyst with in situ removal of water and unreacted methanol Ind. Eng. Chem. Res. 2009, 48, 2810
10. Liu, Y.; Wang, L.; Yan, Y. Biodiesel synthesis combining pre-esterification with alkali catalyzed process from rapeseed oil deodorizer distillate Fuel Proc. Technol. 2009, 90, 857
11. 3 catalysts Appl. Catal., A 2009, 353, 203
12. Santacesaria, E.; Tesser, R.; Di Serio, M.; Guida, M.; Gaetano, D.; Agreda, A. G.; Cammarota, F. Comparison of different reactor configurations for the reduction of free acidity in raw materials for biodiesel production Ind. Eng. Chem. Res. 2007, 46, 8355
13. Ozbay, N.; Oktar, N.; Tapan, N. A. Esterification of free fatty acids in waste cooking oils (WCO): Role of ion-exchange resins Fuel 2008, 87, 1789
14. Mo, X.; Lotero, E.; Lu, C.; Liu, Y.; Goodwin, J. G. A novel sulfonated carbon composite solid acid catalyst for biodiesel synthesis Catal. Lett. 2008, 123, 1
15. Mbaraka, I. K.; Radu, D. R.; Lin, V.-Y.; Shanks, B. H. Organosulfonic acid-functionalized mesoporous silicas for the esterification of fatty acid J. Catal. 2003, 219, 329
16. Marchetti, J. M.; Errazu, A. F. Comparison of different heterogeneous catalysts and different alcohols for the esterification reaction of oleic acid Fuel 2008, 87, 3477
17. Souza, M. S.; Aguieiras, E. C. G.; Silva, M. A. P.; Langone, M. A. P. Biodiesel synthesis via esterification of feedstock with high content of free fatty acids Appl. Biochem. Biotechnol. 2009, 154, 253
18. 5 catalyst Ind. Eng. Chem. Res. 2009, 48, 10816
19. Aranda, D. A. G.; Gonçalves, J. A.; Peres, J. S.; Ramos, A. L. D.; Melo, C. A. R., Jr.; Antunes, O. A. C.; Furtado, N. C.; Taft, C. A. The use of acids, niobium oxide, and zeolite catalysts for esterification reactions J. Phys. Org. Chem. 2009, 22, 709
20. Kiss, A. A.; Dimian, A. C.; Rothenberg, G. Biodiesel by catalytic reactive distillation powered by metal oxides Energy Fuels 2008, 22, 598
21. Kiss, A. A.; Dimian, A. C.; Rothenberg, G. Solid acid catalysts for biodiesel production-Towards sustainable energy Adv. Synth. Catal. 2006, 348, 75
22. Kiss, A. A.; Omota, F.; Dimian, A. C.; Rothenberg, G. The heterogeneous advantage: Biodiesel by catalytic reactive distillation Top. Catal. 2006, 40, 141
23. 2 Catal. Today 2009, 148, 169
24. Ngaosuwan, K.; Lotero, E.; Suwannakarn, K.; Goodwin, J. G., Jr.; Praserthdam, P. Hydrolysis of triglycerides using solid acid catalysts Ind. Eng. Chem. Res. 2009, 48, 4757
25. Sreeprasanth, P. S.; Srivastava, R.; Srinivas, D.; Ratnasamy, P. Hydrophobic, solid acid catalysts for production of biofuels and lubricants Appl. Catal., A 2006, 314, 148
26. Lotero, E.; Liu, Y.; Lopez, D. E.; Suwannakarn, K.; Bruce, D. A.; Goodwin, J. G., Jr. Synthesis of biodiesel via acid catalysis Ind. Eng. Chem. Res. 2005, 44, 5353
27. Leadbeater, N. E.; Stencel, L. M. Fast, easy preparation of biodiesel using microwave heating Energy Fuels 2006, 20, 2281
28. Fortuny, M.; Ramos, A. L. D.; Dariva, C.; Egues, S. M. S.; Santos, A. F.; Nele, M.; Coutinho, R. C. C. Principais aplicações das microondas na produção e refino de petróleo Quim. Nova 2008, 31, 1553
29. Meredith, R. Engineers' Handbook of Industrial Microwave Heating; The Institution of Electrical Engineers: London, 1998.
30. Berlan, J. Microwaves in chemistry: Another way of heating reaction mixtures Radiat. Phys. Chem. 1995, 45, 581
31. Loupy, A. Microwaves in Organic Synthesis; Wiley-VCH Verlag GmbH & Co.: Weinheim, 2002.
32. Azcan, N.; Danisman, A. Microwave assisted transesterification of rapeseed oil Fuel 2008, 87, 1781
33. Perin, G.; Álvaro, G.; Westphal, E.; Viana, L. H.; Jacob, R. G.; Lenardão, E. J.; D'Oca, M. G. M. Transesterification of castor oil assisted by microwave irradiation Fuel 2008, 87, 2838
34. Zhang, S.; Zu, Y. G.; Fu, Y. J.; Luo, M.; Zhang, D. Y.; Efferth, T. Rapid microwave-assisted transesterification of yellow horn oil to biodiesel using a heteropolyacid solid catalyst Bioresour. Technol. 2010, 101, 931
35. Pipus, G.; Plazl, I.; Koloini, T. Esterification of benzoic acid with 2-ethylhexanol in a microwave stirred-tank reactor Ind. Eng. Chem. Res. 2002, 41, 1129
36. Kabza, K. G.; Chapados, B. R.; Gestwicki, J. E.; McGrath, J. L. Microwave-induced esterification using heterogeneous acid catalyst in a low dielectric constant medium J. Org. Chem. 2000, 65, 1210
37. Toukoniitty, B.; Mikkola, J. P.; Eranen, K.; Salmi, T.; Murzin, D. Y. Esterification of propionic acid under microwave irradiation over an ion-exchange resin Catal. Today 2005, 100, 431
38. Raner, K. D.; Strauss, C. R. Influence of microwaves on the rate of esterification of 2,4,6-trimethylbenzoic acid with 2-propanol J. Org. Chem. 1992, 57, 6231
39. Chemat, F.; Poux, M.; Galema, S. A. Esterification of stearic acid by isomeric forms of butanol in a microwave over under homogeneous and heterogeneous reaction conditions J. Chem. Soc., Perkin Trans. 1997, 2, 2371
40. Melo Júnior, C. A. R.; Albuquerque, C. E. R.; Fortuny, M.; Dariva, C.; Egues, S.; Santos, A. F.; Ramos, A. L. D. Use of microwave irradiation in the noncatalytic esterification of C18 fatty acids Energy Fuels 2009, 23, 580
41. López, D. E.; Goodwin, J. G., Jr.; Bruce, D. A. Transesterification of triacetin with methanol on Nafion® acid resins J. Catal. 2007, 245, 381
42. López, D. E.; Goodwin, J. G., Jr.; Bruce, D. A.; Furuta, S. Esterification and transesterification using modified-zirconia catalysts Appl. Catal., A 2008, 339, 76
43. Garcia, C. M.; Teixeira, S.; Marciniuk, L. L.; Schuchardt, U. Transesterification of soybean oil catalyzed by sulfated zirconia Bioresour. Technol. 2008, 99, 6608
44. Aranda, D. A. G.; Santos, R. T. P.; Tapanes, N. C. O.; Ramos, A. L. D.; Antunes, O. A. C. Acid-catalyzed homogeneous esterification reaction for biodiesel production from palm fatty acids Catal. Lett. 2008, 122, 20
45. Cardoso, A. L.; Neves, S. C. G.; Silva, M. J. Kinetic study of alcoholysis of the fatty acids catalyzed by tin chloride (II): An alternative catalyst for biodiesel production Energy Fuels 2009, 23, 1718
46. Kiss, A. A. Novel process for biodiesel by reactive absorption Sep. Purif. Technol. 2009, 69, 280
47. Dimian, A. C.; Bildea, C. S.; Omota, F.; Kiss, A. A. Innovative process for fatty acid esters by dual reactive distillation Comput. Chem. Eng. 2009, 33, 743