Determination of insoluble soap in agricultural soil and sewage sludge samples by liquid chromatography with ultraviolet detection

Environmental Toxicology and Chemistry

Volumn 29, Issue 11, 2010, Pages 2470-2476

  Cantarero, Samuel ^a   Zafra Gómez, Alberto ^a   Ballesteros, Oscar ^a   Navalón, Alberto ^a   Vílchez, José L ^a   Crovetto, Guillermo ^a   Verge, Coral ^b   De Ferrer, Juan A ^b  

^a UNIVERSITY OF GRANADA   (Spain)

^b CEPSA   (Spain)

Author keywords

Agricultural soil; Liquid chromatography; Microwave assisted extraction; Sewage sludge; Soap

Indexed keywords

AGRICULTURAL SOILS; ANALYTES; ANALYTICAL METHODOLOGY; ANALYTICAL PROCEDURE; DERIVATIZATION PROCEDURES; ENVIRONMENTAL BEHAVIOR; ENVIRONMENTAL COMPARTMENT; FATTY ACID SALTS; MATRIX EFFECTS; MICROWAVE-ASSISTED EXTRACTION; PETROLEUM ETHER; POTASSIUM CARBONATES; POTASSIUM SALTS; QUANTIFICATION LIMIT; SAMPLE CLEAN-UP; SLUDGE SAMPLES; SOAP; SOLUBLE SALTS; ULTRA VIOLET DETECTION;

ADSORPTION; BEHAVIORAL RESEARCH; CALCIUM; ESTERS; ETHERS; FATTY ACIDS; LIQUIDS; METHANOL; SALTS; SEWAGE SLUDGE; SOILS;

LIQUID CHROMATOGRAPHY;

4 BROMOPHENACYL BROMIDE; CALCIUM SALT; EDETIC ACID; MAGNESIUM SALT; PETROLEUM ETHER; POTASSIUM CARBONATE; POTASSIUM SALT; SOAP;

ADSORPTION; AGRICULTURAL SOIL; CALCIUM; CLEANUP; DETERGENT; ENVIRONMENTAL ASSESSMENT; ESTER; FATTY ACID; LIQUID CHROMATOGRAPHY; MAGNESIUM; POLLUTANT REMOVAL; POTASSIUM; PRECIPITATION (CHEMISTRY); SAMPLING; SEWAGE; SLUDGE; TRANSFORMATION; ULTRAVIOLET RADIATION;

ADSORPTION KINETICS; ARTICLE; BIOTRANSFORMATION; CONTROLLED STUDY; ESTERIFICATION; EXTRACTION; LIQUID CHROMATOGRAPHY; MICROWAVE IRRADIATION; NONHUMAN; PRECIPITATION; PRIORITY JOURNAL; REACTION TIME; SLUDGE; SOIL; ULTRAVIOLET RADIATION;

CALCIUM; CHROMATOGRAPHY, LIQUID; MAGNESIUM; SEWAGE; SOAPS; SOIL POLLUTANTS; SPECTROPHOTOMETRY, ULTRAVIOLET;

EID: 78649543518     PISSN: 07307268     EISSN: 15528618     Source Type: Journal    
DOI: 10.1002/etc.303     Document Type: Article

References (25)

1. Ogoshi T, Miyawaki Y. 1985. Soap and related products: Palm and lauric oil. JAOCS 62: 331-335.
2. Ivanković T, Hrenović J. 2010. Surfactants in the environment. Arh Hig Rada Toksikol 61: 95-110.
3. European Union. 2003. Report of Human and Environmental Risk Assessment on ingredients of European household cleaning products (HERA). Fatty acids salts (Soaps) Environmental Risk Assessment. Draft September, 2003. Brussels, Belgium.
4. Prats D, Rodríguez M, Varo P, Moreno A, Ferrer J. 1996. Biodegradation of soaps in anaerobic digestors and on sludge amended soils. Proceedings, 4th World Surfactants Congress, Barcelona, Spain, June 3-7, pp 233-245.
5. Varó-Galván P, Prats-Rico D, Rodríguez-Pastor M. 2005. Temperature effects in anaerobic biodegradation of soaps in anaerobic screening tests. Tenside Surfactants Detergents 42: 40-43.
6. Gerike P. 1984. The biodegradability testing of poorly water soluble compounds. Chemosphere 13: 169-190.
7. Wood TE. 1999. Book of Analytical Methods, Evaluation Techniques, and Regulatory Requirements, Soap Technology for the 1990. American Oil Chemist Society, Champaign, IL, USA.
8. American Oil Chemist Society 1964. Official and Tentative Methods. Section D: Sampling and Analysis of Soap and Soap Product, 3rd ed. (revised 1973). Champaign, IL, USA.
9. American Society for Testing Materials. 2009. Standard test methods for chemical analysis of soaps containing synthetic detergents. D820-93. In Annual Book of ASTM standards, Vol 15.04. Section 9-12. West Conshohocken, PA, USA.
10. 12 fatty acids in water and sludge. J High Res Chromatogr 7: 540-541.
11. Vioque E, Maza MP, Millán F. 1985. High performance liquid chromatography of fatty acids as their p-phenyl-azophenacyl esters. J Chromatogr 331: 187-192.
12. Mukherjee PS, Karnes HT. 1996. Ultraviolet and fluorescence derivatization reagents for carboxylic acids suitable for high performance liquid chromatography: A review. Biomed Chromatogr 10: 193-204.
13. 22) in urban wastewater by GC-MS. Water Res 32: 3168-3172.
14. González-Casado A, del Olmo M, Alonso EJ, Espinosa P, Vílchez JL. 1998. Determination of total fatty acids (C8-C22) in sludge by gas chromatography-mass spectrometry. J Chromatogr A 826: 49-56.
15. Matthijs E, Holt M, Kiewiet A, Rijs G. 1996. Fate of surfactants in activated sludge waste water treatment plants: Outcome of field studies on linear alkylbenzene sulphonate, alcohol ethoxylate, alcohol ethoxy sulphate, alcohol sulphate and soap. Proceedings, 4th World Surfactants Congress, Barcelona, Spain, June 3-7, pp 81-86.
16. Hayashi K, Kawase J, Yoshimura K, Ara K, Tsuji K. 1984. Determination of trace levels of FA metal salts by HPLC with fluorescence prelabelling. Anal Biochem 136: 314-320.
17. Moreno A, Bravo J, Ferrer J, Bengoechea C. 1993. Soap determination in sewage sludge by high-performance liquid chromatography. JAOCS 70: 667-671.
18. Folke J, Cassani G, Ferrer J, López I. 2003. Linear alkylbenzene sulphonates, branched dodecylbenzene sulphonates and soap analysed in marine sediments from the Baltic Proper and Little Belt. Tenside Surfactants Detergents 40: 17-23.
19. Manugistics. 2000. Statgraphics Plus, Version 5.0. Rockville, MD, USA.
20. Knapp DR. 1979. Handbook of Analytical Derivatization Reactions, 1st ed. Wiley-InterScience, New York, NY, USA.
21. Blau K, Halket J. 1994. Handbook of Derivatives for Chromatography, 2nd ed. John Wiley & Sons, New York, NY, USA.
22. Cela R. 1994. Avances en Quimiometría Práctica. University of Santiago de Compostela, Servicio de Publicaciones e, Intercambio Científico Eds. Santiago de Compostela, Spain.
23. Analytical Methods Committee. 1994. Is my calibration linear? Analyst 119: 2363-2366.
24. MacDougall D, Crummett WB. 1980. Guidelines for data acquisition and data quality evaluation in environmental chemistry. Anal Chem 52: 2242-2249.
25. González-Casado A, Cuadros-Rodríguez L, Hernández EA, Vílchez JL. 1996. Estimate of gas chromatographic blanks application to detection limits evaluation as recommended by IUPAC. J Chromatogr A 726: 133-139.