Structure of lignosulphonates from acidic magnesium-based sulphite pulping of Eucalyptus globulus

Journal of Wood Chemistry and Technology

Volumn 29, Issue 4, 2009, Pages 337-357

  Marques, A P ^a   Evtuguin, D V ^a   Magina, S ^a   Amado, F M L ^a   Prates, A ^b  

^a UNIVERSITY OF AVEIRO   (Portugal)

^b Silvicaima Sociedade Silvícola Caima SA   (Portugal)

Author keywords

ESI MS; Eucalyptus globulus; Lignosulphonates; NMR; Structure; Sulphite pulping; Sulphite spent liquor

Indexed keywords

ESI-MS; EUCALYPTUS GLOBULUS; LIGNOSULPHONATES; SULPHITE PULPING; SULPHITE SPENT LIQUOR;

DIALYSIS; ELECTROSPRAY IONIZATION; ETHERS; LIGNIN; MAGNESIUM; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE; OLIGOMERS; PHASE TRANSITIONS; RESONANCE;

FORESTRY;

BUILDINGS; DIALYSIS; ETHERS; EUCALYPTUS GLOBULUS; FORESTRY; IONIZATION; LIGNINS; MAGNESIUM; NUCLEAR MAGNETIC RESONANCE; OLIGOMERS; PHASE TRANSITION; RESONANCE;

EID: 78649543045     PISSN: 02773813     EISSN: 15322319     Source Type: Journal    
DOI: 10.1080/02773810903207762     Document Type: Article

References (23)

1. Sjöström, E. Wood Chemistry. Fundamentals and Applications; Academic Press: New York, USA, 1993.
2. Glasser, W.G.; Kelly, S.S. Lignin. In Encyclopedia of Polymer Science and Engineering; Vol. 8, Mark, H.F.; Bikales, N.M.; Overberger, C.G.; Menges G. Eds; Wiley Interscience; New York 1987, 795-850.
3. Hoyt, C.H.; Goheen, D.W. Polymeric products. In Lignins Occurrence, Formation, Structure and Reactions; Sarkanen, K.V.; Ludwig, C.H., Eds.; Wiley Interscience; New York, 1971; 833-860.
4. Sazanov, Yu. N.; Podeshvo, I.V.; Mikhailov, G.M.; Fedorova, G.N.; Goikhman, M. Ya.; Lebedeva, M.F.; Kudryavtsev, V.V. Polymeric materials derived from vanillic acid. Russian J. Appl. Chem. (Engl. Transl.), 2002, 75 (5), 777-780.
5. Bjørsvik, H.-R. Fine chemicals from lignosulfonates. 1. Synthesis of vanillin by oxidation of lignosulfonates. Organic Process Research &Development 1999, 3, 330-340.
6. Bjørsvik, H.-R.; Liguori, L. Organic processes to pharmaceutical chemicals based on fine chemicals from lignosulfonates. Organic Process Research &Development 2002, 6, 279-290.
7. Hocking, M.B. Vanillin: Synthetic flavoring from spent sulfite liquor. J. Chem. Educ. 1997, 74 (9), 1055-1059.
8. Marques, A.P.; Evtuguin, D.V.; Magina, S.; Amado, F.M.L.; Prates A. Chemical composition of spent liquors from acidic magnesium-based sulphite pulping of Eucaplyptus globulus. J. Wood Chem. Technol. 2009. Submitted article.
9. Evtuguin, D.V.; Pascoal Neto, C.; Silva, A.M.S.;Domingues, P.M.;Amado, F.M.L.; Robert, D.; Faix O. Comprehensive study on the chemical structure of dioxane lignin from plantation Eucalyptus globulus wood. J. Agric. Food Chem. 2001, 49, 4252-4261. (Pubitemid 32896418)
10. Evtuguin, D.V.; Tomás, J.L.; Silva A.M.S.; Pascoal Neto, C. Characterization of acetylated heteroxylan from Eucalyptus globulus Labill. Carbohydr. Res. 2003, 338 (7), 597-607.
11. Lisboa, S.A.; Evtuguin, D.V.; Pascoal Neto C.; Goodfellow, B.J. Isolation and structural characterization of polysaccharides dissolved in Eucalyptus globules kraft black liquors. Carbohydr. Polym. 2005, 60, 77-85. (Pubitemid 40371058)
12. Luthaes, B.F.; Myrvold, B.O.; Lauten, R.A.; Endeshaw, M.M. 1H and 13C NMR data of benzylsulfonic acids-Model compounds for lignosulfonates. Mang. Reson. Chem. 2008, 46, 299-305.
13. Gellerstedt, G.; Gierer, J. The reactions of lignin during acidic sulphite pulping. Svensk Papperstidn. 1971, 74 (5), 117-127.
14. Gellerstedt, G.; Gierer, J. The reactions of lignin during neutral sulfite pulping. Part I. The behaviour of β-arylrther structures. Acta Chem. Scan. 1968, 22 (8), 2510-2518.
15. Gellerstedt, G.; Gierer, J. The reactions of lignin during neutral sulfite pulping. Part III. The mechanism of formation of styrene-β- sulphonic acid structures. Acta Chem. Scan. 1970, 24 (5), 1645-1654.
16. Gellerstedt, G.; Gierer, J. The reactions of lignin during neutral sulfite pulping. Part IV. The behaviour of structural elements of the pinoresinol type. Acta Chem. Scan. 1972, 26 (2), 701-714.
17. Ralph, S.A.; Ralph, J.; Landucci, L.L. NMR database of lignin and cell wall model compounds, 2004; Available at http://ars.usda.gov/Services/ docs.htm?docid=10491 (accessed 13 April 2009).
18. Robert, D. Carbon-13 Nuclear magnetic resonance spectrometry. In Methods in Lignin Chemistry; Lin, S.Y.; Dence, C.W., Eds.; Springer-Verlag; Berlin, 1992; 250-273.
19. Evtuguin, D.V.; Amado, F.M.L. Application of electrospray ionization mass spectrometry to the elucidation of the primary structure of lignin. Macromol. Biosci. 2003, 3 (6), 339-343. (Pubitemid 36903760)
20. Reis, A.; Domingues, M.R.M.; Domingues, P.; Ferrer-Correia, A.J.; CoimbraM.A. Positive and negative electrospray ionisation tandem mass spectrometry as a tool for structural characterisation of acid released oligosaccharides from olive pulp glucuronoxylans. Carbohydr. Res. 2003, 338 (7), 1497-1505. (Pubitemid 36776302)
21. Pinto, P.C.; Evtuguin, D.V.; Pascoal Neto, C.; Silvestre, A.J.D. Behaviour of Eucalyptus globulus lignin during kraft pulping. Part 2. Analysis by NMR, ESI/MS and GPC techniques. J. Wood Chem. Technol. 2002, 22 (2), 109-125. (Pubitemid 35039581)
22. Glennie, D.W. Reactions in sulfite pulping. In Lignins Occurrence, Formation, Structure and Reactions; Sarkanen, K.V.; Ludwig, C.H., Eds.; Wiley Interscience; New York, 1971; 597-637.
23. Gellerstedt, G. The reactions of lignin during sulfite pulping. Svensk Papperstidn. 1976, 79, 537-543.