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Volumn 132, Issue 47, 2010, Pages 16759-16761

The redox chemistry of sulfenic acids

Author keywords

[No Author keywords available]

Indexed keywords

DISSOCIATION ENTHALPIES; EPR SPECTROSCOPY; H-BONDING; REDOX CHEMISTRY; SULFENIC ACIDS;

EID: 78649504423     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1083046     Document Type: Article
Times cited : (57)

References (52)
  • 1
    • 78649524705 scopus 로고    scopus 로고
    • For recent perspectives in this area, see
    • For recent perspectives in this area, see
  • 4
    • 78649525403 scopus 로고    scopus 로고
    • The best studied examples to date are peroxiredoxins, (3) hydrogenases, (4) NADH peroxidases, (5) and nitrile and thiocyanate hydrolases (6)
    • The best studied examples to date are peroxiredoxins, (3) hydrogenases, (4) NADH peroxidases, (5) and nitrile and thiocyanate hydrolases (6)
  • 5
    • 78649522272 scopus 로고    scopus 로고
    • For a recent review, see
    • For a recent review, see
  • 8
    • 78649518492 scopus 로고    scopus 로고
    • For a review, see
    • For a review, see
  • 17
    • 78649507023 scopus 로고    scopus 로고
    • Several chapters of a recent volume of Methods in Enzymology is devoted to this topic. See, in particular
    • Several chapters of a recent volume of Methods in Enzymology is devoted to this topic. See, in particular
  • 23
    • 78649526877 scopus 로고    scopus 로고
    • Examples include
    • Examples include
  • 34
    • 78649495707 scopus 로고    scopus 로고
    • 33S (S = 3/2; a = 1.72 G) was also visible
    • 33S (S = 3/2; a = 1.72 G) was also visible.
  • 35
    • 78649508125 scopus 로고    scopus 로고
    • 3SO was generated via photolysis of either (a) a solution of dimethyl sulfide, isopropyl alcohol, and di- tert -butylperoxide or (b) a mixture of methanethiol, di- tert -butylperoxide, and ethylene. See
    • 3SO was generated via photolysis of either (a) a solution of dimethyl sulfide, isopropyl alcohol, and di- tert -butylperoxide or (b) a mixture of methanethiol, di- tert -butylperoxide, and ethylene. See
  • 37
    • 78649495923 scopus 로고    scopus 로고
    • The tert -butyl sulfinyl radicals were generated by photolysis of di- tert -butylperoxide containing solutions of t -BuSOH formed in situ from the thermolysis of di- tert -butyl sulfoxide. See
    • The tert -butyl sulfinyl radicals were generated by photolysis of di- tert -butylperoxide containing solutions of t -BuSOH formed in situ from the thermolysis of di- tert -butyl sulfoxide. See
  • 39
    • 78649501146 scopus 로고    scopus 로고
    • 2, have been observed in frozen aqueous samples. See
    • 2, have been observed in frozen aqueous samples. See
  • 41
    • 78649494091 scopus 로고    scopus 로고
    • 2-SR
    • 2-SR.
  • 42
    • 78649516445 scopus 로고    scopus 로고
    • -9 at 298 K
    • -9 at 298 K.
  • 45
    • 78649509106 scopus 로고    scopus 로고
    • The calculated electronic structure in PhSO suggests no delocalization of spin from the sulfinyl radical. See
    • The calculated electronic structure in PhSO suggests no delocalization of spin from the sulfinyl radical. See
  • 48
    • 78649501500 scopus 로고    scopus 로고
    • 3H could not catalyze the condensation of the sulfenic acid to the corresponding thiosulfinate
    • 3H could not catalyze the condensation of the sulfenic acid to the corresponding thiosulfinate.
  • 50
    • 78649524341 scopus 로고    scopus 로고
    • 2O at 20°C. See
    • 2O at 20°C. See
  • 52
    • 78649496297 scopus 로고    scopus 로고
    • This was the maximum reliable value we could obtain with our pH probe
    • This was the maximum reliable value we could obtain with our pH probe.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.