Evidences for the relationship between surface structure and reactivity of goethite nanoparticles based on advanced molecular-probe methods

Adsorption

Volumn 16, Issue 4-5, 2010, Pages 185-195

  Stevanovic, Stéphane ^a   AliAhmad, Mouhamad ^b   Razafitianamaharavo, Angelina ^a   Villiéras, Frédéric ^a   Odile, Barrès ^a   Prélot, Bénédicte ^b   Zajac, Jerzy ^b   Douillard, Jean Marc ^b   Chanéac, Corinne ^c  

^a UNIVERSITÉ DE LORRAINE   (France)

^b CNRS   (France)

^c UNIVERSITÉ PIERRE ET MARIE CURIE   (France)

Author keywords

Acid sites; Ammonia; Goethites; Nitrogen adsorption; Pyridine

Indexed keywords

ACID SITE; AMMONIA ADSORPTION; ELECTRON-DONATING; GASEOUS NITROGEN; GOETHITE NANOPARTICLES; GOETHITES; HIGH ENERGY; MOLECULAR NITROGEN; MOLECULAR PROBES; NITROGEN ADSORPTION; NITROGEN DERIVATIVES; ORDER OF MAGNITUDE; PROBE METHODS; PYRIDINE MOLECULES; SPECIFIC ADSORPTION; SURFACE ACIDITY; SURFACE DOMAINS; SURFACE SITES;

ACIDS; AMMONIA; ARGON; DESORPTION; NITROGEN; PROBES; PYRIDINE; SURFACE PROPERTIES; SURFACE STRUCTURE;

GAS ADSORPTION;

EID: 78649447113     PISSN: 09295607     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10450-010-9221-6     Document Type: Article

References (30)

1. Cornell, R.M., Schwertmann, U.: The Iron: Structure, Properties, Reactions, Occurrences and Uses, p. 573. VCH, Weinheim (1996)
2. 2 contamination. J. Electroanal. Chem. 105, 161-167 (1979)
3. Gaboriaud, F., Ehrhardt, J.J.: Effects of different crystal faces on the surface charge of colloidal goethite (a-FeOOH) particles: An experimental and modeling study. Geochim. Cosmochim. Acta 67, 967-983 (2003)
4. Garnier, C., Gorner, T., Villiéras, F., De Donato, P., Polakovic, M., Bersillon, J.L.,Michot, L.J.: Activated carbon surface heterogeneity seen by parallel probing by inverse liquid chromatography at the solid/liquid interface and by gas adsorption analysis at the solid/gas interface. Carbon 45, 240-247 (2007)
5. Grillet, Y., Rouquerol, F., Rouquerol, J.: Study of physical adsorption of gases by a continuous procedure. 1. Application to determination of specific surface-areas of mesoporous or non-porous adsorbents. J. Chim. Phys. Physico-Chim. Biol. 74, 179-182 (1977)
6. Hiemstra, T., Van Riemsdijk, W.H.: A surface structural approach to ion adsorption: The charge distribution model. J. Colloid Interface Sci. 179, 488-508 (1996)
7. Jolivet, J.P., Chaneac, C., Tronc, E.: Iron oxide chemistry. From molecular clusters to extended solid networks. Chem. Commun. 481-487 (2004)
8. Kargol, M., Zajac, J., Jones, D.J., Rozière, J.: Selectivity of gas phase adsorption of propene and propane onto mesoporous silica materials derivatised with Ag(I) and Cu(II) at low surface coverages: Comparison between equilibrium adsorption and flow microcalorimetry studies. Thermochim. Acta 434, 15-21 (2005)
9. Marrocchi, Y., Razafitianamaharavo, A., Michot, L.J., Marty, B.: Lowpressure adsorption of Ar, Kr, and Xe on carbonaceous materials (kerogen and carbon blacks), ferrihydrite, and montmorillonite: Implications for the trapping of noble gases onto meteoritic matter. Geochim. Cosmochim. Acta 69, 2419-2430 (2005)
10. Michot, L.J., Didier, F., Villieras, F., Cases, J.M.: Phenol adsorption on activated carbon studied by high resolution argon adsorption and controlled transformation rate thermal analysis. Pol. J. Chem. 71, 665-678 (1997)
11. Michot, L., François,M., Cases, J.M.: Surface heterogeneity studied by a quasi-equilibrium gas adsorption procedure. Langmuir 6, 677-681 (1990)
12. Morterra, C., Chiorino, A., Borello, E.: An IR spectroscopic characterization of alpha-FeOOH (goethite). Mater. Chem. Phys. 10, 119-138 (1984a)
13. Morterra, C., Mirra, C., Borello, E.: IR Spectroscopic study of pyridine adsorption onto alpha-FeOOH (goethite). Mater. Chem. Phys. 10, 139-154 (1984b)
14. Prélot, B., Lantenois, S., Nedellec, Y., Lindheimer, M., Douillard, J.- M., Zajac, J.: The difference between the surface reactivity of amorphous silica in the gas and liquid phase due to material porosity. Colloids Surf. A, Physicochem. Eng. Asp. 355, 67-74 (2010)
15. Prélot, B., Villiéras, F., Pelletier, M., Gerard, G., Gaboriaud, F., Ehrhardt, J.J., Perrone, J., Fedoroff, M., Jeanjean, J., Lefevre, G., Mazerolles, L., Pastol, J.L., Rouchaud, J.C., Lindecker, C.: Morphology and surface heterogeneities in synthetic goethites. J. Colloid Interface Sci. 261, 244-254 (2003)
16. Rouquerol, J., Rouquerol, F., Grillet, Y., Ward, R.J.: In: Hunger, K.K. (ed.) Characterization of Porous Solids, p. 67. Elsevier, Amsterdam (1988)
17. Schwertmann, U., Cambier, P., Murad, E.: Clays Clay Miner. 33, 369 (1985)
18. Schwertmann, U., Cornell, R.M.: Iron Oxides in the Laboratory: Preparation and Characterization, p. 137. VCH, Weinheim (1991)
19. Schwertmann, U., Taylor, R.M.: In: Dixon, J.B., Weed, S.B. (eds.) Minerals in Soil Environment, pp. 379-438. Soil Science Society of America, Madison (1989)
20. Villiéras, F., Cases, J.M., François, M., Michot, L.J., Thomas, F.: Texture and surface energetic heterogeneity of solids from modeling of low pressure gas adsorption isotherms. Langmuir 8, 1789-1795 (1992)
21. Villiéras, F., Chamerois, M., Bardot, F., Michot, L.J.: Evaluation of wetting properties of powders from low pressure gas adsorption experiments. Contact Angle Wettability Adhes. 2, 435-447 (2002a)
22. Villiéras, F., Chamerois, M., Yvon, J., Cases, J.M.: Surface heterogeneity at the solid-gas interface of hydrophilic solids modified by water-repellent molecules. Adsorpt. Sci. Technol. 25, 561-571 (2007)
23. Villiéras, F., Michot, L.J., Bardot, F., Cases, J.M., François, M., Rudzinski, W.: An improved derivative isotherm summation method to study surface heterogeneity of clay minerals. Langmuir 13, 1104-1117 (1997a)
24. Villiéras, F., Michot, L.J., Bardot, F., Chamerois, M., Eypert-Blaison, C., Francois, M., Gerard, G., Cases, J.-M.: Surface heterogeneity ofminerals. C. R. Geosci. 334, 597-609 (2002b)
25. Villiéras, F., Michot, L.J., Bernardy, E., Chamerois, M., Legens, C., Gerard, G., Cases, J.M.: Assessment of surface heterogeneity of calcite and apatite: From high resolution gas adsorption to the solid-liquid interface. Colloids Surf. A, Physicochem. Eng. Asp. 146, 163-174 (1999)
26. Villiéras, F., Michot, L.J., Cases, J.M., Berend, I., Bardot, F., François, M., Gérard, G., Yvon, J.: Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces. Elsevier, Amsterdam (1997b)
27. Weidler, P.G., Hug, S.J., Wetche, T.P., Hiemstra, T.: Determination of growth rates of (100) and (110) faces of synthetic goethite by scanning force microscopy. Geochim. Cosmochim. Acta 62, 3407-3412 (1998)
28. Ying, J.: NanostructuredMaterials. Academic Press, New York (2001)
29. Zajac, J., Dutartre, R., Jones, D.J., Roziere, J.: Determination of surface acidity of powdered porous materials based on ammonia chemisorption: Comparison of flow-microcalorimetry with batch volumetric method and temperature-programmed desorption. Thermochim. Acta 379, 123-130 (2001)
30. 2: general considerations for the identification of acid sites on surfaces of finely divided metal oxides. Colloid Surf. A, Physicochem. Eng. Asp. 190, 261-274 (2001)