Mesoporous Ti-KIT-6 molecular sieves: Their catalytic activity in the epoxidation of cyclohexene

Journal of the Taiwan Institute of Chemical Engineers

Volumn 41, Issue 6, 2010, Pages 670-675

  Kumaresan, L ^a   Prabhu, A ^a   Palanichamy, M ^a   Murugesan, V ^a  

^a ANNA UNIVERSITY   (India)

Author keywords

Cyclohexene oxide; Epoxidation of cyclohexene; Mesoporous molecular sieves; TBHP; Ti KIT 6

Indexed keywords

BET SURFACE AREA; CATALYTIC ACTIVITY; CYCLOHEXENE OXIDE; CYCLOHEXENES; HIGHER YIELD; HYDROTHERMALLY; MESOPOROUS; MESOPOROUS MOLECULAR SIEVES; ORDERED ARRANGEMENT; PLURONICS; POROUS NETWORKS; SEM; SOLVENT POLARITY; TBHP; TEM; TEM IMAGES; TERT-BUTYLHYDROPEROXIDE; TI-KIT-6; TIO; TRIBLOCK COPOLYMERS; UV-VIS-DRS; XRD;

BLOCK COPOLYMERS; CATALYST ACTIVITY; ELECTROCHEMICAL SENSORS; MESOPOROUS MATERIALS; MOLECULAR SIEVES; SIEVES; SOLVENTS; SORBENTS; TITANIUM;

OLEFINS;

EID: 78649442776     PISSN: 18761070     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jtice.2010.02.004     Document Type: Article

References (33)

1. Berube F., Kleitz F., Kaliaguine S. A Comprehensive Study of Titanium-Substituted SBA-15 Mesoporous Materials Prepared by Direct Synthesis. J. Phys. Chem. C 2008, 112:14403.
2. Blasco T., Corma A., Navarro N.T., Pariente J.P. Synthesis, Characterization and Catalytic Activity of Ti-MCM-41 Structures. J. Catal. 1995, 156:65.
3. Camblor M.A., Corma A., Martínez A., Pariente J.P. Synthesis of a Titaniumsilicoaluminate Isomorphous to Zeolite Beta and its Application as a Catalyst for the Selective Oxidation of Large Organic Molecules. J. Chem. Soc. Chem. Commun. 1992, 589.
4. Chen Y., Huang Y., Xiu J., Han X., Bao X. Direct Synthesis, Characterization and Catalytic Activity of Titanium-Substituted SBA-15 Mesoporous Molecular Sieves. Appl. Catal. A: Gen. 2004, 273:185.
5. Corma A., Esteve I.P., Martinez A. Solvent Effects during the Oxidation of Olefins and Alcohols with Hydrogen Peroxide on Ti-Beta Catalyst: The Influence of the Hydrophilicity-Hydrophobicity of the Zeolite. J. Catal. 1996, 161:11.
6. Dubey A., Choi M., Ryoo R. Mesoporous Polymer-Silica Catalysts for Selective Hydroxylation of Phenol. Green Chem. 2006, 8:144.
7. Fraile J.M., Garcia J.I., Mayoral J.A., Vispe E. Optimization of Cyclohexene Epoxidation with Dilute Hydrogen Peroxide and Silica-Supported Titanium Catalysts. Appl. Catal. A: Gen. 2003, 245:363.
8. Galacho C., Ribeiro Carrott M.M.L., Carrott P.J.M. Structural and Catalytic Properties of Ti-MCM-41 Synthesized at Room Temperature up to High Ti Content. Micropor. Mesopor. Mater. 2007, 100:312.
9. Gierszal K.P., Kim T.W., Ryoo R., Jaroniec M. Adsorption and Structural Properties of Ordered Mesoporous Carbons Synthesized by Using Various Carbon Precursors and Ordered Siliceous P6mm and Ia3d Mesostructures as Templates. J. Phys. Chem. B 2005, 109:23263.
10. Hall, J. B. and W. J. Weiger, "Cyclohexane Diol Composition," US Patent 4, 061, 686 (1977).
11. Haskouri J.E., Cabrera S., Gutierrez M., Beltran-Porter A., Beltran-Porter D., Marcos M.D., Amoros P. Very high Titanium Content Mesoporous Silicas. Chem. Commun. 2001, 309.
12. 2 over Ti-Containing Molecular Sieves with MFI, BEA and MCM-41 Topologies. Appl. Catal. A: Gen. 2004, 277:99.
13. Kim T.W., Kleitz F., Paul B., Ryoo R. Controlled Polymerization in Mesoporous Silica toward the Design of Organic-Inorganic Composite Nanoporous Materials. J. Am. Chem. Soc. 2005, 127:7601.
14. Kleitz F., Choi S.H., Ryoo R. Cubic Ia3d Large Mesoporous Silica: Synthesis and Replication to Platinum Nanowires, Carbon Nanorods and Carbon Nanotubes. Chem. Commun. 2003, 2136.
15. 2 Mixed Oxides for the Epoxidation of Cyclohexene. J. Catal. 1997, 171:420.
16. Li K.T., Lin C.C. Propylene Epoxidation over Ti/MCM-41 Catalysts Prepared by Chemical Vapor Deposition. Catal. Today 2004, 97:257.
17. Lin K., Pescarmona P.P., Vandepitte H., Liang D., Tendeloo G.V., Jacobs P.A. Synthesis and Catalytic Activity of Ti-MCM-41 Nanoparticles with Highly Active Titanium Sites. J. Catal. 2008, 254:64.
18. Morey M.S., O'Brien S., Schwarz S., Stucky G.D. Hydrothermal and Postsynthesis Surface Modification of Cubic, MCM-48, and Ultralarge Pore SBA-15 Mesoporous Silica with Titanium. Chem. Mater. 2000, 12:898.
19. Newalkar B.L., Olanrewaju J., Komarneni S. Direct Synthesis of Titanium-Substituted Mesoporous SBA-15 Molecular Sieve under Microwave-Hydrothermal Conditions. Chem. Mater. 2001, 13:552.
20. Oye G., Glomm W.R., Vralstad T., Volden S., Magnusson H., Stocker M., Sjoblom J. Synthesis, Functionalisation and Characterisation of Mesoporous Materials and Sol-Gel Glasses for Applications in Catalysis, Adsorption and Photonics. Adv. Colloid Interface Sci. 2006, 123-126:17.
21. Prasad M.R., Madhavi G., Rao A.R., Kulkarni S.J., Raghavan K.V. Synthesis Characterization of High Ti-Containing Ti-MCM-41 Catalysts and their Activity Evaluation in Oxidation of Cyclohexene and Epoxidation of Higher Olefins. J. Porous Mater. 2006, 13:81.
22. Prokhorov A., Bris N.L., Bernard H., Claudon G., Handel H. Cyclohexanedione Bisaminals as Intermediates for Cyclen, Homocyclen, and Cyclam Synthesis. Syn. Commun. 2006, 36:3271.
23. Ratnasamy P., Srinivas D., Knozinger H. Active Sites and Reactive Intermediates in Titanium Silicate Molecular Sieves. Adv. Catal. 2004, 48:1.
24. Sanchez M.C.C., Martin J.M.C., Fierro J.L.G., de Frutos M.P., Polo A.P. Effective Alkene Epoxidation with Dilute Hydrogen Peroxide on Amorphous Silica-Supported Titanium Catalysts. Chem. Commun. 2000, 855.
25. Sayari A. Catalysis by Crystalline Mesoporous Molecular Sieves. Chem. Mater. 1996, 8:1840.
26. Thangaraj A., Kumar R., Mirajkar S.P., Ratnasamy P. Catalytic Properties of Crystalline Titanium Silicalites. I. Synthesis and Characterization of Titanium-Rich Zeolites with MFI Structure. J. Catal. 1991, 130:1.
27. Vinu A., Srinivasu P., Sawant D.P., Alam S., Mori T., Ariga K., Balasubramanian V.V., Anand C. Fabrication and Morphological Control of Three-Dimensional Cage Type Mesoporous Titanosilicate with Extremely High Ti Content. Micropor. Mesopor. Mater. 2008, 110:422.
28. Wiberg K.B. Oxidation in Organic Chemistry 1965, Academic Press, New York.
29. Wu S., Han Y., Zou Y.C., Song J.W., Zhao L., Di Y., Liu S.Z., Xiao F.S. Synthesis of Heteroatom Substituted SBA-15 by the "pH-Adjusting" Method. Chem. Mater. 2004, 16:486.
30. Wu P., Tatsumi T. Postsynthesis, Characterization, and Catalytic Properties in Alkene Epoxidation of Hydrothermally Stable Mesoporous Ti-SBA-15. Chem. Mater. 2002, 14:1657.
31. Zepeda T.A., Fierro J.L.G., Pawelec B., Nava R., Klimova T., Fuentes G.A., Halachev T. Synthesis and Characterization of Ti-HMS and CoMo/Ti-HMS Oxide Materials with Varying Ti Content. Chem. Mater. 2005, 17:4062.
32. Zhang W.H., Lu J., Han B., Li M., Xiu J., Ying P., Li C. Direct Synthesis and Characterization of Titanium-Substituted Mesoporous Molecular Sieve SBA-15. Chem. Mater. 2002, 14:3413.
33. Zhang W., Wang J., Tanev P.T., Pinnavaia T.J. Catalytic Hydroxylation of Benzene over Transition-Metal Substituted Hexagonal Mesoporous Silicas. Chem. Commun. 1996, 979.