C-H bond activation of N-heterocyclic carbene IMes by rare-earth metal alkyl complexes

Journal of Organometallic Chemistry

Volumn 695, Issue 25-26, 2010, Pages 2794-2797

  Fegler, Waldemar ^a   Saito, Teruhiko ^b   Mashima, Kazushi ^b   Spaniol, Thomas P ^a   Okuda, Jun ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

C H bond activation; Metal alkyl; Rare earth metal; Stable carbene

Indexed keywords

ALKYL COMPLEXES; CARBENES; CH-BOND ACTIVATION; CHELATE LIGANDS; DISTORTED TRIGONAL BIPYRAMID; IMIDAZOL-2-YLIDENE; MESITYL SUBSTITUENTS; METHYL GROUP; N-HETEROCYCLIC CARBENES; RARE-EARTH METALS;

ALKYLATION; CARBON INORGANIC COMPOUNDS; FUNCTIONAL GROUPS; LIGANDS; METAL COMPLEXES; TOLUENE;

METALS;

EID: 78649322677     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2010.08.021     Document Type: Article

References (38)

1. H. Schumann, D.M.M. Freckmann, S. Schutte, S. Dechert, and M. Hummert Z. Anorg. Allg. Chem. 633 2007 888 892
2. P.L. Arnold, S.A. Mungur, A.J. Blake, and C. Wilson Angew. Chem. Int. Ed. 42 2003 5981 5984
3. S.T. Liddle, and P.L. Arnold Organometallics 24 2005 2597 2605
4. I.J. Casely, S.T. Liddle, A.J. Blake, C. Wilson, and P.L. Arnold Chem. Commun. 2007 5037 5039
5. P.L. Arnold, S.T. Liddle, J. McMaster, C. Jones, and D.P. Mills J. Am. Chem. Soc. 129 2007 5360 5361
6. P.L. Arnold, I.J. Casely, Z.R. Turner, and C.D. Carmichael Chem.-Eur. J. 14 2008 10415 10422
7. P.L. Arnold, I.J. Casely, S. Zlatogorsky, and C. Wilson Helv. Chim. Acta 92 2009 2291 2303
8. Z.-G. Wang, H.-M. Sun, H.-S. Yao, Q. Shen, and Y. Zhang Organometallics 25 2006 4436 4438
9. Z.-G. Wang, H.-M. Sun, H.-S. Yao, Y.-M. Yao, Q. Shen, and Y. Zhang J. Organomet. Chem. 691 2006 3383 3390
10. B.L. Wang, D. Wang, D.M. Cui, W. Gao, T. Tang, X.S. Chen, and X.B. Jing Organometallics 26 2007 3167 3172
11. B.L. Wang, D.M. Cui, and K. Lv Macromolecules 41 2008 1983 1988
12. H.S. Yao, Y. Zhang, H.M. Sun, and Q. Shen Eur. J. Inorg. Chem. 2009 1920 1925
13. R.H. Crabtree J. Organomet. Chem. 690 2005 5451 5457
14. W.A. Herrmann, and C. Köcher Angew. Chem. Int. Ed. Engl. 36 1997 2162 2187
15. W.A. Herrmann Angew. Chem. Int. Ed. 41 2002 1290 1309
16. F.E. Hahn, M.C. Jahnke, Angew. Chem., Int. Ed. 47 (2008) 3122-3172;
17. S. Díez-González, N. Marion, and S.P. Nolan Chem. Rev. 109 2009 3612 3676
18. K.C. Hultzsch, T.P. Spaniol, and J. Okuda Angew. Chem. Int. Ed. 38 1999 227 230
19. S. Arndt, P. Voth, T.P. Spaniol, and J. Okuda Organometallics 19 2000 4690 4700
20. S. Arndt, K. Beckerle, K.C. Hultzsch, P.-J. Sinnema, P. Voth, T.P. Spaniol, and J. Okuda J. Mol. Catal. A: Chem. 190 2002 215 223
21. K.C. Hultzsch, P. Voth, T.P. Spaniol, and J. Okuda Z. Anorg. Allg. Chem. 629 2003 1272 1276
22. M. Konkol, T.P. Spaniol, M. Kondracka, and J. Okuda Dalton Trans. 2007 4095 4102
23. M. Ohashi, M. Konkol, I. Del Rosal, R. Poteau, L. Maron, and J. Okuda J. Am. Chem. Soc. 130 2008 6920 6921
24. for reviews see:
25. J. Okuda Dalton Trans. 2003 2367 2378
26. M. Konkol, and J. Okuda Coord. Chem. Rev. 252 2008 1577 1591
27. M. Nishiura, and Z. Hou Nat. Chem. 2 2010 257 268
28. W. Fegler, T.P. Spaniol, and J. Okuda Dalton Trans. 39 2010 6774 6779
29. R. Shannon Acta Crystallogr. A32 1976 751 767
30. J.W. Connolly, and G. Urry Inorg. Chem. 2 1963 645 646
31. M.F. Lappert, and R. Pearce J. Chem. Soc. Chem. Commun. 1973 126
32. H. Schumann, D.M.M. Freckmann, and S. Dechert Z. Anorg. Allg. Chem. 628 2002 2422 2426
33. L. Hintermann Beilstein J. Org. Chem. 3 2007 22
34. A.L. Spek Acta Crystallogr. A46 1990 C34
35. A.L. Spek J. Appl. Crystallogr. 36 2003 7 13
36. A. Altomare, G. Cascarano, C. Giacovazzo, and A. Guagliardi J. Appl. Crystallogr. 26 1993 343 350
37. G.M. Sheldrick Acta Crystallogr A64 2008 112 122
38. L.J. Farrugia J. Appl. Crystallogr. 32 1999 837 838