Study of analyte dissociation and diffusion in laser-induced plasmas: Implications for laser-induced breakdown spectroscopy

Journal of Analytical Atomic Spectrometry

Volumn 25, Issue 12, 2010, Pages 1921-1930

  Diwakar, Prasoon K ^a   Groh, Sebastian ^b   Niemax, Kay ^c   Hahn, David W ^a  

^a UNIVERSITY OF FLORIDA   (United States)

^b LEIBNIZ INSTITUT FÜR ANALYTISCHE WISSENSCHAFTEN ISAS E V   (Germany)

^c BAM FEDERAL INSTITUTE FOR MATERIALS RESEARCH AND TESTING   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ANALYTE CONCENTRATION; ANALYTE SIGNALS; ANALYTES; ANALYTICAL TREATMENT; ATOMIC DIFFUSIONS; ATOMIC EMISSION; DATA SUPPORT; DESOLVATION; DIFFUSION COEFFICIENTS; DIRECT ASSESSMENT; DIRECT IMAGING; EMISSION DATA; EMISSION RATIO; EXCITATION TEMPERATURE; FINITE TIME; HEAT AND MASS TRANSFER; HYDROGEN ATOMS; LASER INDUCED PLASMA; MICRO DROPLETS; ORDER OF MAGNITUDE; PLASMA CONDITIONS; PLASMA-PARTICLE INTERACTION; RESIDENCE TIME; SURFACE SOURCES;

ATOMIC EMISSION SPECTROSCOPY; ATOMIC SPECTROSCOPY; CALCIUM; DESORPTION; DIFFUSION IN SOLIDS; HYDROGEN; LASER PRODUCED PLASMAS; MASS TRANSFER; PLASMA THEORY; SPECTROSCOPIC ANALYSIS;

ATOMS;

EID: 78649294098     PISSN: 02679477     EISSN: 13645544     Source Type: Journal    
DOI: 10.1039/c0ja00063a     Document Type: Article

References (38)

1. S. Yalcin D. R. Crosley G. P. Smith G. W. Faris Spectroscopic characterization of laser-produced plasma for in situ toxic metal monitoring Hazard. Wastes Hazard. Mater. 1996 13 51 61
2. J. E. Carranza B. T. Fisher G. D. Yoder D. W. Hahn Online analysis of ambient air particles using laser-induced breakdown spectroscopy Spectrochim. Acta, Part B 2001 56 851 864
3. R. Noll H. Bette A. Brysch M. Kraushaar I. Mönch L. Peter V. Sturm Laser-induced breakdown spectrometry - applications for production control and quality assurance in steel industry Spectrochim. Acta, Part B 2001 56 637 649
4. S. Palanco C. L. Moreno J. J. Laserna Design, construction and assessment of a field-deployable laser-induced breakdown spectrometer for remote elemental sensing Spectrochim. Acta, Part B 2006 61 88 95
5. A. Giakoumaki K. Melessanaki D. Anglos Laser-induced breakdown spectroscopy (LIBS) in archaeological science - applications and prospects Anal. Bioanal. Chem. 2007 387 749 760
6. J. Diedrich S. J. Rehse Escherichia coli identification and strain discrimination using nanosecond laser-induced breakdown spectroscopy Appl. Phys. Lett. 2007 90 163901
7. A. K. Knight N. L. Scherbarth D. A. Cremers M. J. Ferris Characterization of laser-induced breakdown spectroscopy (LIBS) for application to space exploration Appl. Spectrosc. 2000 54 331 459
8. F. Colao R. Fantoni V. Lazic A. Paolini F. Fabbri G. G. Ori L. Marinangeli A. Baliva Investigation of LIBS feasibility for in situ planetary exploration: an analysis on Martian rock analogues Planet. Space Sci. 2004 52 117 123
9. D. W. Hahn Laser-induced breakdown spectroscopy for analysis of aerosol particles: the path toward quantitative analysis Spectroscopy 2009 24 26 33
10. V. Hohreiter D. W. Hahn Plasma-particle interactions in a laser-induced plasma: implications for laser-induced breakdown spectroscopy Anal. Chem. 2006 78 1509 1514
11. P. K. Diwakar P. B. Jackson D. W. Hahn Investigation of multi-component aerosol particles and the effect on quantitative laser-induced breakdown spectroscopy: consideration of localized matrix effects Spectrochim. Acta, Part B 2007 62 1466 1474
12. G. Cristoforreti A. D. Giacomo M. Dell'Agillo S. Legnaioli E. Tognoni V. Palleschi N. Omenetto Local thermodynamic equilibrium in laser-induced breakdown spectroscopy: beyond the McWhirter criterion Spectrochim. Acta, Part B 2010 65 86 95
13. H. W. Drawin Validity conditions for local thermodynamic equilibrium Z. Phys. 1969 228 99 119
14. M. P. Dziewatkoski L. B. Daniels J. W. Olesik Time-resolved inductively coupled plasma mass spectrometry measurements with individual, monodisperse drop sample introduction Anal. Chem. 1996 68 1101 1109
15. C. B. Boss G. M. Hieftje Experimental studies on spatial distributions of atoms surrounding an individual solute particle vaporizing in an analytical flame Anal. Chem. 1979 51 1897 1905
16. S. Chapman and T. G. Cowling, The Mathematical Theory of Non-Uniform Gases, Cambridge University Press, 1939
17. J. O. Hirschefelder, C. F. Curtiss and R. B. Bird, Molecular Theory of Gases and Liquids, Wiley, New York, 2nd edn, 1954
18. A. B. Murphy Diffusion in equilibrium mixtures of ionized gases Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top. 1993 48 3594 3603
19. A. B. Murphy A comparison of treatments of diffusion in thermal plasmas J. Phys. D: Appl. Phys. 1996 29 1922 1932
20. A. B. Murphy Transport coefficients of hydrogen and argon-hydrogen plasmas Plasma Chem. Plasma Process. 2000 20 279 297
21. V. Rat P. Andre J. Aubreton M. F. Elchinger P. Fauchais A. Lefort Transport properties in a two-temperature plasma: theory and application Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys. 2001 64 026409
22. R. S. Devoto Transport coefficients of partially ionized argon Phys. Fluids 1967 10 354 364
23. V. Colombo E. Ghedini P. Sanibondi Two-temperature thermodynamic and transport properties of argon-hydrogen and nitrogen-hydrogen plasmas J. Phys. D: Appl. Phys. 2009 42 1 12
24. A. Ashkin J. M. Dziedzic J. E. Bjorkholm S. Chu Observation of a single-beam gradient force optical trap for dielectric particles Opt. Lett. 1986 11 5 288 290
25. A. Ashkin History of optical trapping and manipulation of small-neutral particle, atoms, and molecules IEEE J. Sel. Top. Quantum Electron. 2000 6 6 841 856
26. D. R. Burnham D. McGloin Holographic optical trapping of aerosol droplets Opt. Express 2006 9 4175 4181
27. C. Janzen R. Fleige R. Noll H. Schwenke W. Lahmann J. Knoth P. Beaven E. Jantzen A. Oest P. Koke Analysis of small droplets with a new detector for liquid chromatography based on laser-induced breakdown spectroscopy Spectrochim. Acta, Part B 2005 60 993 1001
28. S. Groh P. K. Diwakar C. C. Garcia A. Murtazin D. W. Hahn K. Niemax 100% Efficient sub-nanoliter sample introduction in laser-induced breakdown spectroscopy and inductively coupled plasma spectrometry: implications for ultralow sample volumes Anal. Chem. 2010 82 2568 2573
29. J. W. Olesik Investigating the fate of individual sample droplets in inductively coupled plasmas Appl. Spectrosc. 1997 51 158A 175A
30. J. W. Olesik J. A. Kinzer G. J. McGowan Observation of atom and ion clouds produced from single droplets of sample in inductively coupled plasmas by optical emission and laser-induced fluorescence imaging Appl. Spectrosc. 1997 51 607 616
31. G. M. Hieftje R. M. Miller Y. Pak E. P. Wittig Theoretical examination of solute particle vaporization in analytical atomic spectrometry Anal. Chem. 1987 59 2861 2872
32. S. Groh C. C. Garcia A. Murtazin V. Horvatic K. Niemax Local effects of atomizing analyte droplets on the plasma parameters of the inductively coupled plasma Spectrochim. Acta, Part B 2009 64 247 254
33. P. S. Dalyander I. B. Gornushkin D. W. Hahn Numerical simulation of laser-induced breakdown spectroscopy: modeling of aerosol analysis with finite diffusion and vaporization effects Spectrochim. Acta, Part B 2008 63 293 304
34. R. A. Svehla Estimated viscosities and thermal conductivities of gases at high temperatures NASA Tech. Rep. 1962 R-132
35. 2 interaction energies, transport cross-sections, and collision integrals J. Chem. Phys. 1992 97 3431 3436
36. J. R. Stallcop C. W. Bauschilicher, Jr H. Patridge Theoretical study of hydrogen and nitrogen interactions: N-H transport cross-sections and collisions integrals J. Chem. Phys. 1992 97 5578 5585
37. P. K. Diwakar D. W. Hahn Study of early laser-induced plasma dynamics: transient electron density gradients via Thomson scattering and stark broadening, and the implications on LIBS measurements Spectrochim. Acta, Part B 2008 63 1038 1046
38. C. J. Cremers R. C. Birkebak Application of the Abel integral equation to spectrographic data Appl. Opt. 1966 5 1057 1064