-
3
-
-
0035470233
-
-
Demadis, K. D.; Hartshorn, C. M.; Meyer, T. J. Chem. Rev. 2001, 101, 2655-2686.
-
(2001)
Chem. Rev.
, vol.101
, pp. 2655-2686
-
-
Demadis, K.D.1
Hartshorn, C.M.2
Meyer, T.J.3
-
8
-
-
0000014191
-
-
Goldberg, D. P.; Caneschi, A.; Delfs, C. D.; Sessoli, R.; Lippard, S. J. J. Am. Chem. Soc. 1995, 117, 5789-5800.
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 5789-5800
-
-
Goldberg, D.P.1
Caneschi, A.2
Delfs, C.D.3
Sessoli, R.4
Lippard, S.J.5
-
9
-
-
65349120053
-
-
Miyasaka, H.; Julve, M.; Yamashita, M.; Clérac, R. Inorg. Chem. 2009, 48, 3420-3437.
-
(2009)
Inorg. Chem.
, vol.48
, pp. 3420-3437
-
-
Miyasaka, H.1
Julve, M.2
Yamashita, M.3
Clérac, R.4
-
10
-
-
33646087213
-
-
Toma, L. M.; Lescouezec, R.; Pasan, J.; Ruiz-Perez, C.; Vaissermann, J.; Cano, J.; Carrasco, R.; Wernsdorfer, W.; Lloret, F.; Julve, M. J. Am. Chem. Soc. 2006, 128, 4842-4853.
-
(2006)
J. Am. Chem. Soc.
, vol.128
, pp. 4842-4853
-
-
Toma, L.M.1
Lescouezec, R.2
Pasan, J.3
Ruiz-Perez, C.4
Vaissermann, J.5
Cano, J.6
Carrasco, R.7
Wernsdorfer, W.8
Lloret, F.9
Julve, M.10
-
11
-
-
0037014702
-
-
Sokol, J. J.; Hee, A. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 7656-7657.
-
(2002)
J. Am. Chem. Soc.
, vol.124
, pp. 7656-7657
-
-
Sokol, J.J.1
Hee, A.G.2
Long, J.R.3
-
12
-
-
0029485221
-
-
Entley, W. R.; Treadway, C. R.; Girolami, G S. Mol. Cryst. Liq. Cryst. Sci. Tech. 1995, 273, 153-166.
-
(1995)
Mol. Cryst. Liq. Cryst. Sci. Tech
, vol.273
, pp. 153-166
-
-
Entley, W.R.1
Treadway, C.R.2
Girolami, G.S.3
-
13
-
-
0037418999
-
-
Berlinguette, C. P.; Vaughn, D.; Cañada-Vilalta, C.; Galán-Mascarós, J. R.; Dunbar, K. R. Angew. Chem., Int. Ed. 2003, 42, 1523-1526.
-
(2003)
Angew. Chem., Int. Ed.
, vol.42
, pp. 1523-1526
-
-
Berlinguette, C.P.1
Vaughn, D.2
Cañada-Vilalta, C.3
Galán- Mascarós, J.R.4
Dunbar, K.R.5
-
14
-
-
33645471107
-
-
Li, D.; Parkin, S.; Wang, G.; Yee, G T.; Clérac, R.; Wernsdorfer, W.; Holmes, S. M. J. Am. Chem. Soc. 2006, 128, 4214-4215.
-
(2006)
J. Am. Chem. Soc.
, vol.128
, pp. 4214-4215
-
-
Li, D.1
Parkin, S.2
Wang, G.3
Yee, G.T.4
Clérac, R.5
Wernsdorfer, W.6
Holmes, S.M.7
-
16
-
-
0001548351
-
-
Richardson, D. E.; Sen, J. P.; Buhr, J. D.; Taube, H. Inorg. Chem. 1982, 21, 3136-3140.
-
(1982)
Inorg. Chem.
, vol.21
, pp. 3136-3140
-
-
Richardson, D.E.1
Sen, J.P.2
Buhr, J.D.3
Taube, H.4
-
17
-
-
0030662509
-
-
Ferguson, R.; Solari, E.; Floriani, C.; Osella, D.; Ravera, M.; Re, N.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1997, 119, 10104-10115.
-
(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 10104-10115
-
-
Ferguson, R.1
Solari, E.2
Floriani, C.3
Osella, D.4
Ravera, M.5
Re, N.6
Chiesi-Villa, A.7
Rizzoli, C.8
-
19
-
-
47749090588
-
-
Curley, J. J.; Cook, T. R.; Reece, S. Y.; Müller, P.; Cummins, C. C. J. Am. Chem. Soc. 2008, 130, 9394-9405.
-
(2008)
J. Am. Chem. Soc.
, vol.130
, pp. 9394-9405
-
-
Curley, J.J.1
Cook, T.R.2
Reece, S.Y.3
Müller, P.4
Cummins, C.C.5
-
20
-
-
67650468454
-
-
Ding, K.; Pierpont, A. W.; Brennessel, W. W.; Lukat-Rodgers, G.; Rodgers, K. R.; Cundari, T. R.; Bill, E.; Holland, P. L. J. Am. Chem. Soc. 2009, 131, 9471-9472.
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 9471-9472
-
-
Ding, K.1
Pierpont, A.W.2
Brennessel, W.W.3
Lukat-Rodgers, G.4
Rodgers, K.R.5
Cundari, T.R.6
Bill, E.7
Holland, P.L.8
-
21
-
-
31544454723
-
-
Smith, J. M.; Sadique, A. R.; Cundari, T. R.; Rodgers, K. R.; Lukat-Rodgers, G.; Lachicotte, R. J.; Flaschenriem, C. J.; Vela, J.; Holland, P. L. J. Am. Chem. Soc. 2006, 128, 756-769.
-
(2006)
J. Am. Chem. Soc.
, vol.128
, pp. 756-769
-
-
Smith, J.M.1
Sadique, A.R.2
Cundari, T.R.3
Rodgers, K.R.4
Lukat-Rodgers, G.5
Lachicotte, R.J.6
Flaschenriem, C.J.7
Vela, J.8
Holland, P.L.9
-
22
-
-
33746912338
-
-
Stoian, S. A.; Vela, J.; Smith, J. M.; Sadique, A. R.; Holland, P. L.; Münck, E.; Bominaar, E. L. J. Am. Chem. Soc. 2006, 128, 10181-10192.
-
(2006)
J. Am. Chem. Soc.
, vol.128
, pp. 10181-10192
-
-
Stoian, S.A.1
Vela, J.2
Smith, J.M.3
Sadique, A.R.4
Holland, P.L.5
Münck, E.6
Bominaar, E.L.7
-
24
-
-
70349786171
-
-
Pfirrmann, S.; Limberg, C.; Herwig, C.; Stösser, R.; Ziemer, B. Angew. Chem., Int. Ed. 2009, 48, 3357-3361.
-
(2009)
Angew. Chem., Int. Ed.
, vol.48
, pp. 3357-3361
-
-
Pfirrmann, S.1
Limberg, C.2
Herwig, C.3
Stösser, R.4
Ziemer, B.5
-
26
-
-
0000977192
-
-
Treitel, I. M.; Flood, M. T.; Marsh, R. E.; Gray, H. B. J. Am. Chem. Soc. 1969, 91, 6512-6513.
-
(1969)
J. Am. Chem. Soc.
, vol.91
, pp. 6512-6513
-
-
Treitel, I.M.1
Flood, M.T.2
Marsh, R.E.3
Gray, H.B.4
-
30
-
-
0039129526
-
-
Hart, J. R.; Rappé, A. K.; Gorun, S. M.; Upton, T. H. Inorg. Chem. 1992, 31, 5254-5259.
-
(1992)
Inorg. Chem.
, vol.31
, pp. 5254-5259
-
-
Hart, J.R.1
Rappé, A.K.2
Gorun, S.M.3
Upton, T.H.4
-
31
-
-
0000735317
-
-
Hart, J. R.; Rappé, A. K.; Gorun, S. M.; Upton, T. H. J. Phys. Chem. 1992, 96, 6255-6263.
-
(1992)
J. Phys. Chem.
, vol.96
, pp. 6255-6263
-
-
Hart, J.R.1
Rappé, A.K.2
Gorun, S.M.3
Upton, T.H.4
-
32
-
-
0000043234
-
-
Hart, J. R.; Rappé, A. K.; Gorun, S. M.; Upton, T. H. J. Phys. Chem. 1992, 96, 6264-6269.
-
(1992)
J. Phys. Chem.
, vol.96
, pp. 6264-6269
-
-
Hart, J.R.1
Rappé, A.K.2
Gorun, S.M.3
Upton, T.H.4
-
33
-
-
0000385349
-
-
Weyland, T.; Costuas, K.; Mari, A.; Halet, J. F.; Lapinte, C. Organometallics 1998, 17, 5569-5579.
-
(1998)
Organometallics
, vol.17
, pp. 5569-5579
-
-
Weyland, T.1
Costuas, K.2
Mari, A.3
Halet, J.F.4
Lapinte, C.5
-
34
-
-
0027912953
-
-
Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141-143.
-
(1993)
Nature
, vol.365
, pp. 141-143
-
-
Sessoli, R.1
Gatteschi, D.2
Caneschi, A.3
Novak, M.A.4
-
35
-
-
33947264083
-
-
Milios, C. J.; Vinslava, A.; Wernsdorfer, W.; Moggach, S.; Parsons, S.; Perlepes, S. P.; Christou, G.; Brechin, E. K. J. Am. Chem. Soc. 2007, 129, 2754-2755.
-
(2007)
J. Am. Chem. Soc.
, vol.129
, pp. 2754-2755
-
-
Milios, C.J.1
Vinslava, A.2
Wernsdorfer, W.3
Moggach, S.4
Parsons, S.5
Perlepes, S.P.6
Christou, G.7
Brechin, E.K.8
-
36
-
-
78649242100
-
-
Ph. D. Thesis, University of California, Berkeley, CA
-
Berben, L. A. Ph. D. Thesis, University of California, Berkeley, CA, 2005.
-
(2005)
-
-
Berben, L.A.1
-
37
-
-
51149221317
-
-
Girolami, G. S.; Wilkinson, G.; Galas, A. M. R.; Thorntonpett, M.; Hursthouse, M. B. J. Chem. Soc, Dalton Trans. 1985, 1339-1348.
-
(1985)
J. Chem. Soc, Dalton Trans.
, vol.1339-1348
-
-
Girolami, G.S.1
Wilkinson, G.2
Galas, A.M.R.3
Thorntonpett, M.4
Hursthouse, M.B.5
-
38
-
-
0041727780
-
-
Chávez, I.; Alvarez-Carena, A.; Molins, E.; Roig, A.; Maniukiewicz, W.; Arancibia, A.; Arancibia, V.; Brand, H.; Manríquez, J. M. J. Organomet. Chem. 2000, 601, 126-132.
-
(2000)
J. Organomet. Chem.
, vol.601
, pp. 126-132
-
-
Chávez, I.1
Alvarez-Carena, A.2
Molins, E.3
Roig, A.4
Maniukiewicz, W.5
Arancibia, A.6
Arancibia, V.7
Brand, H.8
Manríquez, J.M.9
-
39
-
-
78649255876
-
-
Bruker Analytical X-Ray Systems, Inc.: Madison, WI
-
APEX 2; Bruker Analytical X-Ray Systems, Inc.: Madison, WI, 2008.
-
(2008)
APEX
, vol.2
-
-
-
40
-
-
0004150157
-
-
Bruker Analytical X-Ray Systems, Inc.: Madison, WI
-
Sheldrick, G. M. SHELXTL; Bruker Analytical X-Ray Systems, Inc.: Madison, WI, 1999.
-
(1999)
SHELXTL
-
-
Sheldrick, G.M.1
-
41
-
-
72949093493
-
-
1.41; Max Planck Institute for Bioinorganic Chemistry: Mülheim an der Ruhr, Germany
-
Bill, E. julX, 1.41; Max Planck Institute for Bioinorganic Chemistry: Mülheim an der Ruhr, Germany, 2008 (http://ewww.mpi-muelheim.mpg.de/bac/ logins/bill/julX-en. php).
-
(2008)
JulX
-
-
Bill, E.1
-
42
-
-
0037070559
-
-
Shores, M. P.; Sokol, J. J.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2279-2292.
-
(2002)
J. Am. Chem. Soc.
, vol.124
, pp. 2279-2292
-
-
Shores, M.P.1
Sokol, J.J.2
Long, J.R.3
-
44
-
-
34047220803
-
-
Gaussian, Inc.: Wallingford, CT
-
Frisch, M. J. et al. Gaussian 03; Gaussian, Inc.: Wallingford, CT, 2004.
-
(2004)
Gaussian
, vol.3
-
-
Frisch, M.J.1
-
46
-
-
36849115659
-
-
Ditchfield, R.; Hehre, W. J.; Pople, J. A. J. Chem. Phys. 1971, 54, 724.
-
(1971)
J. Chem. Phys.
, vol.54
, pp. 724
-
-
Ditchfield, R.1
Hehre, W.J.2
Pople, J.A.3
-
47
-
-
0347170005
-
-
Hehre, W. J.; Ditchfield, R.; Pople, J. A. J. Chem. Phys. 1972, 56, 2257.
-
(1972)
J. Chem. Phys.
, vol.56
, pp. 2257
-
-
Hehre, W.J.1
Ditchfield, R.2
Pople, J.A.3
-
48
-
-
2442617487
-
-
Binkley, J. S.; Pople, J. A.; Hehre, W. J. J. Am. Chem. Soc. 1980, 102, 939.
-
(1980)
J. Am. Chem. Soc.
, vol.102
, pp. 939
-
-
Binkley, J.S.1
Pople, J.A.2
Hehre, W.J.3
-
49
-
-
33645949559
-
-
Francl, M. M.; Pietro, W. J.; Hehre, W. J.; Binkley, J. S.; Gordon, M. S.; DeFrees, D. J.; Pople, J. A. J. Chem. Phys. 1982, 77, 3654.
-
(1982)
J. Chem. Phys.
, vol.77
, pp. 3654
-
-
Francl, M.M.1
Pietro, W.J.2
Hehre, W.J.3
Binkley, J.S.4
Gordon, M.S.5
DeFrees, D.J.6
Pople, J.A.7
-
50
-
-
78649234140
-
-
ORCA is a modern electronic structure program package written by F. Neese, with contributions from
-
ORCA is a modern electronic structure program package written by F. Neese, with contributions from Becker, U.; Ganiouchine, D.; Kossmann, S.; Petrenko, T.; Riplinger, C.; Wennmohs, F.;.
-
-
-
Becker, U.1
Ganiouchine, D.2
Kossmann, S.3
Petrenko, T.4
Riplinger, C.5
Wennmohs, F.6
-
51
-
-
78649249108
-
-
Ahlrichs DZ basis set was obtained from the TurboMole basis set library under ftp.chemie.unikarlsruhe.de/pub/basen
-
The Ahlrichs DZ basis set was obtained from the TurboMole basis set library under ftp.chemie.unikarlsruhe.de/pub/basen.
-
-
-
-
52
-
-
67651233408
-
-
Lopez-Herdandez, A.; Venkatesan, K.; Schmalle, H. W.; Berke, H. Monatsh. Chem. 2009, 140, 845-857.
-
(2009)
Monatsh. Chem.
, vol.140
, pp. 845-857
-
-
Lopez-Herdandez, A.1
Venkatesan, K.2
Schmalle, H.W.3
Berke, H.4
-
53
-
-
78649258038
-
-
F can be isolated. Details concerning the reactivity of these species are under investigation
-
F) can be isolated. Details concerning the reactivity of these species are under investigation.
-
-
-
-
56
-
-
78649242512
-
-
Attempts to collect Raman spectra of 3 have been thwarted by the propensity of 3 to undergo a reversible reaction upon irradiation with the 1064 nm incident laser. Dark green ethereal solutions of 3 turn golden brown upon insertion into the path of the laser; removal prompts the dark green color to reappear. We tentatively attribute this reactivity to reversible coordination of dinitrogen
-
Attempts to collect Raman spectra of 3 have been thwarted by the propensity of 3 to undergo a reversible reaction upon irradiation with the 1064 nm incident laser. Dark green ethereal solutions of 3 turn golden brown upon insertion into the path of the laser; removal prompts the dark green color to reappear. We tentatively attribute this reactivity to reversible coordination of dinitrogen.
-
-
-
-
58
-
-
51149207033
-
-
Salt, J. E.; Wilkinson, G.; Motevalli, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1986, 1141-1154.
-
(1986)
J. Chem. Soc., Dalton Trans.
, vol.1141-1154
-
-
Salt, J.E.1
Wilkinson, G.2
Motevalli, M.3
Hursthouse, M.B.4
-
59
-
-
37049088895
-
-
Denholm, S.; Hunter, G.; Weakley, T. J. R. J. Chem. Soc., Dalton Trans. 1987, 2789-2791.
-
(1987)
J. Chem. Soc., Dalton Trans.
, vol.2789-2791
-
-
Denholm, S.1
Hunter, G.2
Weakley, T.J.R.3
-
60
-
-
34548218160
-
-
Vidyaratne, I.; Scott, J.; Gambarotta, S.; Budzelaar, P. H. M. Inorg. Chem. 2007, 46, 7040-7049.
-
(2007)
Inorg. Chem.
, vol.46
, pp. 7040-7049
-
-
Vidyaratne, I.1
Scott, J.2
Gambarotta, S.3
Budzelaar, P.H.M.4
-
61
-
-
78649285620
-
-
bond distances are different at 1 δ, but are indistinguishable at the 3 δ level
-
The bond distances are different at 1 δ, but are indistinguishable at the 3 δ level.
-
-
-
-
63
-
-
78649269890
-
-
eff for a single unpaired electron. As Kahn has noted, the Bohr magneton is better reserved as a unit of magnetization
-
eff for a single unpaired electron. As Kahn has noted, the Bohr magneton is better reserved as a unit of magnetization.
-
-
-
-
66
-
-
78649259194
-
-
2O
-
2O.
-
-
-
-
68
-
-
78649283120
-
-
However, we note that the mono-oxidized compound 3 does show very slightly longer N-N and shorter Cr-N distances compared to neutral 2
-
However, we note that the mono-oxidized compound 3 does show very slightly longer N-N and shorter Cr-N distances compared to neutral 2.
-
-
-
-
71
-
-
0033516905
-
-
Kheradmandan, S.; Heinze, K.; Schmalle, H. W.; Berke, H. Angew. Chem., Int. Ed. 1999, 38, 2270-2273.
-
(1999)
Angew. Chem., Int. Ed.
, vol.38
, pp. 2270-2273
-
-
Kheradmandan, S.1
Heinze, K.2
Schmalle, H.W.3
Berke, H.4
-
73
-
-
0001445645
-
-
Le Stang, S.; Paul, F.; Lapinte, C. Organometallics 2000, 19, 1035-1043.
-
(2000)
Organometallics
, vol.19
, pp. 1035-1043
-
-
Stang, S.1
Paul, F.2
Lapinte, C.3
-
74
-
-
0034299096
-
-
Denis, R.; Toupet, L.; Paul, F.; Lapinte, C. Organometallics 2000, 19, 4240-4251.
-
(2000)
Organometallics
, vol.19
, pp. 4240-4251
-
-
Denis, R.1
Toupet, L.2
Paul, F.3
Lapinte, C.4
-
75
-
-
0041914622
-
-
Roué, S.; Le Stang, S.; Toupet, L.; Lapinte, C. C. R. Chim. 2003, 6, 353-366.
-
(2003)
R. Chim.
, vol.6
, pp. 353-366
-
-
Roué, S.1
Le Stang, S.2
Toupet, L.3
Lapinte, C.C.4
-
76
-
-
17144424943
-
-
Angaridis, P.; Cotton, F. A.; Murillo, C. A.; Villagran, D.; Wang, X. J. Am. Chem. Soc. 2005, 127, 5008-5009.
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 5008-5009
-
-
Angaridis, P.1
Cotton, F.A.2
Murillo, C.A.3
Villagran, D.4
Wang, X.5
-
77
-
-
78649314980
-
-
Tara, J. B.; Cameron, T. S.; Donal, H. M.; Laurence, K. T.; Manuel, A. S. A. Eur. J. Inorg. Chem. 2007, 2007, 4021-4027.
-
(2007)
Eur. J. Inorg. Chem.
, vol.2007
, pp. 4021-4027
-
-
Tara, J.B.1
Cameron, T.S.2
Donal, H.M.3
Laurence, K.T.4
Manuel, A.S.A.5
-
78
-
-
23844493134
-
-
Bruce, M. I.; Costuas, K.; Davin, T.; Ellis, B. G.; Halet, J.-F.; Lapinte, C.; Low, P. J.; Smith, M. E.; Skelton, B. W.; Toupet, L.; White, A. H. Organometallics 2005, 24, 3864-3881.
-
(2005)
Organometallics
, vol.24
, pp. 3864-3881
-
-
Bruce, M.I.1
Costuas, K.2
Davin, T.3
Ellis, B.G.4
Halet, J.-F.5
Lapinte, C.6
Low, P.J.7
Smith, M.E.8
Skelton, B.W.9
Toupet, L.10
White, A.H.11
-
79
-
-
78649257200
-
-
At any rate, all the compounds studied here feature intense peaks between 900 and 950 nm; metal-to-ligand charge transfer or symmetryallowed HOMO-SOMO transitions are more likely candidates for assignment based on literature precedent
-
At any rate, all the compounds studied here feature intense peaks between 900 and 950 nm; metal-to-ligand charge transfer or symmetryallowed HOMO-SOMO transitions are more likely candidates for assignment based on literature precedent.
-
-
-
-
80
-
-
33644554858
-
-
Klein, A.; Lavastre, O.; Fiedler, J. Organometallics 2005, 25, 635-643.
-
(2005)
Organometallics
, vol.25
, pp. 635-643
-
-
Klein, A.1
Lavastre, O.2
Fiedler, J.3
-
81
-
-
64549131171
-
-
Lohan, M.; Ecorchard, P.; Ruffer, T.; Justaud, F.; Lapinte, C.; Lang, H. Organometallics 2009, 28, 1878-1890.
-
(2009)
Organometallics
, vol.28
, pp. 1878-1890
-
-
Lohan, M.1
Ecorchard, P.2
Ruffer, T.3
Justaud, F.4
Lapinte, C.5
Lang, H.6
-
82
-
-
0033608114
-
-
Demadis, K. D.; El-Samanody, E.-S.; Coia, G. M.; Meyer, T. J. J. Am. Chem. Soc. 1999, 121, 535-544.
-
(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 535-544
-
-
Demadis, K.D.1
El-Samanody, E.-S.2
Coia, G.M.3
Meyer, T.J.4
-
85
-
-
78649286944
-
-
Alternatively, one electron could be added to one of the singly occupied dδ orbitals in 4, again generating a set of three orthogonal singly occupied d orbitals and a quartet ground state
-
Alternatively, one electron could be added to one of the singly occupied dδ orbitals in 4, again generating a set of three orthogonal singly occupied d orbitals and a quartet ground state.
-
-
-
|