Preparation and characterization of immobilized chelate extractant in pva gel beads for an efficient recovery of copper(II) in aqueous solution

Industrial and Engineering Chemistry Research

Volumn 49, Issue 22, 2010, Pages 11652-11660

  Kobayashi, Takashi ^a,b,c   Yoshimoto, Makoto ^b   Nakao, Katsumi ^b  

^a Yamaguchi Prefectural Shimonoseki Technical High School   (Japan)

^b YAMAGUCHI UNIVERSITY   (Japan)

^c Department of Chemical Technology   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

5-DODECYLSALICYLALDOXIME; AQUEOUS SOLUTIONS; CHELATE EXTRACTION; COPPER (II); CUPRIC SULFATE; DIFFUSION RESISTANCE; DIRECT CONTACT; ENVIRONMENT FRIENDLY; EQUIPMENT SYSTEM; EXPANDED BEDS; EXTRACTANTS; EXTRACTION PROCESS; GEL BEADS; GEL PHASE; HIGH CONCENTRATION; LANGMUIRS; LIQUID-LIQUID EXTRACTION; MEAN DIAMETER; PVA-GEL; SHRINKING CORE MODEL; SORPTION EQUILIBRIA; SULFURIC ACID SOLUTION;

CHELATION; COPPER; GELS; ORGANIC SOLVENTS; RECOVERY; SOLUTIONS; SORPTION; SULFURIC ACID;

SOLVENT EXTRACTION;

EID: 78449310293     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie101113s     Document Type: Article

References (35)

1. Sole, K. C.; Feather, A. M.; Cole, P. M. Solvent extraction in Southern Africa: An update of some recent hydrometallurgical developments Hydrometallurgy 2005, 78, 52-78
2. Komulainen, T.; Pekkala, P.; Rantala, A.; Jämsä-Jounela, S.-L. Dynamic modeling of an industrial copper solvent extraction process Hydrometallurgy 2006, 81, 52-61
3. Reddy, B. R.; Priya, D. N. Process development for the separation of copper(II), nickel(II) and zinc(II) from sulphate solutions by solvent extraction using LIX 84 I Sep. Purif. Technol. 2005, 45, 163-167
4. Campderrás, M. E.; Acosta, A.; Marchese, J. Selective separation of copper with Lix 864 in a hollow fiber module Talanta 1998, 47, 19-24
5. Valenzuela, F.; Vega, M. A.; Yanez, M. F.; Basualto, C. Application of a mathematical model for copper permeation from a chilean mine water through a hollow fiber-type supported liquid membrane J. Membr. Sci. 2002, 204, 385-400
6. Marchese, J.; Valenzuela, F.; Basualto, C.; Acosta, A. Transport of molybdenium with Alamine 336 using supported liquid membrane Hydrometallurgy 2004, 72, 309-317
7. Lin, S.-H.; Juang, R.-S. Removal of free and chelated Cu(II) ions from water by a nondispersive solvent extraction process Water Res. 2002, 36, 3611-3619
8. Valenzuela, F.; Fonseca, C.; Basualto, C.; Correa, O.; Tapia, C.; Sapag, J. Removal of copper ions from a waste mine water by a liquid emulsion membrane method Miner. Eng. 2005, 18, 33-40
9. Hebrant, M.; Francois, N.; Tondre, C. Comparison of micellar ultrafiltration and solvent extraction for the removal of copper ions from aqueous solutions Colloids Surf., A 1998, 143, 77-88
10. Kabay, N.; Arda, M.; Saha, B.; Streat, M. Removal of Cr(VI) by solvent impregnated resins (SIR) containing Aliquat 336 React. Funct. Polym. 2003, 54, 103-115
11. Trochimczuk, A. W.; Kabay, N.; Arda, M.; Streat, M. Stabilization of solvent impregnated resins (SIRs) by coating with water soluble polymers and chemical crosslinking React. Funct. Polym. 2004, 59, 1-7
12. Kabay, N.; Arda, M.; Trochimczuk, A.; Streat, M. Removal of chromate by solvent impregnated resins (SIRs) stabilized by coating and chemical crosslinking. I. Batch-mode sorption studies React. Funct. Polym. 2004, 59, 9-14
13. Kabay, N.; Solak, O.; Arda, M.; Topal, U.; Yuksel, M.; Trochimczuk, A.; Streat, M. Packed column study of the sorption of hexavalent chromium by novel solvent impregnated resins containing Aliquat 336: Effect of chloride and sulfate ions React. Funct. Polym. 2005, 64, 75-82
14. Akita, S.; Takeuchi, H. Sorption and separation of metals from aqueous solution by a macromolecular resin containing tri- n -octylamine J. Chem. Eng. Jpn. 1990, 23, 439-443
15. Kamio, E.; Matsumoto, M.; Valenzuela, F.; Kondo, K. Sorption behavior of Ga(III) and In(III) into a microcapsule containing long-chain alkylphosphonic acid monoester Ind. Eng. Chem. Res. 2005, 44, 2266-2272
16. Kamio, E.; Matsumoto, M.; Kondo, K. Extraction mechanism of rare metals with microcapsules containing organophosphorus compounds J. Chem. Eng. Jpn. 2002, 35, 178-185
17. Nishihama, S.; Nishimura, G.; Hirai, T.; Komasawa, I. Separation and recovery of Cr(VI) from simulated plating waste using microcapsules containing quaternary ammonium salt extractant and phosphoric acid extractant Ind. Eng. Chem. Res. 2004, 43, 751-757
18. Yang, W. W.; Luo, G. S.; Gong, X. C. Extraction and separation of metal ions by a column packed with polystyrene microcapsules containing Aliquat 336 Sep. Purif. Technol. 2005, 43, 175-182
19. Ocio, A.; Mijangos, F.; Elizalde, M. Copper and cadmium extraction from highly concentrated phosphoric acid solutions using calcium alginate gels enclosing bis(2,4,4-trimethylpentyl)thiophosphinic acid J. Chem. Technol. Biotechnol. 2006, 81, 1409-1418
20. Outokesh, M.; Mimura, H.; Niibori, Y.; Tanaka, K. Equilibrium and kinetics of silver uptake by multinuclear alginate microcapsules comprising an ion exchanger matrix and cyanex 302 organophosphinic acid extractant Ind. Eng. Chem. Res. 2006, 45, 3633-3643
21. Ngomsik, A.-F.; Bee, A.; Siaugue, J.-M.; Cabuil, V.; Cote, G. Nickel adsorption by magnetic alginate microcapsules containing an extractant Water Res. 2006, 40, 1848-1856
22. Yoshizawa, H.; Fujikubo, K.; Uemura, Y.; Kawano, Y.; Kondo, K.; Hatate, Y. Preparation of divinylbenzene homopolymeric microcapsules with highly porous membranes by in-situ polymerization with solvent evaporation J. Chem. Eng. Jpn. 1995, 28, 78-84
23. Cooper, C.; Lin, Y. S.; Gonzalez, M. Synthesis and characterization of LIX-84 noncovalently bound silica sorbents for metal-ion recovery Ind. Eng. Chem. Res. 2003, 42, 1253-1260
24. Sarkar, M.; Datta, P. K.; Das, M. Equilibrium studies on the optimization of solid-phase extraction using modified silica gel for removal, recovery, and enrichment prior to the determination of some metal ions from aqueous samples of different origin Ind. Eng. Chem. Res. 2002, 41, 6745-6750
25. Warshawsky, A. In Ion Exchange and Solvent Extraction; Marinsky, J. A.; Marcus, Y., Eds.; Marcel Dekker: New York, 1981; Vol. 8, p 229.
26. Hashimoto, S.; Furukawa, K. Immobilization of activated sludge by PVA-boric acid method Biotechnol. Bioeng. 1987, 30, 52-59
27. Ibrahim, M. A.; Yamamoto, M.; Yasuda, Y.; Fukunaga, K.; Nakao, K. Removal of acetaldehyde and propionaldehyde from waste gas in packed column with immobilized activated sludge gel beads J. Chem. Eng. Jpn. 2001, 34, 1195-1203 (Pubitemid 33071661)
28. Ibrahim, M. A.; Mizuno, H.; Yasuda, Y.; Fukunaga, K.; Nakao, K. Removal of mixtures of acetaldehyde and propionaldehyde from waste gas in packed column with immobilized activated sludge gel beads Biochm. Eng. J. 2001, 8, 9-18 (Pubitemid 32506250)
29. Laguecir, A.; Frére, Y.; Danicher, L.; Burgard, M. Size effect of complexing microcapsules on copper ion extraction Eur. Polym. J. 2002, 38, 977-981
30. Laguecir, A.; Frére, Y.; Danicher, L.; Loureiro, J. M.; Ernst, B.; Burgard, M. Polyacrylic gel beads reinforced by a polyamide membrane: Application to copper removal in aqueous media Desalination 2002, 146, 311-317
31. Frére, Y.; Danicher, L.; Laguécir, A.; Loureiro, J. M.; Burgard, M. Complexing capsules-metal extraction and modeling of ion transfer Int. J. Pharm. 2002, 242, 393-397
32. Tokuyama, H.; Yanagawa, K.; Sakohara, S. Temperature swing adsorption of heavy metals on novel phosphate-type adsorbents using thermosensitive gels and/or polymers Sep. Purif. Technol. 2006, 50, 8-14
33. Simpson, J.; Navarro, P.; Alguacil, F. J. Iron(II) extraction by LIX860 and its influence on copper(II) extraction from sulphuric solutions Hydrometallurgy 1996, 42, 13-20
34. Yoshizuka, K.; Arita, H.; Baba, Y.; Inoue, K. Equilibria of solvent extraction of copper(II) with 5-dodecylsalicylaldoxime Hydrometallurgy 1990, 23, 247-261
35. Li, C.; Yoshimoto, M.; Tsukuda, N.; Fukunaga, K.; Nakao, K. A kinetic study on enzymatic hydrolysis of a variety of pulps for its enhancement with continuous ultrasonic irradiation Biochem. Eng. J. 2004, 19, 155-164