Low-temperature, mineral-catalyzed air oxidation: A possible new pathway for PAH stabilization in sediments and soils

Environmental Science and Technology

Volumn 44, Issue 22, 2010, Pages 8547-8552

  Ghislain, Thierry ^a   Faure, Pierre ^a   Biache, Coralie ^a   Michels, Raymond ^a  

^a CRPG CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AIR OXIDATION; CARBONACEOUS RESIDUES; END-PRODUCTS; ENVIRONMENTAL ASSESSMENT; EXPERIMENTAL CONDITIONS; EXPERIMENTAL INVESTIGATIONS; FLUORANTHENE; HIGH MOLECULAR WEIGHT COMPOUNDS; KEY ISSUES; LONG TERM; LOW TEMPERATURES; MINERAL SUBSTRATES; NATURAL CONDITIONS; NATURAL SYSTEMS; ORGANIC MATTER; QUARTZ SAND; SOILS AND SEDIMENTS; TOXIC HAZARD;

AROMATIC HYDROCARBONS; CATALYSIS; CLAY MINERALS; LIMESTONE; MINERALS; OXIDATION; POLYCYCLIC AROMATIC HYDROCARBONS; QUARTZ; SEDIMENTOLOGY; SEDIMENTS; SILICATE MINERALS; SOILS;

STABILIZATION;

CARBON; COAL; FLUORANTHENE; LIMESTONE; MINERAL; ORGANIC MATTER; POLYCYCLIC AROMATIC HYDROCARBON;

CATALYSIS; CLAY; COAL; ENVIRONMENTAL ASSESSMENT; GEOCHEMICAL METHOD; LIMESTONE; LOW TEMPERATURE; MINERAL; MOLECULAR ANALYSIS; ORGANIC MATTER; OXIDATION; PAH; QUARTZ; SEDIMENT ANALYSIS; SOIL TYPE; STABILIZATION; TOXICITY;

AIR OXIDATION; AIR POLLUTION; ARTICLE; CATALYSIS; CLAY; GEOCHEMICAL ANALYSIS; LOW TEMPERATURE; MASS FRAGMENTOGRAPHY; MOLECULAR WEIGHT; OXIDATION KINETICS; QUADRUPOLE TIME OF FLIGHT MASS SPECTROMETRY; SAND; SEDIMENT; SOIL; TIME OF FLIGHT MASS SPECTROMETRY;

ALUMINUM SILICATES; CALCIUM CARBONATE; CARBON DIOXIDE; CATALYSIS; CHLOROFORM; FLUORENES; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; GEOLOGIC SEDIMENTS; MICROSCOPY, ELECTRON, SCANNING; MINERALS; OXIDATION-REDUCTION; POLYCYCLIC HYDROCARBONS, AROMATIC; QUARTZ; SOIL; SOIL POLLUTANTS; TEMPERATURE;

EID: 78449245233     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es102832r     Document Type: Article

References (22)

1. Biache, C.; Mansuy-Huault, L.; Faure, P.; Munier-Lamy, C.; Leyval, C. Effects of thermal desorption on the composition of two coking plant soils: Impact on solvent extractable organic compounds and metal bioavailability Environ. Pollut. 2008, 156 (3) 671-677
2. Merino, J.; Piña, J.; Errazu, A. F.; Bucalá, V. Fundamental study of thermal treatment of soil Soil Sediment. Contam. 2003, 12 (3) 417-441
3. Rivas, F. J. Polycyclic aromatic hydrocarbons sorbed on soils: A short review of chemical oxidation based treatments J. Hazard. Mater. 2006, 138 (2) 234-251
4. Faure, P.; Jeanneau, L.; Lannuzel, F. Analysis of organic matter by flash pyrolysis-gas chromatography-mass spectrometry in the presence of Na-smectite: When clay minerals lead to identical molecular signature Org. Geochem. 2006, 37 (12) 1900-1912
5. Faure, P.; Schlepp, L.; Mansuy-Huault, L.; Elie, M.; Jardé, E.; Pelletier, M. Aromatization of organic matter induced by the presence of clays during flash pyrolysis-gas chromatography-mass spectrometry (PyGC-MS): A major analytical artifact J. Anal. Appl. Pyrol. 2006, 75 (1) 1-10
6. Faure, P.; Landais, P. Evidence for clay minerals catalytic effects during low-temperature air oxidation of n-alkanes Fuel 2000, 79 (14) 1751-1756
7. Granqvist, B.; Sandberg, T.; Hotokka, M. Adsorption of organic probes on silica through Lewis interactions: A comparison of experimental results and quantum chemical calculations J. Colloid Interface Sci. 2007, 310 (2) 369-376
8. Dabestani, R.; Reszka, K. J.; Sigman, M. E. Surface catalyzed electron transfer from polycyclic aromatic hydrocarbons (PAH) to methyl viologen dication: Evidence for ground-state charge transfer complex formation on silica gel J. Photochem. Photobiol., A 1998, 117 (3) 223-233
9. Rooney, J. J.; Pink, R. C. Formation and stability of hydrocarbon radical-ions on a silica-alumina surface Trans. Faraday Soc. 1962, 58, 1632-1641
10. 3-TPD and catalytic tests Appl. Catal., A 2000, 193 (1-2) 55-69
11. Zhang, Z. G.; Kyotani, T.; Tomita, A. TPD study on coal chars chemisorbed with oxygen-containing gases Energy Fuels 1988, 2 (5) 679-684
12. 2 chemisorption and subsequent temperature- programmed desorption of calcium-loaded coal chars Energy Fuels 1989, 3 (5) 566-571
13. Kawahara, S. I.; Tsuzuki, S.; Uchimaru, T. Lewis acidity/basicity of π-electron systems: Theoretical study of a molecular interaction between a π system and a Lewis acid/base Chem.-Eur. J. 2005, 11 (15) 4458-4464
14. Foote, C. S.; Valentine, J. S.; Greenberg, A.; Liebman, J. F., Eds. Active Oxygen in Chemistry. In Structure Energetics and Reactivity Chemistry Series; Chapman & Hall: New York, 1995; pp 105 - 140
15. Jensen, W. B. The Lewis Acid-Base Concepts: An Overview; Wiley: New York, 1980; pp 112 - 141.
16. Leach, M. R., Lewis Acid/Base Reaction Chemistry; Meta-Synthesis: Salford, U.K., 1999; pp 14 - 15, 72-74.
17. Gopalakrishnan, R.; Fullwood, M. J.; Bartholomew, C. H. Catalysis of char oxidation by calcium minerals: Effects of calcium compound chemistry on intrinsic reactivity of doped Spherocarb and Zap chars Energy Fuels 1994, 8 (4) 984-989
18. Gutmann, V. The Donor-Acceptor Approach to Molecular Interactions; Plenum: New York, 1978; pp 57 - 232.
19. Bouxin, F.; Baumberger, S.; Pollet, B.; Haudrechy, A.; Renault, J. H.; Dole, P. Acidolysis of a lignin model: Investigation of heterogeneous catalysis using Montmorillonite clay Bioresour. Technol. 2010, 101 (2) 736-744
20. Dines, M. B. Intercalation in layered compounds J. Chem. Educ. 1974, 51 (4) 221-223
21. Durand, B. Sedimentary organic matter and kerogen. Definition and quantitative importance of kerogen Kerogen: Insoluble Org. Matter Sediment. Rocks 1980, 13-34
22. Durand, B.; Nicaise, G. Procedures for kerogen isolation Kerogen: Insoluble Org. Matter Sediment. Rocks 1980, 35-53