Solvation molar enthalpies and heat capacities of n-alkanes and n-alkylbenzenes on stationary phases of wide-ranging polarity

Journal of Chromatography A

Volumn 1217, Issue 49, 2010, Pages 7767-7775

  Lebrón Aguilar, Rosa ^a   Quintanilla López, Jesús Eduardo ^b   Santiuste, José María ^a  

^a INSTITUTO DE QUÍMICA FÍSICA ROCASOLANO   (Spain)

^b INSTITUTO DE QUÍMICA ORGÁNICA GENERAL   (Spain)

Author keywords

Gas chromatography; Hydrocarbon; Molar enthalpy of solvation; Molar heat capacity of solvation; Retention factor; Stationary phase

Indexed keywords

CAPILLARY COLUMNS; CHROMATOGRAPHIC METHODS; CONSTANT PRESSURES; HEAT CAPACITIES; LINEAR RELATIONSHIPS; MOLAR ENTHALPY; MOLAR HEAT CAPACITIES; N-ALKANES; N-ALKYLBENZENES; PARTIAL MOLAR ENTHALPY; RETENTION FACTORS; STATIONARY PHASE; STATIONARY PHASIS; SUBSTITUTION GROUPS; TEMPERATURE GRADIENT; THERMODYNAMIC VARIABLES; VAN DER WAALS VOLUME;

BLOOD VESSELS; CHROMATOGRAPHIC ANALYSIS; ENTHALPY; ORGANIC COMPOUNDS; PARAFFINS; SOLS; SOLVATION; SPECIFIC HEAT OF SOLIDS; VAN DER WAALS FORCES;

GAS CHROMATOGRAPHY;

ALKANE; ALKYLBENZENE; HYDROCARBON;

ACCURACY; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL COMPOSITION; CONTROLLED STUDY; DILUTION; ENTHALPY; HEAT SENSITIVITY; MATHEMATICAL MODEL; PRESSURE MEASUREMENT; PRIORITY JOURNAL; SOLVATION; SUBSTITUTION REACTION;

ALGORITHMS; ALKANES; BENZENE DERIVATIVES; CHROMATOGRAPHY, GAS; LINEAR MODELS; MODELS, MOLECULAR; MOLECULAR WEIGHT; SOLVENTS; THERMODYNAMICS;

EID: 78249269469     PISSN: 00219673     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chroma.2010.10.019     Document Type: Article

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