Metastable states during dissociation of carbon dioxide hydrates below 273K

Chemical Engineering Science

Volumn 66, Issue 1, 2011, Pages 73-77

  Melnikov, V P ^a,b   Nesterov, A N ^a,b   Reshetnikov, A M ^a   Istomin, V A ^c  

^a EARTH CRYOSPHERE INSTITUTE   (Russian Federation)

^b TYUMEN INDUSTRIAL UNIVERSITY   (Russian Federation)

^c Gazprom Neft JSC   (Russian Federation)

Author keywords

Carbon dioxide hydrate; Crystallization; Nucleation; Phase change; Phase equilibria; Supercooled water

Indexed keywords

GAS EQUILIBRIUM; HYDRATE DISSOCIATION; HYDRATE FILM; HYDRATE PARTICLES; ICE MELTING POINT; LIQUID PHASE; META-STABLE STATE; METASTABLE EQUILIBRIA; METASTABLE LIQUID; METASTABLE PHASE; METHANE HYDRATES; PHASE CHANGE; PROPANE HYDRATE; SUPERCOOLED WATER; TEMPERATURE RANGE;

CARBON DIOXIDE; CRYSTALLIZATION; DISSOCIATION; GASES; HYDRATION; ICE; LIQUIDS; METASTABLE PHASES; METHANE; NUCLEATION; PHASE DIAGRAMS; PHASE EQUILIBRIA; PHASE STABILITY; PROPANE; SOLID SOLUTIONS; SUPERCOOLING;

GAS HYDRATES;

EID: 78149464524     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2010.10.007     Document Type: Article

References (17)

1. Chuvilin E.M., Petrakova S.Y., Gureva O.M., Istomin V.A. Formation of carbon dioxide gas hydrates in freezing sediments and decomposition kinetics of the hydrates formed. Physics and Chemistry of Ice 2007, 147-154. The Royal Society of Chemistry, Cambridge. W.F. Kuhs (Ed.).
2. 4 hydrate. Journal of Physical Chemistry B 2003, 107:5529-5539.
3. Davidson D.W., Garg S.K., Gough S.R., Handa Y.P., Ratclife C.I., Ripmeester J.A., Tse J.S., Lawson W.F. Laboratory analysis of naturally occurring gas hydrate from sediment of the Gulf Mexico. Geochimica et Cosmochimica Acta 1986, 50:619-623.
4. Duchkov A.D., Sokolova L.S., Ayunov D.E., Permyakov M.E. Assesment of potential of Western Siberia permafrost for the carbon dioxide storage. Earth's Cryosphere 2009, 13(4):62-68. in Russian.
5. 2 gas hydrates-surface microstructure and ice perfection. Journal of Physical Chemistry B 2009, 113:15975-15988.
6. Freer E.M., Selim M.S., Sloan E.D. Methane hydrate film growth kinetics. Fluid Phase Equilibria 2001, 185:65-75.
7. Goel N. In situ methane hydrate dissociation with carbon dioxide sequestration: current knowledge and issues. Journal of Petroleum Science and Engineering 2006, 51:169-184.
8. Istomin V.A., Kwon V.G., Durov V.A. Metastable states of gas hydrates. Gazovaya Promishlennost (Gas Industry of Russia, Special Issue: Gas Hydrates) 2006, 32-35. (in Russian).
9. Kuhs W.F., Genov G., Staykova D.K., Hansen T. Ice perfection and onset of anomalous preservation of gas hydrate. Physical Chemistry Chemical Physics 2004, 6:4917-4920.
10. Melnikov V.P., Nesterov A.N., Reshetnikov, Istomin V.A., Kwon V.G. Stability and growth of gas hydrates below the ice-hydrate-gas equilibrium line on the P-T phase diagram. Chemical Engineering Science 2010, 65:906-914.
11. Melnikov V.P., Nesterov A.N., Reshetnikov A.M., Zavodovsky A.G. Evidence of liquid water formation during methane hydrates dissociation below the ice point. Chemical Engineering Science 2009, 64:1160-1166.
12. Mel'nikov V.P., Nesterov A.N., Reshetnikov A.M. Formation of supercooled water upon dissociation of propane hydrates at T<270K. Doklady Physical Chemistry 2007, 417:304-307.
13. Sloan E.D., Koh C.A. Clathrate hydrates of natural gases. 2007, CRS Press Taylor and Francis Group, Boca Raton. third ed.
14. Stern L.A., Circone S., Kirby S.H., Durham W.B. Anomalous preservation of pure methane hydrate at 1 atm. Journal of Physical Chemistry B 2001, 105:1756-1762.
15. Takeya S., Ripmeester J. Dissociation behavior of clathrate hydrates to ice and dependence on guest molecules. Angewandte Chemie International Edition 2008, 47:1276-1279.
16. 4 hydrate. Journal of Physical Chemistry A 2001, 105:9756-9759.
17. Yakushev V.S., Istomin V.A. Gas hydrate self-preservation effect. Physics and Chemistry of Ice. 1992, 136-140. Hokkaido University Press, Sapporo. N. Maeno, T. Hondoh (Eds.).