Alcoholysis kinetics of glucose catalyzed by dilute sulfuric acid in near-critical methanol

Huagong Xuebao/CIESC Journal

Volumn 61, Issue 10, 2010, Pages 2585-2589

  Wu, Xiaoyu ^a   Lü, Xiuyang ^a   Chen, Tian ^a   Chen, Zhangnü ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Alcoholysis; Glucose; Kinetics; Methyl levulinate; Near critical methanol

Indexed keywords

ACID CONCENTRATIONS; ALCOHOLYSIS; ALCOHOLYSIS REACTIONS; DILUTE SULFURIC ACID; FIRST ORDER KINETICS; GLUCOSE CONCENTRATION; HIGHER TEMPERATURES; HIGHER YIELD; METHYL LEVULINATE; NEAR-CRITICAL METHANOL; ONE POT; ONE POT PROCESS; REACTION ORDERS; REACTION TEMPERATURE; TEMPERATURE RANGE;

ACTIVATION ENERGY; CATALYSIS; GLUCOSE; INTEGRAL EQUATIONS; METHANOL; SULFUR DETERMINATION;

SULFURIC ACID;

EID: 78149364858     PISSN: 04381157     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (14)

1. Fitzpatrick S W. Lignocellulose degradation: WO, 8910362. 1989-11-02.
2. Fitzpatrick S W. Production of levulinic acid from carbohydrate-containing materials: WO, 9640609. 1996-12-19.
3. Yang Y, Gilbert A, Xu C B. Production of bio-crude from forestry waste by hydro-liquefaction in sub-/super-critical methanol. AIChE Journal, 2009, 55(3): 807-819.
4. Tsujino J, Kawamoto H, Saka S. Reactivity of lignin in supercritical methanol studied with various lignin model compounds. Wood Science and Technology, 2003, 37: 299-307.
5. Ishikawa Y, Saka S. Chemical conversion of cellulose as treated in supercritical methanol. Cellulose, 2001, 8: 189-195.
6. Minami E, Saka S. Decomposition behavior of woody biomass in water-added supercritical methanol. Journal of Wood Science, 2005, 51: 395-400.
7. Tyrlik S K, Szerszen D, Olejnik M, Danikiewicz W. Concentrated water solutions of salts as solvents for reaction of carbohydrates(II): Influence of some magnesium salts and some ruthenium species on catalysis of dehydration of glucose. Journal of Molecular Catalysis A: Chemical, 1996, 106: 223-233.
8. Tyrlik S K, Szerszen D, Olejnik M, Danikiewicz W. Selective dehydration of glucose to hydroxymethylfurfural and a one-pot synthesis of a 4-acetylbutyrolactone from glucose and trioxane in solutions of aluminum salts. Carbohydrate Research, 1999, 315: 268-272.
9. Bicker M, Kaiser D, Ott L, Vogel H. Dehydration of D-fructose to hydroxymethylfurfural in sub- and supercritical fluids. Journal Supercritical Fluids, 2005, 36: 118-126.
10. Lü Xiuyang, Peng Xinwen, Lu Chongbing, Jing Qi. Decomposition kinetics of hexose catalyzed by strong acidic resins. CIESC Journal, 2009, 60(3): 634-640.
11. Zhao Xianjun. Process technology status of methyl ether and its development. Chemical Industry, 2008, 26(6): 26-30.
12. Straty G C, Palavra A M F, Bruno T J. PVT properties of methanol at temperatures to 300°C. International Journal of Thermophysics, 1986, 7(5): 1077-1089.
13. Peng Xinwen, Lü Xiuyang. Decomposition kinetics of glucose catalyzed by dilute sulfuric acid. Chemical Reaction Engineering and Technology, 2008, 24(6): 523-528.
14. Peng Xinwen, Lü Xiuyang. Decomposition kinetics of 5-hydroxymethylfurfural catalyzed by dilute sulfuric acid. Journal of Chemical Industry and Engineering (China), 2008, 59(5): 1150-1155.