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Volumn 29, Issue 21, 2010, Pages 5435-5445

Dinuclear silicon complexes of uracil, barbituric acid, and 5,5-dimethylbarbituric acid: Hydrolytic formation of cyclic oligomers

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EID: 78149341699     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100461b     Document Type: Article
Times cited : (17)

References (40)
  • 2
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    • Selected reviews on hypercoordinate silicon compounds: In; Wiley: New York,; pp
    • Selected reviews on hypercoordinate silicon compounds: Brook, M. A. In Silicon in Organic, Organometallic and Polymer Chemistry; Wiley: New York, 2000; pp 97-115.
    • (2000) Silicon in Organic, Organometallic and Polymer Chemistry , pp. 97-115
    • Brook, M.A.1
  • 8
    • 0000024039 scopus 로고    scopus 로고
    • Rappoport Z., Apeloig Y. In, Eds.; Wiley: Chichester, U.K,; Vol., Part 2, pp
    • Kost, D.; Kalikhman, I. In The Chemistry of Organic Silicon Compounds; Rappoport, Z.; Apeloig, Y., Eds.; Wiley: Chichester, U.K, 1998; Vol. 2, Part 2, pp 1339-1445.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2 , pp. 1339-1445
    • Kost, D.1    Kalikhman, I.2
  • 11
    • 78149300641 scopus 로고    scopus 로고
    • English translation
    • English translation: Russ. Chem. Rev. 2009, 78, 21-51.
    • (2009) Russ. Chem. Rev. , vol.78 , pp. 21-51
  • 13
    • 0043250975 scopus 로고
    • For other dinuclear hypercoordinate silicon compounds see
    • For other dinuclear hypercoordinate silicon compounds see: Loy, A. D.; Small, J. H.; Shea, K. J. Organometallics 1993, 12, 1484
    • (1993) Organometallics , vol.12 , pp. 1484
    • Loy, A.D.1    Small, J.H.2    Shea, K.J.3
  • 34
    • 78149340709 scopus 로고    scopus 로고
    • 3CN, the solution of which cannot be cooled much further
    • 3CN, the solution of which cannot be cooled much further.
  • 35
    • 0001231737 scopus 로고    scopus 로고
    • We found no conclusive evidence to determine which of the two carbonyl oxygen atoms in uracil is a stronger base or nucleophile; one computational study [Kallies, B.; Mitzner, R. J. Mol. Struct. (THEOCHEM) 1998, 428, 267-282] reported that the urea-type oxygen is more basic in the gas phase toward protonation relative to an amide oxygen. However, the present study suggests that the oxygen affinity toward silicon follows the opposite trend
    • We found no conclusive evidence to determine which of the two carbonyl oxygen atoms in uracil is a stronger base or nucleophile; one computational study [Kallies, B.; Mitzner, R. J. Mol. Struct. (THEOCHEM) 1998, 428, 267-282] reported that the urea-type oxygen is more basic in the gas phase toward protonation relative to an amide oxygen. However, the present study suggests that the oxygen affinity toward silicon follows the opposite trend.
  • 38
    • 3543146179 scopus 로고    scopus 로고
    • English translation
    • English translation: Russ. J. Gen. Chem. 2004, 74, 261-265.
    • (2004) Russ. J. Gen. Chem. , vol.74 , pp. 261-265


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