Heterogeneous reactions of carbonyl sulfide on mineral oxides: Mechanism and kinetics study

Atmospheric Chemistry and Physics

Volumn 10, Issue 21, 2010, Pages 10335-10344

  Liu, Y ^a   Ma, J ^a   He, H ^a  

^a RESEARCH CENTER FOR ECO ENVIRONMENTAL SCIENCES   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; ATMOSPHERIC CHEMISTRY; AUTHIGENIC MINERAL; CARBONYL COMPOUND; CHEMICAL COMPOSITION; DECOMPOSITION; DIFFUSION; FORMATION MECHANISM; HETEROGENEITY; HYDROLYSIS; HYDROXYL RADICAL; OXIDATION; REACTION KINETICS; REACTION RATE; SULFIDE;

EID: 78149272744     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-10-10335-2010     Document Type: Article

References (41)

1. Anderson, T. L., Charison, R. J., Schwartz, S. E., Knutti, R., Boucher, O., Rodhe, H., and Heintzenberg, J.: Climate forcing by aerosols-a hazy picture, Science, 300, 1103-1104, 2003.
2. Andreae, M. O. and Crutzen, P. J.: Atmospheric aerosols: Bio-geochemical sources and role in atmospheric chemistry, Science, 276, 1052-1058, 1997.
3. Aubin, D. G. and Abbatt, J. P.: Laboratory measurements of thermodynamics of adsorption of small aromatic gases to n-hexane soot surfaces, Environ. Sci. Technol., 40, 179-187, 2006.
4. Baltache, H., Khenata, R., Sahnoun, M., Driz, M., Abbar, B., and Bouhafs, B.: Full potential calculation of structural, electronic and elastic properties of alkaline earth oxides MgO, CaO and SrO, Phys. B, 344, 334-342, 2004.
5. 2 on type Ia polar stratospheric cloud materials at 185 K, J. Phys. Chem. A, 101, 8643-8652, 1997.
6. 3 and other oxides of nitrogen on solid NaCl: The role of surface-adsorbed water, J. Phys. Chem., 100, 15218-15228, 1996.
7. 2, J. Phys. Chem. A, 107, 4250-4261, 2003.
8. Chen, H. H., Kong, L. D., Chen, J. M., Zhang, R. Y., and Wang, L.: Heterogeneous uptake of carbonyl sulfide on hematite and hematite-NaCl mixtures, Environ. Sci. Technol., 41, 6484-6490, 2007.
9. Chin, M. and Davis, D. D.: A reanalysis of carbonyl sulfide as a source of stratospheric background sulfur aerosol, J. Geophys. Res., 100, 8993-9005, 1995.
10. Crutzen, P. J. The possible importance of CSO for the sulfate layer of the stratosphere, Geophys. Res. Lett., 3, 73-76, 1976.
11. Dentener, F. J., Carmichael, G. R., Zhang, Y., Lelieveld, J., and Crutzen, P. J.: Role of mineral aerosol as a reactive surface in the global troposphere, J. Geophys. Res., 101, 22869-22889, 1996.
12. De Reus, M., Dentener, F., Thomas, A., Borrmann, S., Ström, J., and Lelieveld, J.: Airborne observations of dust aerosol over the North Atlantic Ocean during ACE 2: Indications for heterogeneous ozone destruction, J. Geophys. Res., 105, 15263-15275, 2000.
13. Frinak, E. K., Wermeille, S. J., Mashburn, C. D., Tolbert, M. A., and Pursell, C. J.: Heterongeous reaciton of gaseous nitric acid on γ-phase iron(III) oxide, J. Phys. Chem. A, 108, 1560-1566, 2004.
14. Graf, H. F. The complex interaction of aerosols and clouds, Science, 303, 1309-1311, 2004.
15. He, H., Liu, J. F., Mu, Y. J., Yu, Y. B., and Chen, M. X.: Heterogeneous oxidation of carbonyl sulfide on atmospheric particles and alumina, Environ. Sci. Technol., 39, 9637-9642, 2005.
16. Jacob, D. J.: Heterogeneous chemistry and tropospheric ozone, At-mos. Environ., 34, 2131-2159, 2000.
17. Jang, M., Czoschke, N. M., Lee, S., and Kamens, R. M.: Heterogeneous atmospheric aerosol production by acid-catalyzed particle reactions, Science, 298, 814-817, 2002.
18. Jones, A., Roberts, D. L., and Slingo, A.: A climate model study of indirect radiative forcing by anthoropogenic sulphate aerosols, Nature, 370, 450-453, 1994.
19. 2O and ZnO single-crystal surfaces: HS-bonding to copper (I) and zinc (II) sites related to catalytic poisoning, J. Am. Chem. Soc., 114, 4718-4727, 1992.
20. 3: An in situ diffuse reflectance infrared Fourier transform spectroscopy investigation, J. Phys. Chem. B, 110, 3225-3230, 2006.
21. 3 over a wide range of humidity, J. Phys. Chem. A, 112, 1561-1571, 2008a.
22. 3, Atmos. Environ., 42, 960-969, 2008b.
23. Liu, Y. C. and He, H.: Experimental and theoretical study of hydrogen thiocarbonate for heterogeneous reaction of carbonyl sulfide on magnesium oxide, J. Phys. Chem. A, 113, 3387-3394, 2009a.
24. Liu Y. C., He, H., and Ma, Q. X.: Temperature dependence of the heterogeneous reaction of carbonyl sulfide on magnesium oxide, J. Phys. Chem. A, 112, 2820-2826, 2008c.
25. Liu, Y. C., He, H., Xu, W. Q., and Yu, Y. B.: Mechanism of heterogeneous reaction of carbonyl sulfide on magnesium oxide, J. Phys. Chem. A, 111, 4333-4339, 2007a.
26. Liu, Y. C., Liu, J. F., He, H., Yu, Y. B., and Xue, L.: Heterogeneous oxidation of carbonyl sulfide on mineral oxides, Chinese Sci. Bull., 52, 2063-2071, 2007b.
27. 3 and MgO, Atmos. Chem. Phys., 9, 6273-6286, doi:10.5194/acp-9-6273-2009, 2009b.
28. Notholt, J., Kuang, Z., Rinsland, C. P., Toon, G. C., Rex, M., Jones, N., Albrecht, T., Deckelmann, H., Krieg, J., Weinzierl, C., Binge-mer, H., Weller, R., and Schrems, O.: Enhanced upper tropical troposhperic COS: Impact on the stratospheric aerosol layer, Science, 300, 307-310, 2003.
29. Ravishankara, A. R. Heterogeneous and multiphase chemistry in the troposphere, Science, 276, 1058-1065, 1997.
30. 2 with metal/oxide surfaces: Band-gap size and chemical reactivity, J. Phys. Chem. B, 102, 5511-5519, 1998.
31. Solomon, S., Sanders, R. W., Garcia, R. R., and Keys, J. G.: Increased chlorine dioxide over Antarctica caused by volcanic aerosols form Mount Pinatubo, Nature, 363, 245-248, 1993.
32. Turco, R. P., Whitten, R. C., Toon, O. B., Pollack, J. B., and Hamill, P.: OCS, stratospheric aerosols and climate, Nature, 283, 283-286, 1980.
33. Underwood, G. M., Li, P., Usher, C. R., and Grassian, V. H.: Determining accurate kinetic parameters of potentially important heterogeneous atmospheric reactions on solid particles surfaces with a Knudsen cell reactor, J. Phys. Chem. A, 104, 819-829, 2000.
34. Underwood, G. M., Miller, T. M., and Grassian, V. H.: Transmission FT-IR and Knudsen cell study of the heterogeneous reactivity of gaseous nitrogen dioxide on mineral oxide particles, J. Phys. Chem. A, 103, 6184-6190, 1999.
35. Usher, C. R., Al-Hosney, H., Carlos-Cuellar, S., and Grassian, V. H.: A laboratory study of the heterogeneous uptake and oxidation of sulfur dioxide on mineral dust particles, J. Geophys. Res., 107, 4713-4721, 2002.
36. Usher, C. R., Michel, A. E., and Grassian, V. H.: Reactions on mineral dust, Chem. Rev., 103, 4883-4939, 2003a.
37. Usher, C. R., Michel, A. E., Stec, D., and Grassian, V. H.: Laboratory studies of ozone uptake on processed mineral dust, Atmos. Environ., 37, 5337-5347, 2003b.
38. Vlasenko, A., Sjogren, S., Weingartner, E., Stemmler, K., Gäggeler, H. W., and Ammann, M.: Effect of humidity on nitric acid uptake to mineral dust aerosol particles, Atmos. Chem. Phys., 6, 2147-2160, doi:10.5194/acp-6-2147- 2006, 2006.
39. Watts, S. F. The mass budgets of carbonyl sulfide, dimethyl sulfide, carbon disulfide and hydrogen sulfide, Atmos. Environ., 34, 761-779, 2000.
40. Wu, H. B., Wang, X., and Cheng, J. M.: Photooxidation of car-bonyl sulfide in the presence of the typical oxides in atmospheric aerosol, Sci. China. Ser. B Chem., 48, 31-37, 2005.
41. Wu, H. B., Wang, X., Cheng, J. M., Yu, H. K., Xue, H. X., Pan X. X., and Hou, H. Q.: Mechanism of the heterogeneous reaction of carbonyl sulfide with typical components of atmospheric aerosol, Chinese Sci. Bull., 49, 1231-1235, 2004.