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2:hexanes (3:7)) to give 1b (2.81 g, 74% yield) as a red glassy solid
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2:hexanes (3:7)) to give 1b (2.81 g, 74% yield) as a red glassy solid.
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The formation of the third-generation dendrimer from second-generation aryl iodide 2c and 2,4-bishydroxymethylphenylallylether (9) proved to be problematic, as no third-generation dendrimer was detected in the crude mixture after 21 days of reaction time under the standard reaction conditions.
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78049513271
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4 with the heterogeneous Pd/C catalyst
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4 with the heterogeneous Pd/C catalyst.
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