LIX®63 stability in the presence of Versatic 10 under proposed commercial extract and strip conditions, part III: Effect of manganese and cobalt loading on oxime stability at 30 °c

Hydrometallurgy

Volumn 104, Issue 2, 2010, Pages 268-277

  Barnard, K R ^a   Turner, N L ^a   Shiers, D W ^a  

^a CSIRO   (Australia)

Author keywords

5,8 diethyl 7 hydroxydodecan 6 oxime; Degradation; Isomer inter conversion; LIX63; Manganese; Solvent extraction; Stability; Synergist

Indexed keywords

5,8-DIETHYL-7-HYDROXYDODECAN-6-OXIME; ADVERSE EFFECT; AQUEOUS SOLUTIONS; CO CONCENTRATIONS; CO LOADING; COBALT LOADING; COMMERCIAL EXTRACTS; CONVERSION PROCESS; DIFFERENT MECHANISMS; HALF LIVES; HIGH TEMPERATURE; LIX63; LOW MANGANESE; MAXIMUM LOADING; RAPID DEGRADATION; RAPID PROCESS; RE-EQUILIBRATION; SYNERGIST; SYNERGISTIC PROPERTIES; ZINC METAL;

CARBOXYLIC ACIDS; CHEMICAL STABILITY; COBALT; COBALT COMPOUNDS; DEGRADATION; ISOMERS; LOADING; MANGANESE; SOLUTIONS; SOLVENT EXTRACTION; SOLVENTS; STOICHIOMETRY; ZINC;

PH EFFECTS;

EID: 78049427022     PISSN: 0304386X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.hydromet.2010.06.015     Document Type: Article

References (27)

1. ®63 stability in the presence of Versatic 10 under proposed commercial extract and strip conditions, part I: Operation at high temperature Hydrometallurgy 91 2008 1 10
2. K.R. Barnard Isolation and characterisation of the LIX®63 degradation product 5, 8-diethyl-6, 7-dodecandione monooxime (keto-oxime) and 5, 8-diethyl-6, 7-dodecanediol (diol) and regeneration of oxime from keto-oxime Hydrometallurgy 90 2008 147 153
3. ®63 oxime and Versatic 10, part III: Nickel Laterite case study B.A. Moyer, SOLVENT EXTRACTION: Fundamentals to Industrial Applications, Proceedings of ISEC 2008 International Solvent Extraction Conference Vol 1 2008 CIMMP Quebec 125 130
4. ®63 stability in the presence of Versatic 10 under proposed commercial extract and strip conditions, part II: Oxime isomer inter-conversion and the effect of oxime degradation products on selected physical properties Hydrometallurgy 91 2008 11 19
5. ®63 oxime and Versatic 10, part II: The El Boleo case study B.A. Moyer, SOLVENT EXTRACTION: Fundamentals to Industrial Applications, Proceedings of ISEC 2008 International Solvent Extraction Conference Vol 1 2008 CIMMP Quebec 119 124
6. ®63 stability under harsh strip conditions and isolation of a diketone degradation product Hydrometallurgy 89 2007 40 51
7. Barnard, K.R., Nealon, G.L., Ogden, M.I., Skelton, B.W., submitted for publication. Crystallographic determination of three Ni-α-hydroxyoxime- carboxylic acid synergist complexes. Solvent Extr. Ion Exch.
8. C.Y. Cheng Solvent extraction of nickel and cobalt with synergistic systems consisting of carboxylic acid and aliphatic hydroxyoxime Hydrometallurgy 84 2006 109 117
9. C.Y. Cheng, C.A. Hughes, K.R. Barnard, and K. Larcombe Manganese in copper solvent extraction and electrowinning Hydrometallurgy 58 2000 135 150
10. C.Y. Cheng, K.R. Barnard, and M.D. Urbani Improving Plant Operations Using Synergistic Solvent Extraction Technology and Organic Monitoring Proc. First Extractive Metallurgy Operators' Conference 2005 AUSIMM Victoria 59 66
11. D. Dreisinger, E. Norton, R. Molnar, K. Baxter, M. Holmes, and J. Riordan The Recovery Of Zinc From Baja Mining Corp's El Boleo Orebody L. Centomo, M. Collins, J. Harlamovs, J. Liu, Zinc and Lead Metallurgy 2008 CIMMP Canada 343 357
12. M.P. Elizalde, J.M. Castresana, M. Aguilar, and M. Cox Synergic extraction of Ni(II) by mixtures of 5, 8-diethyl-7-hydroxydodecan-6-oxime and n-dodecanoic acid in toluene Solvent Extr. Ion Exch. 4 6 1986 1095 1107
13. D.S. Flett, M. Cox, and J.D. Heels Extraction of nickel by α-hydroxy oxime/lauric acid mixtures Proc. ISEC '74 Vol 3 1974 Society of Chemical Industry London 2560 2575
14. K. Inoue, P. Zhang, Y. Koga, and H. Eguchi Development of Synergistic Solvent Extraction System for the Recovery of Nickel and Cobalt from Spent Hydrodesulfurization Catalysts W.C. Cooper, I. Mihaylov, Nickel-Cobalt '97 Vol I: Hydrometallurgy and Refining of Nickel and Cobalt 1997 CIMMP Montreal 221 233
15. G.M. Miller The Problem with Manganese and its Effects on Copper SX-EW Operations W.C. Cooper, D.B. Dreisinger, J.E. Dutrizac, H. Hein, G. Ugarte, Proc. Copper 95-Cobre 95 Int. Conf Met. Soc. CIM Vol. III 1995 649 663
16. ®65N and Dowfax 2AO interaction in copper solvent extraction and electrolysis Can. Metall. Quart. 15 4 1976 383 388
17. K. Osseo-Asare, and D.R. Renninger Synergic extraction of nickel and cobalt by Lix63-dinonylnaphthalene sulfonic-acid mixtures Hydrometallurgy 13 1 1984 45 62
18. J.S. Preston Alpha-substituted oxime extractants - I. Extraction of Cu(II), Ni(II), Co(II) and Fe(III) by aliphatic alpha hydroxyoximes J. Inorg. Nucl. Chem. 37 1975 1235 1242
19. J.S. Preston Solvent extraction of nickel and cobalt by mixtures of carboxylic acids and non-chelating oximes Hydrometallurgy 11 1983 105 124
20. J.S. Preston, and A.C. Du Preez The solvent extraction of nickel and cobalt by mixtures of carboxylic acids and pyridinecarboxylate esters Solvent Extr. Ion Exch. 13 1995 465 494
21. J.S. Preston, and A.C. Du Preez Synergistic effects in solvent-extraction systems based on alkylsalicylic acids.2. Extraction of nickel, cobalt, cadmium and zinc in the presence of some neutral N-, O- and S-donor compounds Solvent Extr. Ion Exch. 14 1996 179 201
22. M. Takahashi, T. Ogata, H. Okino, and Y. Abe The deterioration of nickel extractant LIX64N and its regeneration, Int. Solv. Extr. Conf. AICHE ISEC '83, metallurgical extraction processes II-process chemistry Am. Inst. Chem. Eng. 1 1983 359 360
23. T. Tammi Extraction of nickel and cobalt with hydroxyoxime-containing extraction agents Tutkimus Tek 4 1976 44 45
24. T.T. Tammi Separation of the isomers of the commercial α-hydroxyoxime LIX 63 Hydrometallurgy 2 1977 371 380
25. M. Virnig, M. Eyzaguirre, M. Jo, and J. Calderon Effects of Nitrate on Copper SX Circuits: A Case Study P.A. Riveros, D.G. Dixon, D.B. Dresinger, J.M. Menacho, Proc. Copper 2003-Cobre 2003, 5th Int. Conf., Vol. VI-Hydrometallurgy of Copper (Book 2), Met. Soc. CIM 2003 795 810
26. J.N. West, and J.W. Connor Nifty - Hydrometallurgy in the Sand Dunes Proc. AusIMM 1996 Annual Conf 1996 Perth. AusIMM Carlton 181 183
27. W.J.A. Yeo, J. Wyche, M. Holmes, E. Norton, D. Hunter, T. Ross, S. Britton, and G. Bosworth Baja Mining Corp. El Boleo Project Feasibility Study Summary Report 2007 Report 43-101, http://www.bajamining.com/boleo/dfs-update/, accessed 23/3/2010