-
1
-
-
0000275815
-
Anions of protected cyanohydrins as acyl carbanion equivalents and their use in a new synthesis of ketones
-
Stork, G. & Maldonado, L. Anions of protected cyanohydrins as acyl carbanion equivalents and their use in a new synthesis of ketones. J. Am. Chem. Soc. 93, 5286-5287 (1971).
-
(1971)
J. Am. Chem. Soc.
, vol.93
, pp. 5286-5287
-
-
Stork, G.1
Maldonado, L.2
-
2
-
-
84985109473
-
Nucleophile acylation with masked acyl anions; III. Synthesis of alpha-hydroxy ketones
-
Hünig, S. & Wehner, G. Nucleophile acylation with masked acyl anions; III. Synthesis of alpha-hydroxy ketones. Synthesis 391-392 (1975).
-
(1975)
Synthesis
, pp. 391-392
-
-
Hünig, S.1
Wehner, G.2
-
3
-
-
84989473692
-
Nucleophilic acylation with masked acyl anions II
-
Hünig, S. & Wehner, G. Nucleophilic acylation with masked acyl anions II. Synthesis 180-182 (1975).
-
(1975)
Synthesis
, pp. 180-182
-
-
Hünig, S.1
Wehner, G.2
-
4
-
-
0010225470
-
Nucleophilic acylation with masked acyl anions
-
Deuchert, K., Hertenstein, U. & Hünig, S. Nucleophilic acylation with masked acyl anions. Synthesis 777-778 (1973).
-
(1973)
Synthesis
, pp. 777-778
-
-
Deuchert, K.1
Hertenstein, U.2
Hünig, S.3
-
5
-
-
0001537080
-
Reactions of acyl anion equivalents derived from cyanohydrins, protected cyanohydrins and alpha-dialkylaminonitriles
-
Albright, J. D. Reactions of acyl anion equivalents derived from cyanohydrins, protected cyanohydrins and alpha-dialkylaminonitriles. Tetrahedron 39, 3207-3233 (1983).
-
(1983)
Tetrahedron
, vol.39
, pp. 3207-3233
-
-
Albright, J.D.1
-
6
-
-
0030851129
-
Stereoselective umpolung reactions with metalated P-chiral cyanohydrin phosphates - Enantioselective synthesis of tertiary cyanohydrins
-
Schrader, T. Stereoselective umpolung reactions with metalated P-chiral cyanohydrin phosphates - enantioselective synthesis of tertiary cyanohydrins. Chem. Eur. J. 3, 1273-1282 (1997).
-
(1997)
Chem. Eur. J.
, vol.3
, pp. 1273-1282
-
-
Schrader, T.1
-
7
-
-
0002237394
-
Some molecular rearrangements of organosilicon compounds
-
Brook, A. G. Some molecular rearrangements of organosilicon compounds. Acc. Chem. Res. 7, 77-84 (1974).
-
(1974)
Acc. Chem. Res.
, vol.7
, pp. 77-84
-
-
Brook, A.G.1
-
8
-
-
0035835953
-
The Brook rearrangement in tandem bond formation strategies
-
Moser, W. H. The Brook rearrangement in tandem bond formation strategies. Tetrahedron 57, 2065-2084 (2001).
-
(2001)
Tetrahedron
, vol.57
, pp. 2065-2084
-
-
Moser, W.H.1
-
9
-
-
0000236161
-
Acylsilane-mediated nucleophilic acylation of alpha, beta-unsaturated carbonyl derivatives
-
Deglinnocenti, A., Ricci, A., Mordini, A., Reginato, G. & Colotta, V. Acylsilane-mediated nucleophilic acylation of alpha, beta-unsaturated carbonyl derivatives. Gazz. Chim. Ital. 117, 645-648 (1987).
-
(1987)
Gazz. Chim. Ital.
, vol.117
, pp. 645-648
-
-
Deglinnocenti, A.1
Ricci, A.2
Mordini, A.3
Reginato, G.4
Colotta, V.5
-
10
-
-
0001622693
-
Acylsilane chemistry - Synthesis of regioisomerically and stereoisomerically defined enol silyl ethers using acylsilanes
-
Reich, H. J., Holtan, R. C. & Bolm, C. Acylsilane chemistry - synthesis of regioisomerically and stereoisomerically defined enol silyl ethers using acylsilanes. J. Am. Chem. Soc. 112, 5609-5617 (1990).
-
(1990)
J. Am. Chem. Soc.
, vol.112
, pp. 5609-5617
-
-
Reich, H.J.1
Holtan, R.C.2
Bolm, C.3
-
11
-
-
0034729469
-
Reaction of acylsilanes with potassium cyanide: Brook rearrangement under phase-transfer catalytic conditions
-
Takeda, K. & Ohnishi, Y. Reaction of acylsilanes with potassium cyanide: Brook rearrangement under phase-transfer catalytic conditions. Tetrahedron Lett. 41, 4169-4172 (2000).
-
(2000)
Tetrahedron Lett.
, vol.41
, pp. 4169-4172
-
-
Takeda, K.1
Ohnishi, Y.2
-
12
-
-
0038001592
-
Kinetic control in direct alpha-silyloxy ketone synthesis: A new regiospecific catalyzed cross silyl benzoin reaction
-
Linghu, X. & Johnson, J. S. Kinetic control in direct alpha-silyloxy ketone synthesis: a new regiospecific catalyzed cross silyl benzoin reaction. Angew. Chem. Int. Ed. 42, 2534-2536 (2003).
-
(2003)
Angew. Chem. Int. Ed.
, vol.42
, pp. 2534-2536
-
-
Linghu, X.1
Johnson, J.S.2
-
13
-
-
13644254491
-
Mechanism and scope of the cyanide-catalyzed cross silyl benzoin reaction
-
Linghu, X., Bausch, C. C. & Johnson, J. S. Mechanism and scope of the cyanide-catalyzed cross silyl benzoin reaction. J. Am. Chem. Soc. 127, 1833-1840 (2005).
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 1833-1840
-
-
Linghu, X.1
Bausch, C.C.2
Johnson, J.S.3
-
14
-
-
2942548464
-
Catalytic asymmetric acylation of (silyloxy)nitrile anions
-
Nicewicz, D. A., Yates, C. M. & Johnson, J. S. Catalytic asymmetric acylation of (silyloxy)nitrile anions. Angew. Chem. Int. Ed. 43, 2652-2655 (2004).
-
(2004)
Angew. Chem. Int. Ed.
, vol.43
, pp. 2652-2655
-
-
Nicewicz, D.A.1
Yates, C.M.2
Johnson, J.S.3
-
15
-
-
4644246440
-
Enantioselective cyanation/Brook rearrangement/C-acylation reactions of acylsilanes catalyzed by chiral metal alkoxides
-
Nicewicz, D. A., Yates, C. M. & Johnson, J. S. Enantioselective cyanation/Brook rearrangement/C-acylation reactions of acylsilanes catalyzed by chiral metal alkoxides. J. Org. Chem. 69, 6548-6555 (2004).
-
(2004)
J. Org. Chem.
, vol.69
, pp. 6548-6555
-
-
Nicewicz, D.A.1
Yates, C.M.2
Johnson, J.S.3
-
16
-
-
1642295713
-
Metallophosphites as umpolung catalysts: The enantioselective cross silyl benzoin reaction
-
Linghu, X., Potnick, J. R. & Johnson, J. S. Metallophosphites as umpolung catalysts: the enantioselective cross silyl benzoin reaction. J. Am. Chem. Soc. 126, 3070-3071 (2004).
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 3070-3071
-
-
Linghu, X.1
Potnick, J.R.2
Johnson, J.S.3
-
17
-
-
0037120881
-
Development of a donor2acceptor concept for enzymatic cross-coupling reactions of aldehydes: The first asymmetric cross-benzoin condensation
-
Dunkelmann, P. et al. Development of a donor2acceptor concept for enzymatic cross-coupling reactions of aldehydes: the first asymmetric cross-benzoin condensation. J. Am. Chem. Soc. 124, 12084-12085 (2002).
-
(2002)
J. Am. Chem. Soc.
, vol.124
, pp. 12084-12085
-
-
Dunkelmann, P.1
-
18
-
-
69849086129
-
Asymmetric tandem Wittig rearrangement/aldol reactions
-
Giampietro, N. C., Kampf, J. W. & Wolfe, J. P. Asymmetric tandem Wittig rearrangement/aldol reactions. J. Am. Chem. Soc. 131, 12556-12557 (2009).
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 12556-12557
-
-
Giampietro, N.C.1
Kampf, J.W.2
Wolfe, J.P.3
-
19
-
-
77953041832
-
Direct asymmetric aldol reaction of 5H-oxazol-4-ones with aldehydes catalyzed by chiral guanidines
-
Misaki, T., Takimoto, G. & Sugimura, T. Direct asymmetric aldol reaction of 5H-oxazol-4-ones with aldehydes catalyzed by chiral guanidines. J. Am. Chem. Soc. 132, 6286-6287 (2010).
-
(2010)
J. Am. Chem. Soc.
, vol.132
, pp. 6286-6287
-
-
Misaki, T.1
Takimoto, G.2
Sugimura, T.3
-
20
-
-
0035819981
-
Stereoselective generation of E- and Z-disubstituted amide enolates. Reductive enolate formation from bicylic thioglycolate lactams
-
Manthorpe, J. M. & Gleason, J. L. Stereoselective generation of E- and Z-disubstituted amide enolates. Reductive enolate formation from bicylic thioglycolate lactams. J. Am. Chem. Soc. 123, 2091-2092 (2001).
-
(2001)
J. Am. Chem. Soc.
, vol.123
, pp. 2091-2092
-
-
Manthorpe, J.M.1
Gleason, J.L.2
-
21
-
-
67949106332
-
A unique approach to aldol products for the creation of all-carbon quaternary stereocentres
-
Das, J. P., Chechik, H. & Marek, I. A unique approach to aldol products for the creation of all-carbon quaternary stereocentres. Nature Chem. 1, 128-132 (2009).
-
(2009)
Nature Chem.
, vol.1
, pp. 128-132
-
-
Das, J.P.1
Chechik, H.2
Marek, I.3
-
22
-
-
0030776295
-
Chiral Lewis acid controlled synthesis (CLAC synthesis): Chiral Lewis acids influence the reaction course in asymmetric aldol reactions for the synthesis of enantiomeric dihydroxythioester derivatives in the presence of chiral diamines derived from L-proline
-
Kobayashi, S. & Horibe, M. Chiral Lewis acid controlled synthesis (CLAC synthesis): chiral Lewis acids influence the reaction course in asymmetric aldol reactions for the synthesis of enantiomeric dihydroxythioester derivatives in the presence of chiral diamines derived from L-proline. Chem. Eur. J. 3, 1472-1481 (1997).
-
(1997)
Chem. Eur. J.
, vol.3
, pp. 1472-1481
-
-
Kobayashi, S.1
Horibe, M.2
-
23
-
-
41949101219
-
Lewis base activation of Lewis acids: Catalytic enantioselective glycolate aldol reactions
-
Denmark, S. E. & Chung, W. J. Lewis base activation of Lewis acids: catalytic enantioselective glycolate aldol reactions. Angew. Chem. Int. Ed. 47, 1890-1892 (2008).
-
(2008)
Angew. Chem. Int. Ed.
, vol.47
, pp. 1890-1892
-
-
Denmark, S.E.1
Chung, W.J.2
-
24
-
-
45249085012
-
Lewis base activation of Lewis acids: Catalytic, enantioselective addition of glycolate-derived silyl ketene acetals to aldehydes
-
Denmark, S. E. & Chung, W. J. Lewis base activation of Lewis acids: catalytic, enantioselective addition of glycolate-derived silyl ketene acetals to aldehydes. J. Org. Chem. 73, 4582-4595 (2008).
-
(2008)
J. Org. Chem.
, vol.73
, pp. 4582-4595
-
-
Denmark, S.E.1
Chung, W.J.2
-
25
-
-
36849060666
-
Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes
-
Denmark, S. E., Wilson, T. W., Burk, M. T. & Heemstra, J. R. Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes. J. Am. Chem. Soc. 129, 14864-14865 (2007).
-
(2007)
J. Am. Chem. Soc.
, vol.129
, pp. 14864-14865
-
-
Denmark, S.E.1
Wilson, T.W.2
Burk, M.T.3
Heemstra, J.R.4
-
26
-
-
13744263466
-
Nucleophile-catalyzed asymmetric acylations of silyl ketene imines: Application to the enantioselective synthesis of verapamil
-
Mermerian, A. H. & Fu, G. C. Nucleophile-catalyzed asymmetric acylations of silyl ketene imines: application to the enantioselective synthesis of verapamil. Angew. Chem. Int. Ed. 44, 949-952 (2005).
-
(2005)
Angew. Chem. Int. Ed.
, vol.44
, pp. 949-952
-
-
Mermerian, A.H.1
Fu, G.C.2
-
27
-
-
0001055781
-
On the metalation silylation of O-trimethylsilyl aldehyde cyanohydrins
-
Cunico, R. F. & Kuan, C. P. On the metalation silylation of O-trimethylsilyl aldehyde cyanohydrins. J. Org. Chem. 57, 1202-1205 (1992).
-
(1992)
J. Org. Chem.
, vol.57
, pp. 1202-1205
-
-
Cunico, R.F.1
Kuan, C.P.2
-
28
-
-
0003525986
-
Synthesis of alpha-alkoxyacrylonitriles using substituted diethyl cyanomethylphosphonates
-
Dinizo, S. E., Freerksen, R. W., Pabst, W. E. & Watt, D. S. Synthesis of alpha-alkoxyacrylonitriles using substituted diethyl cyanomethylphosphonates. J. Org. Chem. 41, 2846-2849 (1976).
-
(1976)
J. Org. Chem.
, vol.41
, pp. 2846-2849
-
-
Dinizo, S.E.1
Freerksen, R.W.2
Pabst, W.E.3
Watt, D.S.4
-
30
-
-
0001319213
-
The silylation of nitrile anions - Silyl ketene imines
-
Watt, D. S. The silylation of nitrile anions - silyl ketene imines. Synth. Commun. 4, 127-132 (1974).
-
(1974)
Synth. Commun.
, vol.4
, pp. 127-132
-
-
Watt, D.S.1
-
31
-
-
0006987160
-
Oxidative decyanation of arylacetonitriles - Synthesis of ligusticumic acid
-
Watt, D. S. Oxidative decyanation of arylacetonitriles - synthesis of ligusticumic acid. J. Org. Chem. 39, 2799-2800 (1974).
-
(1974)
J. Org. Chem.
, vol.39
, pp. 2799-2800
-
-
Watt, D.S.1
-
32
-
-
78049349973
-
Alpha-germylated nitriles
-
Belousova, L. I., Kruglaya, O. A., Kalikhman, I. D. & Vyazankin, N. S. Alpha-germylated nitriles. J. Gen. Chem. USSR 51, 678-683 (1981).
-
(1981)
J. Gen. Chem. USSR
, vol.51
, pp. 678-683
-
-
Belousova, L.I.1
Kruglaya, O.A.2
Kalikhman, I.D.3
Vyazankin, N.S.4
-
33
-
-
31944440611
-
Lewis base activation of Lewis acids. Vinylogous aldol addition reactions of conjugated N, O-silyl ketene acetals to aldehydes
-
Denmark, S. E. & Heemstra, J. R. Lewis base activation of Lewis acids. Vinylogous aldol addition reactions of conjugated N, O-silyl ketene acetals to aldehydes. J. Am. Chem. Soc. 128, 1038-1039 (2006).
-
(2006)
J. Am. Chem. Soc.
, vol.128
, pp. 1038-1039
-
-
Denmark, S.E.1
Heemstra, J.R.2
-
34
-
-
0034832840
-
Lewis base activation of Lewis acids: Catalytic enantioselective allylation and propargylation of aldehydes
-
Denmark, S. E. & Wynn, T. Lewis base activation of Lewis acids: catalytic enantioselective allylation and propargylation of aldehydes. J. Am. Chem. Soc. 123, 6199-6200 (2001).
-
(2001)
J. Am. Chem. Soc.
, vol.123
, pp. 6199-6200
-
-
Denmark, S.E.1
Wynn, T.2
-
35
-
-
0141853189
-
Lewis base activation of Lewis acids. Catalytic enantioselective addition of silyl enol ethers of achiral methyl ketones to aldehydes
-
Denmark, S. E. & Heemstra, J. R. Lewis base activation of Lewis acids. Catalytic enantioselective addition of silyl enol ethers of achiral methyl ketones to aldehydes. Org. Lett. 5, 2303-2306 (2003).
-
(2003)
Org. Lett.
, vol.5
, pp. 2303-2306
-
-
Denmark, S.E.1
Heemstra, J.R.2
-
36
-
-
28044462675
-
Catalytic, enantioselective alpha-additions of isocyanides: Lewis base catalyzed Passerini-type reactions
-
Denmark, S. E. & Fan, Y. Catalytic, enantioselective alpha-additions of isocyanides: Lewis base catalyzed Passerini-type reactions. J. Org. Chem. 70, 9667-9676 (2005).
-
(2005)
J. Org. Chem.
, vol.70
, pp. 9667-9676
-
-
Denmark, S.E.1
Fan, Y.2
-
37
-
-
15744387149
-
Lewis base activation of Lewis acids: Catalytic, enantioselective addition of silyl ketene acetals to aldehydes
-
Denmark, S. E., Beutner, G. L., Wynn, T. & Eastgate, M. D. Lewis base activation of Lewis acids: catalytic, enantioselective addition of silyl ketene acetals to aldehydes. J. Am. Chem. Soc. 127, 3774-3789 (2005).
-
(2005)
J. Am. Chem. Soc.
, vol.127
, pp. 3774-3789
-
-
Denmark, S.E.1
Beutner, G.L.2
Wynn, T.3
Eastgate, M.D.4
-
38
-
-
0038805152
-
Lewis base activation of Lewis acids. Vinylogous aldol reactions
-
Denmark, S. E. & Beutner, G. L. Lewis base activation of Lewis acids. Vinylogous aldol reactions. J. Am. Chem. Soc. 125, 7800-7801 (2003).
-
(2003)
J. Am. Chem. Soc.
, vol.125
, pp. 7800-7801
-
-
Denmark, S.E.1
Beutner, G.L.2
-
39
-
-
34547130040
-
Lewis base activation of Lewis acids: Catalytic, enantioselective vinylogous aldol addition reactions
-
Denmark, S. E. & Heemstra, J. R. Lewis base activation of Lewis acids: catalytic, enantioselective vinylogous aldol addition reactions. J. Org. Chem. 72, 5668-5688 (2007).
-
(2007)
J. Org. Chem.
, vol.72
, pp. 5668-5688
-
-
Denmark, S.E.1
Heemstra, J.R.2
-
40
-
-
50249134990
-
Lewis base catalysis in organic synthesis
-
Denmark, S. E. & Beutner, G. L. Lewis base catalysis in organic synthesis. Angew. Chem. Int. Ed. 47, 1560-1638 (2008).
-
(2008)
Angew. Chem. Int. Ed.
, vol.47
, pp. 1560-1638
-
-
Denmark, S.E.1
Beutner, G.L.2
-
41
-
-
77953907329
-
Construction of quarternary stereogenic carbon centers by the Lewis base catalyzed conjugate addition of silyl ketene imines to a, b-unsaturated aldehydes and ketones
-
Denmark, S. E. & Wilson, T. W. Construction of quarternary stereogenic carbon centers by the Lewis base catalyzed conjugate addition of silyl ketene imines to a, b-unsaturated aldehydes and ketones. Synlett. 1723-1728 (2010).
-
(2010)
Synlett
, pp. 1723-1728
-
-
Denmark, S.E.1
Wilson, T.W.2
-
44
-
-
34248548522
-
Independent generation of C5'-nucleosidyl radicals in thymidine and 2'-deoxyguanosine
-
Manetto, A. et al. Independent generation of C5'-nucleosidyl radicals in thymidine and 2'-deoxyguanosine. J. Org. Chem. 72, 3659-3666 (2007).
-
(2007)
J. Org. Chem.
, vol.72
, pp. 3659-3666
-
-
Manetto, A.1
-
45
-
-
69049110960
-
On the mechanism of Lewis base catalyzed aldol addition reactions: Kinetic and spectroscopic investigations using rapid-injection NMR
-
Denmark, S. E., Eklov, B. M., Yao, P. J. & Eastgate, M. D. On the mechanism of Lewis base catalyzed aldol addition reactions: kinetic and spectroscopic investigations using rapid-injection NMR. J. Am. Chem. Soc. 131, 11770-11787 (2009).
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 11770-11787
-
-
Denmark, S.E.1
Eklov, B.M.2
Yao, P.J.3
Eastgate, M.D.4
-
46
-
-
0037421267
-
Highly efficient extractive biocatalysis in the asymmetric reduction of an acyclic enone by the yeast Pichia stipitis
-
Conceicao, G. J. A., Moran, P. J. S. & Rodrigues, J. A. R. Highly efficient extractive biocatalysis in the asymmetric reduction of an acyclic enone by the yeast Pichia stipitis. Tetrahedron Asymm. 14, 43-45 (2003).
-
(2003)
Tetrahedron Asymm.
, vol.14
, pp. 43-45
-
-
Conceicao, G.J.A.1
Moran, P.J.S.2
Rodrigues, J.A.R.3
|