Kinetic and theoretical study of the hydrodechlorination of CH 4- xClx (x = 1-4) compounds on palladium

Langmuir

Volumn 26, Issue 21, 2010, Pages 16615-16624

  Chen, Nan ^a,d   Rioux, Robert M ^b   Barbosa, Luis A M M ^c,e   Ribeiro, Fabio H ^a  

^a PURDUE UNIVERSITY   (United States)

^b The Pennsylvania State University   (United States)

^c EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

^d CHEVRON ENERGY TECHNOLOGY COMPANY   (United States)

^e MEDTRONIC INC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBED MOLECULES; BOND ENERGIES; CHLORINATED COMPOUNDS; CHLORINATED METHANE; DFT CALCULATION; DISSOCIATION ENERGIES; GASPHASE; H-D EXCHANGE; HYDRODECHLORINATION; ISOTOPE EXCHANGE; KINETIC MODELING; LANGMUIR-HINSHELWOOD; MULTI-PATH; PARALLEL REACTIONS; PARAMETERS ESTIMATED; RATE DETERMINING STEP; REACTION MECHANISM; SURFACE INTERMEDIATES; THEORETICAL STUDY;

ACTIVATION ENERGY; ASSOCIATION REACTIONS; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; DEUTERIUM; DISSOCIATION; METHANE; PALLADIUM; REACTION RATES; SULFUR COMPOUNDS;

CHLORINE COMPOUNDS;

CHLORINATED HYDROCARBON; PALLADIUM;

ADSORPTION; ARTICLE; CHEMISTRY; KINETICS; MOLECULAR DYNAMICS; PARTICLE SIZE; SURFACE PROPERTY; SYNTHESIS;

ADSORPTION; HYDROCARBONS, CHLORINATED; KINETICS; MOLECULAR DYNAMICS SIMULATION; PALLADIUM; PARTICLE SIZE; SURFACE PROPERTIES;

EID: 78049281960     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la1020753     Document Type: Article

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