Simulation of polymerization kinetics and molecular weight development in the microwave-activated emulsion polymerization of styrene using EMULPOLY®

Chemical Engineering and Technology

Volumn 33, Issue 11, 2010, Pages 1888-1892

  Jaramillo Soto, G ^a   Ramirez Cupido M ^b   Tenorio Lopez J A ^b   Vivaldo Lima, E ^a   Penlidis, A ^c  

^a Universidad Nacional Autonoma de Mexico Facultad de Quimica   (Mexico)

^b UNIVERSIDAD VERACRUZANA   (Mexico)

^c UNIVERSITY OF WATERLOO   (Canada)

Author keywords

Emulsion polymerization; Microwave activated polymerization; Microwave assisted syntheses; Simulation

Indexed keywords

CONDUCTIVE HEATING; DECOMPOSITION KINETICS; EXPERIMENTAL DATA; IRRADIATION POWER; KINETIC RATE CONSTANTS; MICROWAVE ACTIVATION; MICROWAVE POWER; MICROWAVE-ASSISTED SYNTHESES; MODEL PARAMETERS; MODEL PREDICTION; MONOMER CONVERSIONS; PARTICLE NUMBERS; POLYMERIZATION KINETICS; SIMULATED PROFILE; SIMULATION; SIMULATION PACKAGES; SIMULATOR DATABASE; THERMALLY ACTIVATED; UNIVERSITY OF WATERLOO; WEIGHT-AVERAGE MOLECULAR WEIGHT;

COMPUTER SIMULATION; EMULSIFICATION; EMULSION POLYMERIZATION; IRRADIATION; MOLECULAR WEIGHT; POLYMERS; RATE CONSTANTS; STYRENE;

MICROWAVE IRRADIATION;

EID: 77958548494     PISSN: 09307516     EISSN: 15214125     Source Type: Journal    
DOI: 10.1002/ceat.201000251     Document Type: Article

References (13)

1. E. Saldívar, P. Dafniotis, W. H. Ray, J. Macromol. Sci., Rev. Macromol. Chem. Phys. 1998, C38 (2), 207. DOI: 10.1080/15583729808544528
2. J. Gao, A. Penlidis, Prog. Polym. Sci. 2002, 27, 403. DOI: 10.1016/S0079-6700(01)00044-2
3. W. Xu, X. Zhu, Z. Cheng, G. Chen, J. Lu, Eur. Polym. J. 2003, 39, 1349. DOI: 10.1016/S0014-3057(03)00038-7
4. F. Wiesbrock, R. Hoogenboom, U. S. Schubert, Macromol. Rapid Commun. 2004, 25, 1739. DOI: 10.1002/marc.200400313
5. R. Hoogenboom, U. S. Schubert, Macromol. Rapid Commun. 2007, 28, 368. DOI: 10.1002/marc.200600749
6. J. Palacios, C. Valverde, New Polym. Mater. 1996, 5 (1), 93.
7. R. Correa, G. Gonzalez, V. Dougar, Polymer 1998, 39 (6/7), 1471. DOI: 10.1016/S0032-3861(97)00413-8
8. X. Zhu, J. Chen, Z. Cheng, J. Lu, J. Zhu, J. Appl. Polym. Sci. 2003, 89, 28. DOI: 10.1002/app.12089
9. M. A. Aldana, J. Palacios, E. Vivaldo-Lima, J. Macromol. Sci., Part A: Pure Appl. Chem. 2005, 42, 1207. DOI: 10.1080/10601320500189505
10. P. A. Lovell, M. S. El-Aasser, Emulsion Polymerization and Polymers, John Wiley & Sons, New York 1997.
11. V. S. Ivanov, Radiation Chemistry of Polymers, VSP, Utrecht 1992.
12. M. Buback et al., Macromol. Chem. Phys. 1995, 196, 3267. DOI: 10.1002/macp.1995.021961016
13. G. V. Aguilar, A. Y. Almanza, B.Sc. Thesis, Universidad Nacional Autónoma de México, México D.F. 2002.