The reaction kinetics of a fischer-tropsch synthesis over a commercial eggshell Co/SiO2 catalyst

Petroleum Science and Technology

Volumn 28, Issue 18, 2010, Pages 1834-1845

  Lu, F ^a   Zhang, H ^a   Ying, W ^a   Fang, D ^a  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

eggshell Co SiO2 catalyst; Fischer Tropsch synthesis; hydrocarbon kinetics

Indexed keywords

EGGSHELL CO/SIO2 CATALYST; FISCHER TROPSCH; FIXED-BED REACTORS; GROWTH PROBABILITY; KINETIC MODELS; KINETIC RATES; OPERATING CONDITION; PARAMETER EVALUATION; PILOT SCALE; PRODUCT DISTRIBUTIONS;

CATALYSTS; CHEMICAL REACTORS; HYDROCARBONS; REACTION KINETICS;

FISCHER-TROPSCH SYNTHESIS;

EID: 77958170741     PISSN: 10916466     EISSN: 15322459     Source Type: Journal    
DOI: 10.1080/10916460903261756     Document Type: Article

References (18)

1. Anderson, R. B. (1984). The Fischer-Tropsch Synthesis. Orlando, FL: Academic Press.
2. Biloen, P., and Sachtler, W. M. H. (1981). Mechanism of hydrocarbon synthesis over Fischer-Tropsch catalysts. Adv. Catal. 30:65-216.
3. Donnelly, T. J., and Satterfield, C. N. (1989). Product distributions of the Fischer-Tropsch synthesis on precipitated iron catalyst. Appl. Catal. A 52:93-114.
4. Glebov, L. S., and Kliger, G. A. (1994). The molecular weight distribution of the products of the Fischer-Tropsch synthesis. Russ. Chem. Rev. 63:185-194.
5. Hindermann, J. P., Hutchings, G. J., and Kiennemann, A. (1993). Mechanistic aspects of the formation of hydrocarbon and alcohols from CO hydrogen. Catal. Rev. 35:1-127.
6. Keyser, M. J., Everson, R. C., and Esoinozat, R. L. (2000). Fischer-Tropsch kinetic studies with cobalt-maganese oxide catalysts. Ind. Eng. Chem. Res. 39:48-54.
7. Lox, E. S., and Froment, G. F. (1993). Kinetics of the Fischer-Tropsch reaction on a precipitated promoted iron catalyst. 1. Experimental procedure and results. Ind. Eng. Chem. Res. 32:61-70.
8. Ma, X. D., Sun, Q. W., Cao, F. H., Ying, W. Y., and Fang, D. Y. (2006). Effects of the different supports on the activity and selectivity of iron-cobalt bimetallic catalyst for Fischer-Tropsch synthesis. Natural Gas Chemical Industry 31(1):15-18.
9. Mark, E. D. (2002). The Fischer-Tropsch process: 1950-2000. Catal. Today 71:227-241.
10. Paskas, I., and Hurlbut, R. S. (2003). Comments about the causes of deviations from the Anderson-Schulz-Flory distribution of the Fischer-Tropsch reaction products. Catal. Today 84:99-109.
11. Rautavuoma, A. O. I., and Van der Baan, H. S. (1981). Kinetics and mechanism of the Fischer-Tropsch hydrocarbon synthesis on a cobalt on alumina catalyst. Appl. Catal. A 1:247-272.
12. Sarup, B., and Wojciechowski, B. W. (1989). Studies of the Fischer-Tropsch synthesis on a cobalt catalyst III. Mechanistic formulation of the kinetics of selectivity for higher hydrocarbon formation. Can. J. Chem. Eng. 67:62-74. (Pubitemid 20643457)
13. Van der Laan, G. P., and Beenackers, A. A. C. M. (1999). Kinetics and selectivity of the Fischer-Tropsch synthesis: A literature review. Catal. Rev. 41:255-315.
14. Vannice, M. A. (1975). The catalytic synthesis of hydrocarbons from H2/CO mixtures over the group VIII metals: II. The kinetics of the methanation reaction over supported metals. J. Catal. 37:462-473.
15. Van Steen, E., and Schulz, H. (1999). Polymerisation kinetics of the Fischer-Tropsch CO hydrogenation using iron and cobalt based catalysts. Appl. Catal. A 186:309-320. (Pubitemid 129532968)
16. Wei, J., and Kuo, J. C. W. (1969). A lumping analysis in monomolecular reaction systems. Analysis of the exact & lumpable system. Ind. Eng. Chem. Fund. 8(1):124-133.
17. Wojciechowski, B. W. (1988). The kinetics of the Fischer-Tropsch synthesis. Catal. Rev. 30:629-702.
18. Yates, I. C., and Satterfield, C. N. (1991). Intrinsic kinetics of the Fischer-Tropsch synthesis on a cobalt catalyst. Energy Fuels 5:168-173.