Hydrogen generation from aqueous acid-catalyzed hydrolysis of sodium borohydride

International Journal of Hydrogen Energy

Volumn 35, Issue 22, 2010, Pages 12239-12245

  Kim, Hyun Jae ^a   Shin, Kyoung Jin ^b   Kim, Hyun Jong ^b   Han, M K ^b   Kim, Hansung ^c   Shul, Yong Gun ^c   Jung, Kyeong Taek ^d  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

^b Korea Institute of Industrial Technology   (South Korea)

^c Yonsei University   (South Korea)

^d Gochen dong Uiwang si   (South Korea)

Author keywords

Aqueous acid; Hydrogen; Hydrogen generator; PEMFC; Performance loss; Sodium borohydride

Indexed keywords

AQUEOUS ACIDS; HYDROGEN GENERATOR; PEMFC; PERFORMANCE LOSS; SODIUM BOROHYDRIDE;

CATALYSIS; EXPERIMENTS; FUEL CELLS; GAS GENERATORS; HYDROLYSIS; METAL IONS; ORGANIC ACIDS; WATER VAPOR;

HYDROGEN PRODUCTION;

EID: 77958154432     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.08.027     Document Type: Article

References (21)

1. R.H. Jones, and G.J. Thomas Materials for hydrogen economy 2008 CRC Press Taylor & Francis Group xi-xvii p.
2. M. Dornheim, N. Eigen, G. Barkhordarian, T. Klassen, and R. Bormann Tailoring hydrogen storage materials towards application Adv Eng Mater 8 2006 377 385
3. A. Brockman, Y. Zheng, and J. Gore A study of catalytic hydrolysis of concentrated ammonia borane solution Int J Hydrogen Energy 35 2010 7350 7356
4. A.M. Seayad, and D.M. Antonelli Recent advances in hydrogen stroage in metal-containing inorganic nanostructures and related materials Adv Mater 16 2004 765 777
5. E.Y. Marrero-Alfonso, J.R. Gray, T.A. Davis, and M.A. Matthews Minimizing water utilization in hydrolysis of sodium borohydride: the role of sodium metaborate hydrates Int J Hydrogen Energy 32 2007 4723 4730
6. O. Akdim, U.B. Demirci, and P. Miele More reactive cobalt chloride in the hydrolysis of sodium borohydride Int J Hydrogen Energy 23 2009 9444 9449
7. S.C. Amendola, S.L. Sharp-Goldman, M.S. Janjua, N.C. Spencer, M.T. Kelly, and P.J. Petillo A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst Int J Hydrogen Energy 25 2000 969 975
8. D. Hua, Y. Hanxi, A. Xinping, and C. Chuansin Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst Int J Hydrogen Energy 28 2003 1095 1100
9. J.H. Kim, K.H. Choi, and Y.S. Choi Hydrogen generation from solid NaBH4 with catalytic solution for planar air-breathing proton exchange membrane fuel cells Int J Hydrogen Energy 35 2010 4015 4019
10. B.H. Liu, and Z.P. Li A review: hydrogen generation from borohydride hydrolysis reaction J Power Sources 187 2009 527 534
11. S. Galli, D. Francesco, G. Monteleone, R. Oronzio, and A. Pozio Development of a compact hydrogen generator from sodium borohydride Int J Hydrogen Energy 35 2010 7344 7349
12. Y. Liang, H.B. Dai, L.P. Ma, P. Wang, and H.M. Cheng Hydrogen generation from sodium borohydride solution using a ruthenium supported on graphite catalyst Int J Hydrogen Energy 35 2010 3023 3028
13. X. Yuan, H. Wang, J.C. Sun, and J. Zhang AC impedance technique in PEM fuel cell diagnosis Int J Hydrogen Energy 32 2007 4365 4380
14. J. St-Pierre, D.P. Wilkinson, S. Knights, and M.L. Bos Relationships between water management, contamination and lifetime degradation in PEFC J New Mater Electrochem Syst 3 2000 99 106
15. X. Cheng, Z. Shi, N. Glass, L. Zhang, J. Zhang, and D. Song A review of PEM hydrogen fuel cell contamination: impacts, mechanism, and mitigation J Power Sources 165 2007 739 756
16. H.L. Yeager, and A. Steck Cation and water diffusion in nafion ion exchange membranes: influence of polymer structure J Electrochem Soc 128 1981 1880 1884
17. Z. Samec, A. Trojanek, J. Langmaier, and E. Samcova Diffusion coefficients of alkali metal cations in nafion from ion-exchange measurements J Electrochem Soc 144 1997 4236 4242
18. + ions J Electroanal Chem 442 1998 137 145 (Pubitemid 128427583)
19. K. Kpomblekou, and M.A. Tabatabai Effect of organic acids on release of phosphorus from phosphate rocks Soil Sci 158 1994 442 453
20. A.A. Pohlman, and J.G. McColl Kinetics of metal dissolution from forest soils by soluble organic acids J Environ Qual 15 1986 86 92
21. H.I. Schlesinger, H.C. Brown, A.E. Finholt, J.R. Gilbreath, H.R. Hoekstra, and E.K. Hyde Borohydride: hydrolysis and its generation of hydrogen J Am Chem Soc 75 1953 215 219