Zirconium doped nano-dispersed oxides of Fe, Al and Zn for destruction of warfare agents

Materials Characterization

Volumn 61, Issue 11, 2010, Pages 1080-1088

  Štengl, Václav ^a   Houšková, Vendula ^a   Bakardjieva, Snejana ^a   Murafa, Nataliya ^a   Maříková, Monika ^a   Opluštil, František ^b   Němec, Tomáš ^b  

^a INSTITUTE OF INORGANIC CHEMISTRY   (Czech Republic)

^b Military Technical Institute of Protection Brno   (Czech Republic)

Author keywords

Homogeneous hydrolysis; Nano dispersed oxides; Transition metals; Urea; Warfare agents

Indexed keywords

AQUEOUS SOLUTIONS; BRUNAUER-EMMETT-TELLER SURFACE AREAS; CHEMICAL WARFARE AGENTS; DEGRADATION ACTIVITY; DOPED OXIDES; ENERGY DISPERSIVE X-RAY; EXPERIMENTAL EVALUATION; FERRIC SULPHATE; FERRIHYDRITES; HOMOGENEOUS HYDROLYSIS; METAL OXIDES; NANO-DISPERSED OXIDES; OXIDE SURFACE; SEM; SULFATE SALTS; SULFUR MUSTARD; SURFACE AREA; WARFARE AGENTS; ZR-DOPED;

ADSORPTION; CHEMICAL WARFARE; DEGRADATION; DOPING (ADDITIVES); HYDROLYSIS; INFRARED SPECTROSCOPY; IRON OXIDES; METABOLISM; SCANNING ELECTRON MICROSCOPY; SOLUTIONS; SULFUR; UREA; X RAY DIFFRACTION; ZINC; ZIRCONIUM;

TRANSITION METAL COMPOUNDS;

EID: 77958010128     PISSN: 10445803     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.matchar.2010.06.021     Document Type: Article

References (27)

1. M.A. Henderson, T. Jin, and J.M. White A TPD/AES study of the interaction of dimethyl methylphosphonate with alpha-Fe203 and Si02 J Phys Chem 90 1986 4607 4611
2. M.B. Mitchell, V.N. Sheinker, and E.A. Mintz Adsorption and decomposition of dimethyl methylphosphonate on metal oxides J Phys Chem B 101 1997 11192 11203
3. T.M. Tesfai, V.N. Sheinke, and M.B. Mitche Decomposition of dimethyl methylphosphonate (DMMP) on alumina-supported iron oxide J Phys Chem B 102 1998 7299 7302
4. R.I. Hegde, and J.M. White Surface chemistry of phosphine on clean and oxidized iron J Phys Chem 90 1986 2159 2163
5. R.I. Hegde, and J.M. White JM Interaction of dimethyl methylphosphonate with oxidized iron and the effect of coadsorbed water Appl Surf Sci 28 1987 1 10
6. D.A. Panayotov, and J.R. Morris Catalytic degradation of a chemical warfare agent simulant: reaction mechanisms on TiO2-supported Au nanoparticles J Phys Chem C 112 2008 7496 7502
7. O. Daněk, V. Štengl, S. Bakardjieva, N. Murafa, A. Kalendova, and F. Opluštil Nanodispersive mixed oxides for destruction of warfare agents prepared by homogeneous hydrolysis with urea J Phys Chem Solids 68 2007 707 711
8. I.A. Fallis, P.C. Griffiths, T. Cosgrove, C.A. Dreiss, N. Govan, and R.K. Heenan Locus-specific microemulsion catalysts for sulfur mustard (HD) chemical warfare agent decontamination J Am Chem Soc 131 2009 9746 9755
9. 3. Formation of aluminophosphonates J Am Chem Soc 123 2001 1636 1644
10. A. Garg, and E. Matijevic Preparation and properties of uniform coated inorganic colloidal particles: III. Zirconium hydrous oxide on hematite J Colloid Interface Sci 126 1988 243 250
11. S. Garg, K. Soni, G.M. Kumaran, R. Bal, K.G. Marek, and J.K. Gupta Acidity and catalytic activities of sulfated zirconia inside SBA-15 Catal Today 141 2009 125 129
12. A.P. Oliveira, and M.L. Torem The influence of precipitation variables on zirconia powder synthesis Powder Technol 119 2001 181 193
13. B. Djuričic, S. Pickering, D. McGarry, P. Glaude, R. Tambuyser, and K. Schuster The properties of zirconia powders produced by homogeneous precipitation Ceram Int 21 1995 195 206
14. V. Štengl, S. Bakardjieva, N. Murafa, F. Opluštil, L. Österlund, and A. Mattsson Warfare agents degradation on zirconium doped titania Microsc Microanal 15 2009 1038 1039
15. V. Štengl, M. Maříková, S. Bakardjieva, J. Šubrt, F. Opluštil, and M. Olšanská Reaction of HD, VX and GD with nanosized anatase TiO2 and ferrihydrite J Chem Technol Biotechnol 80 2005 754 758
16. JCPDS PDF-2 release 2001, ICDD Newtown Square, PA, USA
17. P. Scherrer Gottinger Nachr 2 1918 98
18. S. Brunauer, P.H. Emmett, and E. Teller Adsorption of gases in multimolecular layers J Am Chem Soc 60 1938 309 319
19. E.P. Barret, L.G. Joyner, and P.P. Halenda The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms J Am Chem Soc 73 1951 373 380
20. J.L. Shi, and J.H. Gao Preparation of spherical zirconium salt particles by homogeneous precipitation J Mater Sci 30 1995 793 799
21. V. Štengl, S. Bakardjieva, N. Murafa, and F. Opluštil Zirconium doped titania: destruction of warfare agents and photocatalytic degradation of orange 2 dye Open Process Chem J 1 2008 1 7
22. N. Venkatachalam, M. Palanichamy, B. Arabindoo, and V. Murugesan Enhanced photocatalytic degradation of 4-chlorophenol by Zr4+ doped nano TiO2 J Mol Catal A: Chem 266 2007 158 165
23. Y.M. Wang, S.W. Liu, M.K. Lü, S.F. Wang, F. Gu, and X.Z. Gai Preparation and photocatalytic properties of Zr4+-doped TiO2 nanocrystals J Mol Catal A: Chem 215 2004 137 142
24. V.C. Farmer Infrared spectra of minerals, Mineralogical Society Monograph 4 1974 Mineralogical Society London
25. 2O Can J Chem 45 1967 585 588
26. L. Wang, and M. Muhammed Synthesis of zinc oxide nanoparticles with controlled morphology J Mater Chem 9 1999 2871 2878
27. S. Lowell, and J.E. Shields Powder surface area and porosity 1998 Chapman & Hall London