Retarding effect of aromatic solvents on cobalt(II)-based catalyst system during synthesis of high cis-1,4-polybutadiene

Industrial and Engineering Chemistry Research

Volumn 49, Issue 20, 2010, Pages 9648-9654

  Singh, Archana ^a   Modi, Siddharth ^a   Subrahmanyam, N ^a   Munshi, Pradip ^b   Upadhyay, Vinod K ^b   Jasra, Raksh Vir ^b   Maiti, Madhuchhanda ^b  

^a NIRMA UNIVERSITY   (India)

^b RELIANCE INDUSTRIES LIMITED   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SITE; ALKYLALUMINUM; AROMATIC SOLVENT; BUTADIENYL; CATALYST SYSTEM; COMPARATIVE STUDIES; DIETHYLALUMINUM CHLORIDES; DIETHYLBENZENES; DIFFERENT SOLVENTS; ELECTRON DENSITIES; LEWIS ACIDITY; O-XYLENE; POLYMERIZATION KINETICS; POLYMERIZATION RATES; REACTION CONDITIONS; RETARDING EFFECT; VISCOSITY AVERAGE MOLECULAR WEIGHT;

AROMATIC HYDROCARBONS; BUTADIENE; CATALYSTS; CHLORINE COMPOUNDS; COBALT; CYCLOHEXANE; ETHYLBENZENE; MOLECULAR WEIGHT; ORGANIC SOLVENTS; POLYBUTADIENES; POLYMERIZATION; POLYMERS; RATE CONSTANTS; SYNTHESIS (CHEMICAL); XYLENE;

TOLUENE;

EID: 77957997894     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie101324d     Document Type: Article

References (46)

1. Blow, C. M. and Hepburn, C. Rubber Technology and Manufacture; Butterworth Scientific: London, 1982.
2. Ramamurthy, K. World synthetic rubber scenario with special reference to asia pacific region. In India International Rubber Conference; Udaipur, India, Nov 1-3, 2007; Mohan Lal Sukhadia University: Udaipur, India, 2007; paper no. 10A.
3. Friebe, L.; Nuyken, O.; Obrecht, W. Neodymium-based Ziegler-Natta catalysts and their application in diene polymerization Adv. Polym. Sci. 2006, 204, 1-154
4. Rao, G. S. S.; Upadhyay, V. K.; Jain, R. C. Polymerization of 1,3-butadiene with neodymium chloride/2-ethylhexanoate/triethylaluminium catalyst system Angew. Makromol. Chem. 1997, 251, 193-205
5. Kwag, G.; Lee, J. G.; Lee, H.; Kim, S. Study of the active site and activation process of Ni-based catalyst for 1,3-butadiene polymerization using X-ray absorption and crystal-field spectroscopies J. Mol. Catal. A: Chem. 2003, 193, 13-20
6. Pires, N.; Ferreira, A.; Lira, C.; Coutinho, P.; Nicolini, L.; Soares, B.; Coutinho, F. Performance evaluation of high cis -1,4-polybutadienes J. Appl. Polym. Sci. 2006, 99, 88-99
7. Boor, J. Ziegler Natta Catalysis and Polymerizations; Academic Press: New York, 1979.
8. Saltman, W. M. The Stereo Rubbers; John Wiley and Sons: New York, 1977.
9. Carlson, G. J.; Berkeley, W. D.; Higgins, T. L.; Cerrito, E.; Charles, H. U.S. Patent 3066127, 1962.
10. Upadhyay, V. K.; Sivaram, S. Effect of reaction parameters on the solution polymerization of 1,3-butadiene using cobalt (II)-2-ethylhexoate- diethylaluminium chloride catalyst Indian J. Technol. 1991, 29, 579-583
11. Gippin, M. Polymerization of butadiene with alkylaluminium and cobalt chloride Ind. Eng. Chem. Prod. Res. Dev. 1962, 1, 32-39
12. Gippin, M. Stereoregular polymerization of butadiene with alkylaluminum chlorides and cobalt octoate Ind. Eng. Chem. Prod. Res. Dev. 1965, 4, 160-167
13. Cass, P.; Pratt, K.; Mann, T.; Laslett, B.; Rizzardo, E. Replacement of benzene with regulators for the catalyzed polymerization of 1, 3-butadine to high cis -1, 4-polybutadiene J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 2244-2255
14. Odar, J. U.S. Patent 4314045, 1982.
15. Odar, J. U.S. Patent 4224426, 1980.
16. Lasis, E.; U.S. Patent 4242478, 1980.
17. Van der Arend, J. C. M.; De Boer-Wildschut, M.; van der Huizen, A. A.; Kersten, M. J. E. U.S. Patent 5691429, 1997.
18. Tsujimoto, N.; Yano, T.; Akikawa, K.; Kotani, C.; Tsukahara, K.; U.S. Patent 5905125, 1999.
19. Odar, J.; U.S. Patent 4303769, 1981.
20. Cass, P.; Pratt, K.; Fairhall, K.; Laslett, B.; Rizzardo, E. Active-center equilibrium in Ziegler-Natta butadiene polymerization J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 2256-2261
21. Cass, P.; Pratt, K.; Mann, T.; Laslett, B.; Rizzardo, E.; Burford, R. Investigation of methylaluminoxane as a cocatalyst for the polymerization of 1,3-butadiene to high cis -1,4-polybutadiene J. Polym. Sci., Part A: Polym. Chem. 1999, 37, 3277-3284
22. Capello, C.; Fischer, U.; Hungerbühler, K. What is a green solvent? A comprehensive framework for the environmental assessment of solvents Green Chem. 2007, 9, 927-934
23. Upadhyay, V. K.; Sivaram, S. Solvent effects in the polymerization of 1, 3- butadiene with Cobalt (II) 2-ethylhexoate- diethyl aluminum chloride catalyst Indian J. Technol. 1987, 25, 669-673
24. Porri, L.; Giarrusso, A.; Ricci, G. Recent views on the mechanism of diolefin polymerization with transition metal initiator systems Prog. Polym. Sci. 1991, 16, 405-441
25. Ricci, G.; Boffa, G.; Porri, L. Polymerization of 1,3-dialkenes with neodymium catalysts. Some remarks on the influence of the solvent Makromol. Chem., Rapid Commun. 1986, 7, 355-359
26. Mello, I. L.; Coutinho, F. M. B.; Nunes, D. S. S.; Soares, B. G.; Costa, M. A. S.; Maria, L. C. D. S. Solvent effect in cis -1,4-polymerization of 1,3-butadiene by a catalyst based on neodymium Eur. Polym. J. 2004, 40, 635-640
27. 2. A new highly active and stereospecific catalyst for 1,2 polymerization of conjugated dienes when used in association with MAO Macromolecules 2005, 38, 1064-1070
28. Honig, J. A. J.; Burford, R. P.; Chaplin, R. P. Ziegler-Natta polymerization of butadiene: Kinetic and molecular weight study J. Polym. Sci., Part A: Polym. Chem. 1983, 21, 2559-2571
29. Honig, J. A. J.; Burford, R. P.; Chaplin, R. P. Molecular weight phenomena at high conversions in the Ziegler-Natta polymerization of butadiene J. Polym. Sci., Part A: Polym. Chem. 1984, 22, 1461-1470
30. Perrin, D. D.; Armarego, W. L. F. Purification of Laboratory Chemicals; Pergamon Press; London, 1988.
31. Ciampelli, F.; Morero, D.; Cambini, M. Some remarks on the infrared analysis of polyisoprenes Makromol. Chem. 1963, 61, 250-253
32. Danusso, F.; Moraglio, G.; Gianotti, G. cis -Tactic polybutadiene: Solubility, [η]-M relations in different solvents, and molecular conformation J. Polym. Sci. 1961, 51, 475-485
33. Mello, I. L.; Coutinho, F. M. B. Neodymium Ziegler-Natta catalysts: Evaluation of catalyst ageing effect on 1,3-butadiene polymerization Eur. Polym. J. 2008, 44, 2893-2898
34. Racanelli, P.; Porri, L. Cis -1,4-polybutadiene by cobalt catalysts. Some features of the catalysts prepared from alkylaluminium compounds containing Al-O-Al bonds Eur. Polym. J. 1970, 6, 751-761
35. Saltman, W. M.; Kuzma, L. J. Preparation and properties of polydienes Rubber Chem. Technol. 1973, 46, 1055-1067
36. Iovu, H.; Hubcaa, G.; Racoti, D.; Hurst, J. S. Modelling of the butadiene and isoprene polymerization processes with a binary neodymium-based catalyst Eur. Polym. J. 1999, 35, 335-344
37. Carey, F. A.; Sundberg, R. J. Advanced Organic Chemistry Part A: Structure and Mechanisms; Springer: New York, 2006.
38. Tanase, S.; Hierso, J. C.; Bouwman, E.; Reedijk, J.; Borg, J. T.; Bielemanb, J. H.; Schut, A. New insights on the anti-skinning effect of methyl ethyl ketoxime in alkyd paints New J. Chem. 2003, 27, 854-859
39. Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochman, M. Advanced Inorganic Chemistry; John Wiley and Sons: New York, 1999.
40. Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Effects of solvent, temperature, and pressure on the photophysical and visible- spectroscopic behavior of the trans-diammine(1,4,8,11-tetraazacyclotetradecane) chromium(III) ion Inorg. Chem. 1992, 31, 4950-4958
41. Friesen, D. A.; Lee, S. H.; Lilie, J.; Waltz, W. L.; Vincze, L. Photochemistry and photophysics of cis-and trans -diammine(1,4,8,11- tetraazacyclotetradecane)chromium(III) ions in acidified aqueous media under different pressure and temperature conditions Inorg. Chem. 1991, 30, 1975-1980
42. Aminova, G. A.; Manuiko, G. V.; Litvinenko, G. I.; D'yakonov, G. S.; Zolotarev, V. L.; Filipova, A. G.; Ignashina, T. V.; Davydova, V. V.; Antonova, O. V. Mechanism of butadiene polymerization on cobalt-containing catalyst. Russ J. Appl. Chem. 2002, 75, 1146-1150
43. Honig, J. A. J.; Gloor, P. E.; Macgregor, J. F.; Hamielec, A. E. A mathematical model for Ziegler-Natta polymerization of butadiene J. Appl. Polym. Sci. 1987, 34, 829-845
44. Liu, G.; Wang, G.; Li, W. Solvent effect on the type (red-shifted or blue-shifted) of hydrogen bond J. Mol. Struct.-THEOCHEM 2006, 772, 103-108
45. Bayliss, N. S.; McRae, E. G. Solvent effects in organic spectra: Dipole forces and the Franck-Condon principle J. Phys. Chem. 1954, 58, 1002-1006
46. Lever, A. B. P. Inorganic Electronic Spectroscopy; Elsevier: Amsterdam, 1985.