Block copolymer self-assembly-directed single-crystal homo- and heteroepitaxial nanostructures

Science

Volumn 330, Issue 6001, 2010, Pages 214-219

  Arora, Hitesh ^a,c   Du, Phong ^a,d   Tan, Kwan W ^a   Hyun, Jerome K ^a,e   Grazul, John ^b   Xin, Huolin L ^a   Muller, David A ^a   Thompson, Michael O ^a   Wiesner, Ulrich ^a  

^a Cornell University   (United States)

^b Department of Obstetrics Gynecology   (United States)

^c INTEL CORPORATION   (United States)

^d DUPONT COMPANY   (United States)

^e Northwestern University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COPOLYMER; CRYSTALLIN; NANOMATERIAL; SELF ASSEMBLED MONOLAYER; SILICONE;

CRYSTAL; NANOTECHNOLOGY; POLYMER; POROUS MEDIUM; SILICON; STOICHIOMETRY;

ARTICLE; CRYSTALLIZATION; ENERGY CONVERSION; IRRADIATION; PRIORITY JOURNAL; STOICHIOMETRY;

EID: 77957736715     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1193369     Document Type: Article

References (34)

1. T. Yanagisawa, T. Shimizu, K. Kuroda, C. Kato, Bull. Chem. Soc. Jpn. 63, 988 (1990).
2. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, J. S. Beck, Nature 359, 710 (1992).
3. M. Templin et al., Science 278, 1795 (1997).
4. D. Zhao et al., Science 279, 548 (1998).
5. P. Yang, D. Zhao, D. I. Margolese, B. F. Chmelka, G. D. Stucky, Nature 396, 152 (1998).
6. S. H. Joo et al., Nature 412, 169 (2001).
7. S. C. Warren et al., Science 320, 1748 (2008).
8. A. W. Vere, Crystal Growth: Principles and Progress (Plenum, New York, 1987).
9. J. Aizenberg, D. A. Muller, J. L. Grazul, D. R. Hamann, Science 299, 1205 (2003).
10. M. Park, C. Harrison, P. M. Chaikin, R. A. Register, D. H. Adamson, Science 276, 1401 (1997).
11. R. Ruiz et al., Science 321, 936 (2008).
12. C. Tang, E. M. Lennon, G. H. Fredrickson, E. J. Kramer, C. J. Hawker, Science 322, 429 (2008).
13. T. Thurn-Albrecht et al., Science 290, 2126 (2000).
14. S. Y. Chou, C. Keimel, J. Gu, Nature 417, 835 (2002).
15. C. De Rosa, C. Park, E. L. Thomas, B. Lotz, Nature 405, 433 (2000).
16. P. Yang et al., Science 282, 2244 (1998).
17. B. Lee, T. Yamashita, D. Lu, J. N. Kondo, K. Domen, Chem. Mater. 14, 867 (2002).
18. J. N. Kondo, K. Domen, Chem. Mater. 20, 835 (2008).
19. A. S. Finnemore et al., Adv. Mater. 21, 3928 (2009).
20. E. S. Toberer, M. Grossman, T. Schladt, F. F. Lange, R. Seshadri, Chem. Mater. 19, 4833 (2007).
21. See the supporting material on Science Online.
22. P. Du et al., Adv. Mater. 16, 953 (2004).
23. D. H. Auston, C. M. Surko, T. N. C. Venkatesan, R. E. Slusher, J. A. Golovchenko, Appl. Phys. Lett. 33, 437 (1978).
24. A. Okabe, B. Boots, K. Sugihara, S. N. Chiu, Spatial Tessellations: Concepts and Applications of Voronoi Diagrams (Wiley, New York, 2000).
25. R. A. Segalman, A. Hexemer, R. C. Hayward, E. J. Kramer, Macromolecules 36, 3272 (2003).
26. C. Detavernier et al., Nature 426, 641 (2003).
27. Thicker NiSi films with sufficient volume for x-ray diffraction confirm NiSi stoichiometry.
28. G. E. Jellison, D. H. Lowndes, D. N. Mashburn, R. F. Wood, Phys. Rev. B 34, 2407 (1986).
29. G. E. Jellison Jr., D. H. Lowndes, J. W. Sharp, J. Mater. Res. 3, 498 (1988).
30. J. M. Poate, J. Mayer, Laser Annealing of Semiconductors (Academic Press, New York, 1982).
31. M. O. Thompson et al., Phys. Rev. Lett. 52, 2360 (1984).
32. J. G. Li, H. Hausner, Mater. Lett. 14, 329 (1992).
33. M. Stefik et al., Chem. Mater. 21, 5466 (2009).
34. 2), an Energy Frontiers Research Center funded by the U.S. Department of Energy Office of Science, Office of Basic Energy Sciences, under award no. SC0001086. K.W.T. gratefully acknowledges the Singapore Clean Energy Programme Office for a National Research Foundation graduate fellowship. The use of facilities of the Cornell Center for Materials Research, with funding from the Materials Research Science and Engineering Center program of NSF (under cooperative agreement DMR-0520404), and of the Cornell Nanoscale Science and Technology Facility, supported by NSF under grant no. ECS-0335765, is gratefully acknowledged. The authors also thank J. Gregoire, P. Huang, M. Thomas, S. Warren, C. Garcia, and R. Dorin for assistance in these experiments and A. Burns for help with graphics. A provisional patent application titled "Method for Large Mismatch Heteroepitaxy on Silicon" has been filed with Cornell University.