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Volumn 29, Issue 19, 2010, Pages 4210-4212

Extraction of hydrogen from alcohols by a methylene-bridged iridium(I) dinuclear complex having a short Ir-Ir double bond

Author keywords

[No Author keywords available]

Indexed keywords

DIHYDRIDE COMPLEXES; DINUCLEAR COMPLEX; DOUBLE BONDS;

EID: 77957677531     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100630g     Document Type: Article
Times cited : (5)

References (23)
  • 8
    • 0011775782 scopus 로고
    • 2) depending on whether it is considered as a neutral (two-electron donor) or dianionic (four-electron donor) ligand. We will take the methylene as a neutral ligand throughout the paper, on the basis of our NMR results of 1 and its isolobality with the carbonyl ligand. Thus, for instance, the formal oxidation state of iridium atoms in 1 is "+1"
    • 2) depending on whether it is considered as a neutral (two-electron donor) or dianionic (four-electron donor) ligand. We will take the methylene as a neutral ligand throughout the paper, on the basis of our NMR results of 1 and its isolobality with the carbonyl ligand. Thus, for instance, the formal oxidation state of iridium atoms in 1 is "+1": Mealli, C.; Proserpio, D. M. J. Organomet. Chem. 1990, 386, 203
    • (1990) J. Organomet. Chem. , vol.386 , pp. 203
    • Mealli, C.1    Proserpio, D.M.2
  • 10
    • 77957659821 scopus 로고    scopus 로고
    • 2 = 0.1595 (all data), GOF = 1.075. CCDC 782295
    • 2 = 0.1595 (all data), GOF = 1.075. CCDC 782295.
  • 18
    • 77957679913 scopus 로고    scopus 로고
    • 3 species
    • 3 species.
  • 19
    • 77957674762 scopus 로고    scopus 로고
    • 2 ligand may cause some electronic asymmetry between the two metal atoms at a certain activation stage
    • 2 ligand may cause some electronic asymmetry between the two metal atoms at a certain activation stage.
  • 20
    • 4344602894 scopus 로고    scopus 로고
    • A similar multiple interaction is proposed for selective oxidation of alcohols
    • A similar multiple interaction is proposed for selective oxidation of alcohols: Mori, K.; Hara, T.; Mizugaki, T.; Ebitani, K.; Kaneda, K. J. Am. Chem. Soc. 2004, 126, 10657
    • (2004) J. Am. Chem. Soc. , vol.126 , pp. 10657
    • Mori, K.1    Hara, T.2    Mizugaki, T.3    Ebitani, K.4    Kaneda, K.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.