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) 2 tan θ. Inserting the zero-field g values in this expression leads to an asymptotic angle of the moment with respect to H of 40°, instead of the actual 20°. This discrepancy arises from the mixture of the excited crystal field states into the ground state by the Zeeman effect, which modifies the g values.
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77957601233
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note
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With the mean value λ = - 0.51 T / μ B, the calculated T N value in zero field is 1.48 K, rather than the experimental value 1.2 K. This probably reflects a small imperfection of the model, which requires a 15% higher λ value to account for the in-field properties than for the zero-field T N value.
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