A comparative study on polarization behavior of (La,Sr)MnO3 and (La,Sr)CoO3 cathodes for solid oxide fuel cells

International Journal of Hydrogen Energy

Volumn 35, Issue 19, 2010, Pages 10505-10512

  Yang, Jun ^a   Muroyama, Hiroki ^a   Matsui, Toshiaki ^a   Eguchi, Koichi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Lanthanum strontium cobaltite; Nonstoichiometry; Polarization; Solid oxide fuel cell; Strontium doped lanthanum manganite

Indexed keywords

CATHODE MATERIALS; CATHODE POTENTIAL; CIRCUIT STATE; COMPARATIVE STUDIES; DOPED CERIA; LANTHANUM COBALTITE; NON-STOICHIOMETRY; PERFORMANCE ENHANCEMENTS; POLARIZATION BEHAVIOR; RELAXATION BEHAVIORS; SOLID OXIDE; STABILIZED ZIRCONIA; STRONTIUM COBALTITE; STRONTIUM DOPED LANTHANUM MANGANITES; STRONTIUM-DOPED LANTHANUM MANGANITE;

CATHODES; CERIUM COMPOUNDS; COBALT COMPOUNDS; ELECTRIC RESISTANCE MEASUREMENT; ELECTROLYTES; LANTHANUM; LANTHANUM ALLOYS; LANTHANUM OXIDES; MANGANESE OXIDE; SOLID OXIDE FUEL CELLS (SOFC); STRONTIUM; ZIRCONIA;

CATHODIC POLARIZATION;

EID: 77957282613     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.07.174     Document Type: Article

References (48)

1. T. Matsui, J.Y. Kim, R. Kikuchi, and K. Eguchi Sudden deterioration in performance during discharge of anode-supported solid oxide fuel cells Electrochemistry 77 2009 123 126
2. J.P. Jiang Development of lanthanum strontium manganite perovskite cathode materials of solid oxide fuel cells: a review Journal of Materials Science 43 2008 6799 6833
3. 3 for high-temperature solid electrolyte fuel-cells Materials Research Bulletin 24 1989 367 380
4. F. Zheng, and L.R. Pederson Phase behavior of lanthanum strontium manganites Journal of the Electrochemical Society 146 1999 2810 2816
5. 3 Solid State Ionics 132 2000 167 180
6. H. Yokokawa, H.Y. Tu, B. Iwanschitz, and A. Mai Fundamental mechanisms limiting solid oxide fuel cell durability Journal of Power Sources 182 2008 400 412
7. M.A. Haider, and S. McIntosh Evidence for two activation mechanisms in LSM SOFC cathodes Journal of the Electrochemical Society 156 2009 B1369 B1375
8. X.J. Chen, S.H. Chan, and K.A. Khor Cyclic voltammetry of (La,Sr)MnO3 electrode on YSZ substrate Solid State Ionics 164 2003 17 25
9. 3-yttria-stablized zirconia electrode-kinetics Electrochimica Acta 40 1995 1741 1753
10. 3+/-δ under cathodic polarization Electrochemical and Solid State Letters 7 2004 A144 A147
11. 3 on yttria-stabilized zirconia. 2. Electrode kinetics Journal of the Electrochemical Society 144 1997 134 140
12. 3+/-δ Solid State Ionics 86-88 1996 1197 1201
13. 3 electrodes Solid State Ionics 146 2002 1 22
14. 2 reduction reaction Journal of the Electrochemical Society 147 2000 3195 3205
15. Y. Jiang, S.Z. Wang, Y.H. Zhang, J.W. Yan, and W.Z. Li Kinetic study of the formation of oxygen vacancy on lanthanum manganite electrodes Journal of the Electrochemical Society 145 1998 373 378
16. J. Mizusaki Nonstoichiometry, diffusion, and electrical properties of perovskite-type oxide electrode materials Solid State Ionics 52 1992 79 91
17. 3 with oxygen-deficit nonstoichiometry Solid State Ionics 161 2003 209 217
18. J. Yang, H. Muroyama, T. Matsui, and K. Eguchi Transient response of LSM electrode under cathodic polarization Electrochemical Society Transaction 25 2009 2349 2358
19. 3-δ cathodes Journal of the Electrochemical Society 155 2008 B1 B7
20. M. Backhaus-Ricoult, K. Adib, T.S. Clair, B. Luerssen, L. Gregoratti, and A. Barinov In-situ study of operating SOFC LSM/YSZ cathodes under polarization by photoelectron microscopy Solid State Ionics 179 2008 891 895
21. Y. Takeda, R. Kanno, M. Noda, Y. Tomida, and O. Yamamoto Cathodic polarization phenomena of perovskite oxide electrodes with stabilized zirconia Journal of the Electrochemical Society 134 1987 2656 2661
22. V.V. Srdic, R.P. Omorjan, and J. Seydel Electrochemical performances of (La,Sr)CoO3 cathode for zirconia-based solid oxide fuel cells Materials Science and Engineering B-Solid State Materials for Advanced Technology 116 2005 119 124
23. 3 electrodes for solid oxide fuel cells Solid State Ionics 135 2000 353 358
24. 3-δ Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy 57 2001 2071 2076
25. S.B. Adler Factors governing oxygen reduction in solid oxide fuel cell cathodes Chemical Reviews 104 2004 4791 4843
26. 3 cathode with ceria interlayer on zirconia electrolyte Electrochemical and Solid State Letters 2 1999 428 430
27. A. Ringuede, and J. Fouletier Oxygen reaction on strontium-doped lanthanum cobaltite dense electrodes at intermediate temperatures Solid State Ionics 139 2001 167 177
28. 3-δ Solid State Ionics 128 2000 65 78
29. 3-δ cathode on YSZ(100) Journal of Physics and Chemistry of Solids 66 2005 343 348
30. T. Matsui, R. Kishida, J.Y. Kim, H. Muroyama, and K. Eguchi Performance deterioration of Ni-YSZ anode induced by electrochemically generated steam in solid oxide fuel cells Journal of the Electrochemical Society 157 2010 B776 B781
31. 3 thin-film yttria-stabilized zirconia interface studied by impedance spectroscopy Journal of the Electrochemical Society 141 1994 2118 2121
32. 3/YSZ electrodes Journal of the Electrochemical Society 142 1995 2659 2664
33. 3 electrodes of solid oxide fuel cells Solid State Ionics 177 2006 1361 1369
34. M. Kuznecov, P. Otschik, P. Obenaus, K. Eichler, and W. Schaffrath Diffusion controlled oxygen transport and stability at the perovskite/ electrolyte interface Solid State Ionics 157 2003 371 378
35. 3 cathode for low-temperature SOFCs Solid State Ionics 170 2004 1 7
36. 3-δ as porous SOFC-cathode Solid State Ionics 179 2008 1422 1426
37. 2(g) vertical bar YSZ system Solid State Ionics 111 1998 185 218
38. 2 interface by electrochemical impedance spectroscopy Journal of Power Sources 110 2002 201 208
39. S.B. Adler, X.Y. Chen, and J.R. Wilson Mechanisms and rate laws for oxygen exchange on mixed-conducting oxide surfaces Journal of Catalysis 245 2007 91 109
40. O'G.J. La, R.F. Savinell, and Y. Shao-Horn Activity enhancement of dense strontium-doped lanthanum manganite thin films under cathodic polarization: a combined AES and XPS study Journal of the Electrochemical Society 156 2009 B771 B781
41. J. Yang, H. Muroyama, T. Matsui, and K. Eguchi Simulation of dynamic response of strontium-doped lanthanum manganite under cathodic polarization Journal of the Electrochemical Society 157 2010 B449 B454
42. M. Cherry, M.S. Islam, and C.R.A. Catlow Oxygen-ion migration in perovskite oxides Journal of Solid State Chemistry 118 1995 125 132
43. 3 electrodes of solid oxide fuel cells Solid State Ionics 158 2003 45 53
44. 3 electrode by ac-impedance analysis Journal of Solid State Electrochemistry 11 2007 117 125
45. 3-YSZ composite electrodes investigated using potentiostatic current transient method Journal of the Electrochemical Society 155 2008 B762 B769
46. W. Sitte, E. Bucher, and W. Preis Nonstoichiometry and transport properties of strontium-substituted lanthanum cobaltites Solid State Ionics 154-155 2002 517 522
47. 4 U. Bossel, Proceedings of the 7th euro solid oxide fuel cell forum 2006 Luzern
48. 4 in composite ceramics Solid State Ionics 178 2008 1843 1852