Discrepancies in thorium oxide solubility values: Study of attachment/detachment processes at the solid/solution interface

Inorganic Chemistry

Volumn 49, Issue 19, 2010, Pages 8736-8748

  Vandenborre, Johan ^a   Grambow, Bernd ^a   Abdelouas, Abdessalam ^a  

^a UNIVERSITÉ DE NANTES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77957257554     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic100756f     Document Type: Article

References (35)

1. Hubert, S., Barthelet, K., Fourest, B., Lagarde, G., Dacheux, N., and Baglan, N., Influence of the precursor and the calcination temperature on the dissolution of thorium dioxide. J. Nucl. Mater. 2001, 297, (2), 206-213. (Pubitemid 32691096)
2. 2 (M = U, Pu). Université Paris XI, Orsay, 2003.
3. 2O system at 23°C and 90°C. Radiochim. Acta 2000, 88, 297-306.
4. 2 solution. Radiochim. Acta 2004, 92, 537-543.
5. Rothe, J., Denecke, M. A., Neck, V., Müller, R., and Kim, J. I., XAFS investigation of the structure of aqueous Thorium(IV) species, colloids, and solid Thorium(IV) oxide/hydroxide. Inorg. Chem. 2002, 41, 249-258.
6. 2 mixed oxides fuel particles. Mater. Res. Soc. Symp. Proc. 2004, 807. (Pubitemid 40163021)
7. Vandenborre, J., Abdelouas, A., and Grambow, B., Discrepancies in thorium oxide solubility values: a new experimental approach to improve understanding of oxide surface at solid/solution interface. Radiochim. Acta 2008, 96, 515-520.
8. Felmy, A. R., Rai, D., and Mason, M. J., The solubility of hydrous thorium(IV) oxide in chloride media: development of an aqueous ion-interaction model. Radiochim. Acta 1991, 55, 177-185.
9. Moon, H. C., Equilibrium ultrafiltration of hydrolized thorium (IV) solutions. Bull. Korean Chem. Soc. 1989, 10, (3), 270-272.
10. Nabivanets, B. and Kudritskaya, L. N., Hydrocomplexes of thorium(IV). Ukr. Khim. Zh. 1964, 30, 891-895.
11. 2 solutions. Radiochim. Acta 1997, 79, 239-247. (Pubitemid 127493830)
12. Ryan, J. L. and Rai, D., Thorium(IV) hydrous oxide solubility. Inorg. Chem. 1987, 26, (24), 4140-4142.
13. Rand, M., Fuger, J., Neck, V., Grenthe, I., and Rai, D., Chemical Thermodynamics of Thorium. North Holland Elsevier Science Publishers B. V.: Amsterdam, The Netherlands, 2008; Vol. 11.
14. Baes, C. F., Meyer, N. J., and Roberts, C. E., The Hydrolysis of Thorium(IV) at 0 and 95°. Inorg. Chem. 1965, 4, 518-527.
15. Bundschuh, T., Knopp, R., Müller, R., Kim, J. I., Neck, V., and Fanghänel, T., Application of LIBD to the determination of the solubility product of thorium (IV)-colloids. Radiochim. Acta 2000, 88, 625-629. (Pubitemid 32103763)
16. 2O. J. Colloid Interface Sci. 1985, 103, (1), 170-177. (Pubitemid 15437412)
17. 2. Radiochim. Acta 2002, 90, (9), 523-527.
18. 2+x(s) as host phase. Radiochim. Acta 2006, 94, 517-522.
19. Jernström, J., Vuorinen, U., and Hakanen, M. Solubility of thorium in 0.1 M NaCl solution and in saline and fresh anoxic reference groundwater; 2002.
20. Neck, V., Müller, R., Bouby, M., Altmaier, M., Rothe, J., Denecke, M. A., and Kim, J. I., Solubility of amorphous Th(IV) hydroxide-application of LIBD to determine the solubility product and EXAFS for aqueous speciation. Radiochim. Acta 2002, 90, 485-494.
21. 2 in phosphate media. Radiochim. Acta 1995, 788, 1-6.
22. 2O media. Geochim. Cosmochim. Acta 1994, 58, (2), 613-623. (Pubitemid 24423745)
23. Wierczinski, B., Helfer, S., Ochs, M., and Skarnemark, G., Solubility measurements and sorption studies of thorium in cement pore water. J. Alloys Compd. 1998, 271-273, 272-276. (Pubitemid 128424961)
24. 2 solid solutions in nitric media. J. Nucl. Mater. 2003, 321, (2-3), 141-151.
25. 2O(am) in carbonate solution and the formation of ternary Th(IV) hydroxide-carbonate complexes. Radiochim. Acta 2005, 93, (2), 83-92. (Pubitemid 40332960)
26. Bitea, C., Müller, R., Neck, V., Walther, C., and Kim, J. I., Study of the generation and stability of thorium(IV) colloids by LIBD combined with ultrafiltration. Colloids Surf., A 2003, 217, (1-3), 63-70. (Pubitemid 36555182)
27. Neck, V. and Kim, J. I., Solubility and hydrolysis of tetravalent actinides. Radiochim. Acta 2001, 9, 1-16. (Pubitemid 32146184)
28. Cox, J. D., Wagman, D. D., and Medvedev, V. A., CODATA Key Values for Thermodynamics. Hemisphere Pub. Corp.: 1989; p 271.
29. Fuger, J. and Oetting, F. L., The Chemical Thermodynamics of Actinide Elements and Compounds: Part 2, The Actinide Aqueous Ions. Vienna, 1976.
30. 2 Organic Substances in SI Units. J. Phys. Chem. 1982, 11, (2).
31. Müller, A., Establishment of the technology to manufacture uranium dioxide kernels for PBMR fuel. Proceedings HTR2006: 3rd International Topical Meeting on High Temperature Reactor Technology 2006, B00000070.
32. Kwok, R. W. M. XPSPeak95, 4.1; The Chinese University of Hong Kong: 1999.
33. 2 mixed oxides fuel particles. J. Nucl. Mater. 2005, 346, (1), 32-39. (Pubitemid 41427885)
34. 2 system. J. Nucl. Mater. 1966, 18, (2), 77-107.
35. 2 comme phase daccueil. Université de Nantes, Nantes, 2002.