Heat capacity, entropy, and magnetic properties of jarosite-group compounds

Physics and Chemistry of Minerals

Volumn 37, Issue 9, 2010, Pages 635-651

  Majzlan, Juraj ^a   Glasnák, Peter ^b   Fisher, Robert A ^d   White, Mary Anne ^e   Johnson, Michel B ^e   Woodfield, Brian ^c   Boerio Goates, Juliana ^c  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

^b UNIVERSITY OF FREIBURG   (Germany)

^c Brigham Young University   (United States)

^d UNIVERSITY OF CALIFORNIA   (United States)

^e DALHOUSIE UNIVERSITY   (Canada)

Author keywords

Antiferromagnet; Entropy; Heat capacity; Jarosite; Spin glass

Indexed keywords

ANISOTROPIC PEAK BROADENING; ANTIFERROMAGNETICS; ANTIFERROMAGNETS; CONFIGURATIONAL ENTROPY; HEAT CAPACITIES; JAROSITES; LATTICE CONTRIBUTION; LINEAR TERMS; LOW TEMPERATURES; NOMINAL COMPOSITION; SECOND GROUP; STANDARD ENTROPY; SYNCHROTRON X RAY DIFFRACTION; TRANSITION TEMPERATURE;

ANTIFERROMAGNETIC MATERIALS; ANTIFERROMAGNETISM; DEFECTS; DIFFRACTION; ENTROPY; GLASS; GLASS TRANSITION; HOLOGRAPHIC INTERFEROMETRY; MAGNETIC PROPERTIES; NEON; RUBIDIUM; SODIUM; SPECIFIC HEAT; SULFATE MINERALS; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

SPIN GLASS;

CHEMICAL COMPOSITION; ENTROPY; HEAT CAPACITY; JAROSITE; MAGNETIC FIELD; MAGNETIC PROPERTY; X-RAY DIFFRACTION;

EID: 77957155045     PISSN: 03421791     EISSN: 14322021     Source Type: Journal    
DOI: 10.1007/s00269-010-0363-6     Document Type: Article

References (44)

1. 3), standard reference material 720 and the effect of temperature-scale differences on thermodynamic properties. J Phys Chem Ref Data 22: 1441-1453.
2. Baron D, Palmer CD (1996) Solubility of jarosite at 4-35°C. Geochim Cosmochim Acta 60: 185-195.
3. 6 and the crystal chemistry of the ammoniojarosite-hydronium jarosite solid-solution series. Mineral Mag 71: 427-441.
4. Basciano LC, Peterson RC (2007b) Jarosite-hydronium jarosite solid-solution series with full iron site occupancy: mineralogy and crystal chemistry. Am Mineral 92: 1464-1473.
5. Basciano LC, Peterson RC (2008) Crystal chemistry of the natrojarosite-jarosite and natrojarosite-hydronium jarosite solid solution series: a synthetic study with full Fe site occupancy. Am Mineral 93: 853-862.
6. Bishop JL, Murad E (2005) The visible and infrared spectral properties of jarosite and alunite. Am Mineral 90: 1100-1107.
7. Bloss FD (1994) Crystallography and crystal chemistry. Mineralogical Society of America, pp 545.
8. Boer GJ, Sokolika IN, Martin ST (2008) Infrared optical constants of aqueous sulfate-nitrate-ammonium multi-component tropospheric aerosols from attenuated total reflectance measurements-Part I: results and analysis of spectral absorbing features. J Quant Spectrosc Radiat Transf 108: 17-38.
9. Breitinger DK, Krieglstein R, Bogner A, Schwab RG, ThH Pimpl, Mohr J, Schukow H (1997) Vibrational spectra of synthetic minerals of the alunite and crandallite type. J Mol Struct 408(409): 287-290.
10. 15. Phys Rev B 74: 024426.
11. Debye P (1912) Zur Theorie der spezifischen Wärmen. Ann Phys 39: 789-839.
12. Dutrizac JE, Jambor JL (2000) Jarosites and their application in hydrometallurgy. Rev Mineral Geochem 40: 405-453.
13. Gopal ESR (1966) Specific heat at low temperatures. Plenum Press, New York, pp 240.
14. 6. Abstr Programs Geol Sci Am 32: A180.
15. Grey IE, Mumme WG, Bordet P, Mills SJ (2009) The crystal chemical role of Zn in alunite-type minerals: structure refinements for kintoreite and zincian kintoreite. Am Mineral 94: 676-683.
16. 3O + ···OH-interaction. Chem Mater 19: 3061-3066.
17. Grohol D, Nocera DG, Papoutsakis D (2003) Magnetism of pure iron jarosites. Phys Rev B 67: 064401.
18. Grohol D, Matan K, Cho J-H, Lee S-H, Lynn JW, Nocera DG, Lee YS (2005) Spin chirality on a two-dimensional frustrated lattice. Nat Mater 4: 323-328.
19. Harrison A, Wills AS, Ritter C (1997) Long-range order induced by diamagnetic dilution of jarosites, model Kagome antiferromagnets. Phys B 241: 722-723.
20. Hendricks SB (1937) The crystal structure of alunite and the jarosites. Am Mineral 22: 773-784.
21. 2. Phys Rev B 61: 12181-12186.
22. o of synthetic jarosite and its sulfate analogues. Geochem Int 12: 115-121.
23. Kennedy CA, Stancescu M, Marriott RA, White MA (2007) Recommendations for accurate heat capacity measurements using a quantum design physical property measurement system. Cryogenics 47: 107-112.
24. Larson AC, von Dreele RB (1994) GSAS: general structure analysis system. LANSCE, MS-H805, Los Alamos.
25. Lashley JC, Lang BE, Boerio-Goates J, Woodfield BF, Darling TW, Chu F, Migliori A, Thoma D (2002) The heat capacity of single crystal AuZn near the martensitic transition. J Chem Thermodyn 34: 251-261.
26. Majzlan J, Navrotsky A, Woodfield BF, Lang BE, Boerio-Goates J, Fisher RA (2003) Phonon, spin-wave, and defect contribution to the low-temperature specific heat of α-FeOOH. J Low Temp Phys 130: 69-76.
27. 6. Phys Chem Miner 31: 518-531.
28. 2]. Phys Chem Miner 33: 567-573.
29. 2. Phys Rev Lett 96: 247201.
30. 6 by multi-nuclear solid-state NMR spectroscopy. Am Mineral 92: 587-597.
31. 2H MAS NMR spectroscopy. Chem Mater 20: 2234-2241.
32. Pitzer KS, Coulter LV (1938) The heat capacities, entropies, and heats of solution of anhydrous sodium sulfate and of sodium sulfate decahydrate. The application of the third law of thermodynamics to hydrated crystals. J Am Chem Soc 60: 1310-1313.
33. Powers DA, Rossman GR, Schugar HJ, Gray HB (1975) Magnetic-behavior and infrared-spectra of jarosite, basic iron sulfate, and their chromate analogs. J Solid State Chem 13: 1-13.
34. Rajdev D, Whitmore DH (1962) Debye temperature for cadmium derived for low-temperature specific-heat measurements. Phys Rev 128: 1030-1032.
35. Sato E, Nakai I, Miyawaki R, Matsubara S (2009) Crystal structures of alunite family minerals: beaverite, corkite, alunite, natroalunite, jarosite, svanbergite, and woodhouseite. Neues Jb Miner Abh 185: 313-322.
36. Serna CJ, Cortina CP, Ramos JVG (1986) Infrared and Raman study of alunite-jarosite compounds. Spectrochim Acta 42A: 729-734.
37. Stevens R, Boerio-Goates J (2004) Heat capacity of copper on the ITS-90 temperature scale using adiabatic calorimetry. J Chem Thermodyn 36: 857-863.
38. Stoffregen RE (1993) Stability relations of jarosite and natrojarosite at 150-250°C. Geochim Cosmochim Acta 57: 2417-2429.
39. Townsend MG, Longworth G, Roudaut E (1986) Triangular-spin, kagome plane in jarosites. Phys Rev B 33: 4919-4926.
40. Ulbrich HH, Waldbaum DR (1976) Structural and other contributions to the third-law entropies of silicates. Geochim Cosmochim Acta 40: 1-24.
41. Wills AS, Harrison A, Ritter C, Smith RI (2000) Magnetic properties of pure and diamagnetically doped jarosites: model kagomé antiferromagnets with variable coverage of the magnetic lattice. Phys Rev B 61: 6156-6169.
42. 6 using xyz polarized neutron diffraction. Phys Rev B 64: 094436.
43. Xu H, Zhao Y, Vogel SC, Hickmott DD, Daemen LL, Hartl MA (2009) Thermal expansion and decomposition of jarosite: a high-temperature neutron diffraction study. Phys Chem Miner. doi: 10. 1007/s00269-009-0311-5.
44. f 298° of jarosite synthesized from a natural solution. Geokhimia 5: 739-745 (in Russian).