Dialkynyl carbene derivatives: Generation and characterization of triplet tert -butylpentadiynylidene (t -Bu-C-̈-C-H) and dimethylpentadiynylidene (Me-C-̈-C-Me)

Journal of Organic Chemistry

Volumn 75, Issue 19, 2010, Pages 6372-6381

  Thomas, Phillip S ^a   Bowling, Nathan P ^a   Burrmann, Nicola J ^a   McMahon, Robert J ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL SUBSTITUTION; AXIAL SYMMETRY; CARBENE DERIVATIVES; CARBENES; CARBON CHAINS; CARBONYL OXIDES; CHEMICAL TRAPPING; CRYOGENIC MATRICES; DIAZO COMPOUNDS; DOPED MATRIX; ELECTRON PARAMAGNETIC RESONANCE SPECTRUM; ELECTRONIC ABSORPTION; ELECTRONIC SPECTRUM; ELECTRONIC TRANSITION; EPR SPECTRA; PHOTOCHEMICAL REARRANGEMENT; TRANSITION WAVELENGTHS; TRIPLET CARBENES; UV IRRADIATION; UV- AND; VIBRONIC PROGRESSIONS; VISIBLE REGION; WEAK ABSORPTION; ZERO-FIELD SPLITTING PARAMETERS;

ORGANIC COMPOUNDS; PARAMAGNETIC RESONANCE;

ELECTRON SPIN RESONANCE SPECTROSCOPY;

CARBENE; CARBONYL OXIDE; DIALKYNYLCARBENE DERIVATIVE; DIAZONIUM COMPOUND; DIMETHYLPENTADIYNYLIDENE; OXIDE; OXYGEN; TERT BUTYLPENTADIYNYLIDENE; UNCLASSIFIED DRUG;

ABSORPTION SPECTROSCOPY; ARTICLE; CONTROLLED STUDY; INFRARED SPECTROSCOPY; PHOTOCHEMISTRY; ULTRAVIOLET RADIATION;

ALKYNES; COMPUTER SIMULATION; METHANE; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 77957110739     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo101096n     Document Type: Article

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