Kinetic study on the synthesis of ethyl nitrite by the reaction of C2H5OH, O2, and NO in a trickle bed reactor

Chemical Engineering Journal

Volumn 163, Issue 3, 2010, Pages 422-428

  Wang, Huajun ^a   Li, Guangxing ^a  

^a HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Ethyl nitrite; Kinetics; Synthesis; Trickle bed reactor; Two film model

Indexed keywords

COUPLING REACTION; ETHYL NITRITE; EXPERIMENT DATA; FILM MODEL; GAS-LIQUID REACTION; HYDROGENATION PROCESS; KINETIC STUDY; KINETICS MODELS; LIQUID HOURLY SPACE VELOCITY; MOLAR RATIO; REGENERATION REACTIONS; SYNTHESIS; SYNTHESIS REACTION; TRICKLE BED REACTOR; TWO-FILM MODEL;

ATMOSPHERIC PRESSURE; CHEMICAL REACTORS; ETHYLENE; ETHYLENE GLYCOL; LIQUID FILMS; REACTION KINETICS; STATISTICAL TESTS; TITRATION;

SYNTHESIS (CHEMICAL);

EID: 77956649689     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2010.07.055     Document Type: Article

References (21)

1. Uchiumi S.I., Ataka K., Matsuzaki T. Oxidative reactions by a palladium-alkyl nitrite system. J. Organoment. Chem. 1999, 576:279-289.
2. Matsuzaki T., Nakamura A. Dimethyl carbonate synthesis and other oxidative reactions using alkyl nitrites. Catal. Surveys Jpn. 1997, 1:77-88.
3. Celik F.E., Kim T.J., Bell A.T. Vapor-phase carbonylation of dimethoxymethane over H-Faujasit. Angew. Chem. Int. Ed. 2009, 48:1-4.
4. 3 catalysts. Appl. Catal. A: Gen. 2001, 211:47-51.
5. 2 catalysts prepared by the ammonia-evaporation method: texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol. J. Catal. 2008, 257:172-180.
6. Su Y.H., Ji J.M., Jiang X.Z., Zhou S.H. A study on the regeneration ethyl nitrite. Chem. Reaction Eng. Technol. (in Chinese) 2000, 16:45-49.
7. K. Nishihira, S. Tanaka, S. Yoshida, Process for producing alkyl nitrite, EP Patent 0,911,316 A2 (1999).
8. J. Doumaux, R. Arthur, M. James, P. Joseph, M. John, Preparation of nitrite esters, US Patent 4,353,843 (1982).
9. Chen J.W., Xu G.H., Li Z.H., Chen H.F. kinetics of regeneration reaction for CO coupling. J. Chem. Ind. Eng. (China) (in Chinese) 1993, 44:66-72.
10. Hu Z.C., Yin D.X., He C.Y., Ma X.B., Li Z.H. New technique for ethyl nitrite regeneration. Chem. Ind. Eng. (in Chinese) 2008, 25:112-115.
11. van Hasselt B.W., Calis H.P.A., Sie S.T., van den Bleek C.M. Gas-liquid mass transfer characteristics of the three-levels-of porosity reactor. Chem. Eng. Sci. 2001, 56:531-536.
12. Vas Bhat R.D., Kuipers J.A.M., Versteeg G.F. Mass transfer with complex chemical reactions in gas-liquid systems: two-step reversible reactions with unit stoichiometric and kinetic orders. Chem. Eng. J. 2000, 76:127-152.
13. 2 into NaOH in a bubble column. Chem. Eng. Sci. 1996, 51:1715-1724.
14. Huang X., Varma A., McCready M.J. Heat transfer characterization of gas-liquid flows in a trickle-bed. Chem. Eng. Sci. 2004, 59:3767-3776.
15. Vas Bhat R.D., van Swaaij W.P.M., Kuipers J.A.M., Versteeg G.F. Mass transfer with complex chemical reaction in gas-liquid systems-I. Consecutive reversible reactions with equal diffusivities. Chem. Eng. Sci. 1999, 54:121-136.
16. 2 cleaner system by using aqueous solutions of monoethanolamine and diethanolamine. Ind. Eng. Chem. Res. 2003, 42:4861-4866.
17. Wilke C.R., Chang P. Correlation of diffusion coefficients in dilute solutions. AIChE J. 1955, 1:264-270.
18. Battino R. Solubility Data Series, vol. 7, Oxygen and Ozone 1981, Pergamon Press, Oxford, p. 274.
19. Young C.L. Solubility Data Series, vol. 8, Oxides of Nitrogen 1981, Pergamon Press, Oxford, p. 343.
20. Jiang X.Z. Theory and Application Basis of Gas-Liquid Reaction (in Chinese) 1989, Hydrocarbon Processing Press, Peking, p. 129.
21. 3 catalyst. Ind. Eng. Chem. Res. 2005, 44:41-50.