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Volumn 26, Issue 18, 2010, Pages 14923-14928

Controlled assembly of janus nanoparticles

Author keywords

[No Author keywords available]

Indexed keywords

AFM; AIR/WATER INTERFACES; AQUEOUS SOLUTIONS; BREATHING MODES; CONTROLLED ASSEMBLY; DYNAMIC LIGHT SCATTERING MEASUREMENT; FTIR MEASUREMENTS; GAUCHE DEFECTS; HYDROGEN BONDING INTERACTIONS; HYDROXYL MOIETY; INTENSITY PROFILES; LIGAND EXCHANGE REACTIONS; MINIMAL INTERACTIONS; PROPANEDIOLS; PYRIDINE RINGS; RAMAN SPECTROSCOPIC; SHARP CONTRAST; SOLID FILMS; STABLE AGGREGATES; TEM; TRANS CONFORMATIONS; VIBRATIONAL FEATURES; WATER MOLECULE;

EID: 77956597969     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la102540n     Document Type: Article
Times cited : (34)

References (36)
  • 15
    • 0035900106 scopus 로고    scopus 로고
    • Chen, S. W. Langmuir 2001, 17, 6664-6668
    • (2001) Langmuir , vol.17 , pp. 6664-6668
    • Chen, S.W.1
  • 16
    • 0035353399 scopus 로고    scopus 로고
    • Chen, S. W. Langmuir 2001, 17, 2878-2884
    • (2001) Langmuir , vol.17 , pp. 2878-2884
    • Chen, S.W.1
  • 22
    • 77956571596 scopus 로고    scopus 로고
    • http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre-index.cgi?lang=eng.
  • 32
    • 77956597648 scopus 로고    scopus 로고
    • One may note that nanoparticle aggregates started to form at much lower concentrations as shown in Figures 1 and 2. Thus the selection of this concentration as CMC is somewhat arbitrary, but it may represent an upper limit. Experimentally we first prepared the nanoparticles at 1 mg/mL, and then diluted the solutions to varied lower concentrations (0.004 to 0.4 mg/mL). The fact that we observed drastic variation of the dimensions of the nanoparticle aggregates suggests that the nanoparticle aggregates dissembled at concentrations below the CMC value, and the nanoparticle assembly was driven by thermodynamics rather than kinetics, analogous to conventional surfactant molecules
    • One may note that nanoparticle aggregates started to form at much lower concentrations as shown in Figures 1 and 2. Thus the selection of this concentration as CMC is somewhat arbitrary, but it may represent an upper limit. Experimentally we first prepared the nanoparticles at 1 mg/mL, and then diluted the solutions to varied lower concentrations (0.004 to 0.4 mg/mL). The fact that we observed drastic variation of the dimensions of the nanoparticle aggregates suggests that the nanoparticle aggregates dissembled at concentrations below the CMC value, and the nanoparticle assembly was driven by thermodynamics rather than kinetics, analogous to conventional surfactant molecules.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.