Comparing linear free energy relationships for organic chemicals in soils: Effects of soil and solute properties

Environmental Science and Technology

Volumn 44, Issue 18, 2010, Pages 6971-6977

  Faria, Isabel R ^a   Young, Thomas M ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS CONCENTRATIONS; AROMATIC CONTENTS; AROMATIC ORGANIC COMPOUNDS; AVERAGE DEVIATION; DISSOLVED ORGANIC MATTERS; EXPERIMENTAL DATA; LINEAR FREE ENERGY RELATIONSHIPS; MULTIPARAMETERS; NATURAL SORBENTS; ORGANIC MATTER; PHYSICAL CHEMICAL PROPERTY; SOIL ORGANIC MATTERS; SOLUTE PROPERTIES; SORPTION COEFFICIENTS; SORPTION ISOTHERMS; STRUCTURAL DESCRIPTORS;

AROMATIC COMPOUNDS; BENZENE; BIOGEOCHEMISTRY; BIOLOGICAL MATERIALS; CHEMICAL COMPOUNDS; CHEMICAL PROPERTIES; FREE ENERGY; ORGANIC CARBON; SOIL TESTING; SOILS; SORPTION;

ORGANIC CHEMICALS;

ORGANIC COMPOUND; ORGANIC MATTER; SORBENT;

AQUEOUS SOLUTION; BENZENE; CARBON; CHEMICAL COMPOSITION; COMPARATIVE STUDY; DISSOLVED ORGANIC MATTER; PHYSICOCHEMICAL PROPERTY; SOIL CHEMISTRY; SOIL ORGANIC MATTER; SOLUTE; SORPTION;

ACCURACY; AQUEOUS SOLUTION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL COMPOSITION; CONCENTRATION (PARAMETERS); ENERGY; ISOTHERM; PHYSICAL CHEMISTRY; QUANTITATIVE ANALYSIS; SOIL POLLUTION; SOLUTE;

ADSORPTION; CHLOROBENZENES; LINEAR ENERGY TRANSFER; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; ORGANIC CHEMICALS; SOIL; THERMODYNAMICS;

EID: 77956554585     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es100440a     Document Type: Article

References (26)

1. Alexander, M. Aging, bioavailability, and overestimation of risk from environmental pollutants Environ. Sci. Technol. 2000, 34 (20) 4259-4265
2. Lu, Y.; Pignatello, J. J. Demonstration of the "conditioning effect" in soil organic matter in support of a pore deformation mechanism for sorption hysteresis Environ. Sci. Technol. 2002, 36 (21) 4553-4561
3. Weber, W. J.; Leboeuf, E. J.; Young, T. M.; Huang, W. L. Contaminant interactions with geosorbent organic matter: Insights drawn from polymer sciences Water Res. 2001, 35 (4) 853-868
4. Goss, K. U.; Schwarzenbach, R. P. Linear free energy relationships used to evaluate equilibrium partitioning of organic compounds Environ. Sci. Technol. 2001, 35 (1) 1-9
5. Niederer, C.; Schwarzenbach, R. P.; Goss, K. U. Elucidating differences in the sorption properties of 10 humic and fulvic acids for polar and nonpolar organic chemicals Environ. Sci. Technol. 2007, 41 (19) 6711-6717
6. Doucette, W. J. Quantitative structure-activity relationships for predicting soil-sediment sorption coefficients for organic chemicals Environ. Toxicol. Chem. 2003, 22 (8) 1771-1788
7. Nguyen, T. H.; Goss, K. U.; Ball, W. P. Polyparameter linear free energy relationships for estimating the equilibrium partition of organic compounds between water and the natural organic matter in soils and sediments Environ. Sci. Technol. 2005, 39 (4) 913-924
8. Malcolm, H. M.; Howe, P. D.; Dobson, S. Chlorobenzenes other than hexachlorobenzene: Environmental aspects; World Health Organization: London, 2004; p 33.
9. Wilson, S. C.; Jones, K. C. Bioremediation of soil contaminated with Polynuclear Aromatic Hydrocarbons (PAHs)-a review Environ. Pollut. 1993, 81 (3) 229-249
10. Ju, D. Y.; Young, T. M. Effects of competitor and natural organic matter characteristics on the equilibrium sorption of 1,2-dichlorobenzene in soil and shale Environ. Sci. Technol. 2004, 38 (22) 5863-5870
11. Watanabe, N.; Schwartz, E.; Scow, K. M.; Young, T. M. Relating desorption and biodegradation of phenanthrene to SOM structure characterized by quantitative pyrolysis GC-MS Environ. Sci. Technol. 2005, 39 (16) 6170-6181
12. Ju, D.; Young, T. M. The influence of the rigidity of geosorbent organic matter on non-ideal sorption behaviors of chlorinated benzenes Water Res. 2005, 39 (12) 2599-2610
13. Watanabe, N. Phenanthrene sorption/desorption by geosorbent: Role of soil organic matter and reactive mineral characteristics; University of California: Davis, CA, USA, 2006.
14. Ran, Y.; Huang, W. L.; Rao, P. S. C.; Liu, D. H.; Sheng, G. Y.; Fu, J. M. The role of condensed organic matter in the nonlinear sorption of hydrophobic organic contaminants by a peat and sediments J. Environ. Qual. 2002, 31 (6) 1953-1962
15. Manes, M.; Hofer, L. J. E. Application of Polanyi adsorption potential theory to adsorption from solution on activated carbon J. Phys. Chem. 1969, 73 (3) 584-590
16. Greenbank, M.; Manes, M. Application of the Polanyi adsorption potential theory to adsorption from solution on activated carbon 0.12. Adsorption of organic liquids from binary liquid-solid mixtures in water J. Phys. Chem. 1982, 86 (21) 4216-4221
17. Xia, G. S.; Ball, W. P. Adsorption-partitioning uptake of nine low-polarity organic chemicals on a natural sorbent Environ. Sci. Technol. 1999, 33 (2) 262-269
18. Miller, J. C.; Miller, J. N. Statistics for analytical chemistry, 2nd ed.; Ellis Horwood Limited, Halsted Press, John Wiley & Sons: Chichester, 1988.
19. OC) at environmentally relevant sorbate concentrations Environ. Sci. Technol. 2009, 43 (9) 3094-3100
20. Seth, R.; Mackay, D.; Muncke, J. Estimating the organic carbon partition coefficient and its variability for hydrophobic chemicals Environ. Sci. Technol. 1999, 33 (14) 2390-2394
21. Abraham, M. H.; Ibrahim, A.; Zissimos, A. M. Determination of sets of solute descriptors from chromatographic measurements J. Chromatogr., A 2004, 1037 (1-2) 29-47
22. Abraham, M. H.; Chadha, H. S.; Whiting, G. S.; Mitchell, R. C. Hydrogen-Bonding 32. An analysis of water-octanol and water-alkane partitioning and the δLog P parameter of Seiler J. Pharm. Sci. 1994, 83 (8) 1085-1100
23. Endo, S.; Grathwohl, P.; Haderlein, S. B.; Schmidt, T. C. Compound-specific factors influencing sorption nonlinearity in natural organic matter Environ. Sci. Technol. 2008, 42 (16) 5897-5903
24. Zhu, D. Q.; Pignatello, J. J. A concentration-dependent multi-term linear free energy relationship for sorption of organic compounds to soils based on the hexadecane dilute-solution reference state Environ. Sci. Technol. 2005, 39 (22) 8817-8828
25. Huang, W. L.; Weber, W. J. A distributed reactivity model for sorption by soils and sediments. 10. Relationships between desorption, hysteresis, and the chemical characteristics of organic domains Environ. Sci. Technol. 1997, 31 (9) 2562-2569
26. Kleineidam, S.; Schuth, C.; Grathwohl, P. Solubility-normalized combined adsorption-partitioning sorption isotherms for organic pollutants Environ. Sci. Technol. 2002, 36 (21) 4689-4697