PVTx measurements of water-n-pentane mixtures in critical and supercritical regions

Journal of Chemical and Engineering Data

Volumn 55, Issue 9, 2010, Pages 3247-3261

  Rasulov, Suleiman M ^a   Abdulagatov, Ilmutdin M ^b,c  

^a INSTITUTE OF PHYSICS   (Russian Federation)

^b Institute for Geothermal Problems   (Russian Federation)

^c NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOUNDARY CURVES; BREAK-POINTS; CONFIDENCE LEVELS; COVERAGE FACTORS; CRITICAL CURVE; CRITICAL END POINTS; CRITICAL PROPERTIES; DENSITY RANGE; HIGH DENSITY; LIQUID-LIQUIDS; LOW DENSITY; MOLE FRACTION; N-PENTANE MIXTURES; PHASE DATA; PVTX MEASUREMENTS; PVTX PROPERTIES; SUPER-CRITICAL REGIONS;

BINARY MIXTURES; LIQUIDS; PARAFFINS; TEMPERATURE MEASUREMENT;

UNCERTAINTY ANALYSIS;

EID: 77956536148     PISSN: 00219568     EISSN: 15205134     Source Type: Journal    
DOI: 10.1021/je100073y     Document Type: Article

References (48)

1. Morrow, N. M. Interface Phenomena in Petroleum Recovery; Dekker: New York, 1991; p 1.
2. Siskin, M.; Katritzky, A. R. Reactivity of organic compounds in hot water: geological and technological implications Science 1991, 254, 231-237
3. Weingaertner, H.; Franck, E. U. Supercritical water Angew. Chem., Int. Ed. 2005, 44, 2672-2692
4. OBrien, C. P.; Theis, M. C.; Bruce, D. A. Supercritical water oxidation of the PCB congener 2-chlorobiphenil in methanol solutions: a kinetic analysis Environ. Sci. Technol. 2005, 39, 6839-6844
5. Eckert, C. A.; Liotta, C. L.; Bush, D.; Brown, J. S.; Hallett, J. P. Sustainable reactions in tunable solvents J. Phys. Chem. 2004, 108, 18108-180118
6. de Loos, T. W.; van Dorp, J. H.; Lichtenthaler, R. N. Phase equilibria and critical phenomena in fluid (n -alkane + water) systems at high pressures and temperatures Fluid Phase Equilib. 1983, 10, 279-287
7. Brunner, E. Fluid mixtures at high pressures. IX. Phase separation and critical phenomena in 23 (n -alkane + water) mixtures J. Chem. Thermodyn. 1990, 22, 335-353
8. Connolly, J. F. Solubility of hydrocarbons in water near the critical temperature J. Chem. Eng. Data 1966, 11, 13-17
9. Roof, J. G. Three-phase critical point in hydrocarbon + water systems J. Chem. Eng. Data 1970, 15, 301-303
10. Anisimov, M. A.; Sengers, J. V. Critical region. In Equations of State for Fluids and Fluids Mixtures; Sengers, J. V.; Kayser, R. F.; Peters, C. J.; White, H. J., Eds.; Elsevier: Amsterdam, 2000; pp 381-434.
11. Fisher, M. E. Renormalization of the critical exponents by hidden variables Phys. Rev. B 1968, 176, 257-271
12. de Loos, T. W.; Wijen, A. J. M.; Diepen, G. A. M. Phase equilibria and critical phenomena in fluid (propane + water) at high pressures and temperatures J. Chem. Thermodyn. 1980, 12, 193-204
13. Neichel, M.; Franck, E. U. Critical curves and phase equilibria of water- n -alkane binary systems to high pressures and temperatures J. Supercrit. Fluids 1996, 9, 69-74
14. Abdulagatov, I. M.; Bazaev, A. R.; Bazaev, E. A.; Saidakhmedova, M. B.; Ramazanova, A. E. Excess, partial, and apparent molar volumes of n -alkanes in near- and supercritical water J. Solution Chem. 1998, 27, 731-753
15. Abdulagatov, I. M.; Bazaev, A. R.; Bazaev, E. A.; Saidakhmedova, M. B.; Ramazanova, A. E. Volumetric properties of near- and supercritical water- n -pentane mixtures: Molar, excess, partial, and apparent volumes J. Chem. Eng. Data 1998, 43, 451-458
16. Scheffer, F. E. On mixing in a binary system for which the three phase pressure is greater than the sum of the vapor tensions of the two components Proc. Sect. Sci. 1914, 17, 834-839
17. Jou, F. Y.; Mather, A. E. Vapor-liquid-liquid locus of the system pentane + water J. Chem. Eng. Data 2000, 45, 728-729
18. Gillespie, P. C.; Wilson, G. M. Vapor-liquid and liquid-liquid equilibria: Water-methane, water-carbon dioxide, water-hydrogen sulfide, water-n-pentane, water-methane-n-pentane; Gas Processors Association Research Report RR-48, Project 758-B-77 for Wiltec Res. Co., Inc.: Provo, UT, 1982.
19. Wormald, C. J.; Colling, C. N.; Lancaste, N. M.; Sellers, A. J. Excess enthalpy experimental data. Binary mixtures: Water + n-pentane; Water + n-hexane; Water + n-heptane, and Water + n-octane; Research Report, RR-68, University of Bristol, Bristol, U.K., 1983.
20. Rasulov, S. M. PVT properties and phase equilibrium in binary water + n -pentane mixture Russ. J. Phys. Chem. 2009, 83, 756-759
21. Kamilov, I. K.; Stepanov, G. V.; Rasulov, S. M. Liquid-liquid and liquid-gas equilibrium curves and critical lines of water + n -hexane mixture High Temp. High Pressures 1997, 29, 491-495
22. Rasulov, S. M.; Isaev, I. A. Phase equilibrium and the critical lines in water + n -pentane and water + n -hexane mixtures Russ. High Temp. 2006, 44, 847-859
23. Rasulov, S. M.; Rasulov, A. R. Liquid-liquid equilibria and PVT properties of binary water- n -hexane mixtures Russ. J. Phys. Chem. 2000, 74, 1613-1615
24. Rasulov, S. M.; Rasulov, A. P. PVT -dependence of the water + n -octane-sodium dodecylsulfate microemulsion + n -pentanol for two compositions Russ. High Temp. 2008, 46, 953-956
25. Rasulov, A. R.; Rasulov, S. M.; Radzhabova, L. M. In Thermal properties of n-butanol in the near-critical region, Proc. 12th Russian Thermophys. Prop. Conf., Moscow, 2008; pp 286-289.
26. Wagner, W.; Pruss, A. The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use J. Phys. Chem. Ref. Data 2002, 31, 387-535
27. Mather, A. E.; Sadus, R. J.; Franck, E. U. Phase equilibria in (water + krypton) at pressures from 31 to 273 MPa and temperatures from 610 to 660 K and in (water + neon) from 45 to 255 MPa and from 660 to 700 K J. Chem. Thermodyn. 1993, 25, 771-779
28. Shmonov, V. M.; Sadus, R. J.; Franck, E. U. High-pressure phase equilibria and supercritical pVT data of the binary water + methane mixture to 723 K and 200 MPa J. Phys. Chem. 1993, 97, 9054-9059
29. Lentz, H. A method of studying the behavior of fluid phases at high pressures and temperatures Rev. Sci. Instrum. 1968, 40, 371-372
30. Levelt-Sengers, J. M. H.; Hastings, J. R. Equation of state of ethylene vapor between 223 and 273 K by the Burnett method Int. J. Thermophys. 1981, 2, 269-288
31. Bazaev, A. R.; Abdulagatov, I. M.; Bazaev, E. A.; Abdurashidova, A. A.; Ramazanova, A. E. PVT measurements for pure methanol in the near-critical and supercritical regions J. Supercrit. Fluids 2007, 41, 217-226
32. 2O mixtures up to 500 °C and 1500 bar High Temp. High Pressures 1977, 9, 305-312
33. 2O + methanol mixture in the sub-critical and supercritical regions Int. J. Thermophys. 2004, 25, 804-838
34. Polikhronidi, N. G.; Abdulagtaov, I. M.; Batyrova, R. G.; Stepanov, G. V. Experimental study of the PVTx properties of aqueous ammonia mixture in the critical and supercritical regions Int. J. Refrig. 2009, 32, 1897-1913
35. Kamilov, I. K.; Stepanov, G. V.; Abdulagatov, I. M.; Rasulov, A. R.; Milikhina, E. M. Liquid-liquid-vapor and liquid-vapor phase transitions in aqueous n -hexane mixtures from isochoric heat capacity measurements J. Chem. Eng. Data 2001, 46, 1556-1567
36. Kamilov, I. K.; Stepanov, G. V.; Malysheva, L. V.; Rasulov, A. R.; Rasulov, S. M.; Shakhbanov, K. A. Phase equilibrium curves and critical lines of n -hexane-water: liquid-liquid and liquid-gas High Temp. High Pressures 1997, 29, 237-246
37. Polikhronidi, N. G.; Stepanov, G. V.; Abdulagatov, I. M.; Batyrova, R. G. Thermodynamic study of the n -octane-1-pentanol-sodium dodecyl sulfate solutions in water Thermochim. Acta 2007, 454, 99-108
38. S) of high-purity toluene near the critical point Fluid Phase Equilib. 2008, 263, 71-84
39. Polikhronidi, N. G.; Abdulagatov, I. M.; Batyrova, R. G. Features of isochoric heat capacity measurements near the phase transition points Fluid Phase Equilib. 2002, 201, 269-286
40. Abdulagatov, A. I.; Stepanov, G. V.; Abdulagatov, I. M. Krichevskii parameter and thermodynamic properties infinite dilute aqueous solutions near the critical point of pure water Russ. Supercrit. Fluids Theory Pract. 2007, 2, 20-54
41. Plyasunov, A. V.; Shock, E. L. Estimation of the Krichevskii parameter for aqueous nonelectrolytes J. Supercrit. Fluids 2001, 20, 91-103
42. Plyasunov, A. V.; Shock, E. L. Prediction of the vapor-liquid distribution constants for volatile nonelectrolytes in water up to its critical temperature Geochim. Cosmochim. Acta 2003, 67, 4981-5009
43. Abdulagatov, A. I.; Stepanov, G. V.; Abdulagatov, I. M. Crossover equation of state and microstructure properties of infinite dilute solutions near the critical point of pure solvent Russ. J. Struct. Chem. 2001, 48, 585-597
44. Krichevskii, I. R. Thermodynamics of critical phenomena in infinitely dilute binary solutions Russ. J. Phys. Chem. 1967, 41, 1332-1338
45. Levelt Sengers, J. M. H. Solubility near the sovents critical point J. Supercrit. Fluids 1991, 4, 215-222
46. Levelt-Sengers, J. M. H. Saturated properties of ordinary water substance. In Physical Chemistry of Aqueous Systems, Proceedings of the 12th International Conference Properties of Water and Steam, Begell House, NY, 1995; White, H. J.; Sengers, J. V.; Neumann, D. B.; Bellows, J. C., Eds.; pp A143-149.
47. Debenedetti, P. G.; Mohamed, R. S. Attractive, weakly attractive and repulsive near-critical systems J. Chem. Phys. 1989, 90, 4528
48. Span, R.; Wagner, W. Equation of state for technical applications. II. Results for Nonpolar Fluids Int. J. Thermophys. 2003, 24, 41-109