Experimental study of the spontaneous thermal homopolymerization of methyl and n-butyl acrylate

Journal of Applied Polymer Science

Volumn 118, Issue 4, 2010, Pages 1898-1909

  Srinivasan, Sriraj ^a   Kalfas, George ^b   Petkovska, Violeta I ^b   Bruni, Christopher ^b   Grady, Michael C ^b   Soroush, Masoud ^a  

^a Drexel University   (United States)

^b DUPONT COMPANY   (United States)

Author keywords

Alkyl acrylates; Butyl acrylate; MALDI; Methyl acrylate; Spontaneous thermal polymerization

Indexed keywords

ALKYL ACRYLATES; BUTYL ACRYLATE; MALDI; METHYL ACRYLATES; THERMAL POLYMERIZATIONS;

ACRYLIC MONOMERS; ACRYLICS; ALKYLATION; AROMATIC HYDROCARBONS; BATCH REACTORS; DESORPTION; DIMETHYL SULFOXIDE; FREE RADICAL REACTIONS; FREE RADICALS; HOMOPOLYMERIZATION; MOLECULAR OXYGEN; MOLECULAR WEIGHT; ORGANIC SOLVENTS; SALTS; XYLENE;

POLYMERS;

EID: 77956463083     PISSN: 00218995     EISSN: 10974628     Source Type: Journal    
DOI: 10.1002/app.32313     Document Type: Article

References (38)

1. VOC's Directive; EU Committee of the American Chamber of Commerce in Belgium, ASBL/VZw: Brussels, 1996.
2. Adamsons, K.; Blackman, G.; Gregorovich, B.; Lin, L.; Matheson, R. Prog Org Coat 1998, 34, 64.
3. Grady, M. C.; Simonsick, W. J.; Hutchinson, R. A. Macromol Symp 2002, 182, 149.
4. Peck, A. N. F.; Hutchinson, R. A.; Grady, M. C. Polym Prepr 2002, 43, 154.
5. Peter, A. C.; Moskal, M. G. Higher-Solids, Higher Quality Acrylic Coatings Resins Produced with Organic Peroxide Initiators. http://www.arkema- inc.com/literature/pdf/304pdf. Arkema, Inc.: King of Prussia, PA.
6. Peck, A. N. F.; Hutchinson, R. A. Macromolecules 2004, 37, 5944.
7. Buback, M.; Klingbeil, S.; Sandmann, J.; Sderra, M. B.; Vögele, H.; Wackerbarth, H.; Wittkowski, L. Z. Phys Chem 1999, 210, 199.
8. Buback, M.; King, M.; Schamtz, S. Z. Phys Chem 2005, 219, 1.
9. Chiefari, J.; Jeffery, J.; Mayadunne, R. T. A.; Moad, G.; Rizzardo, E.; Thang, S. G. Macromolecules 1999, 32, 7700.
10. Grady, M. C.; Quan, C.; Soroush, M. U. S. Pat. Appl. 60/484, 393 (2003).
11. Quan, C.; Soroush, M.; Grady, M. C.; Hansen, J. E.; Simonsick, W. J. Macromolecules 2005, 38, 7619.
12. Rantow, F. S.; Soroush, M.; Grady, M. C.; Kalfas, G. A. Polymer 2006, 47, 1423.
13. Junkers, T.; Bennet, F.; Koo, S. S.; Barner-Kowollik, B. J Polym Sci - Polym Chem 2008, 46, 3433.
14. Lehrle, R. S.; Shortland, A. Eur Polym J 1988. 24, 425.
15. (a) Mayo, F. R. J Am Chem Soc 1953, 75, 6133;
16. (b) Mayo, F. R. J Am Chem Soc 1968, 90, 1289.
17. Pryor, W. A.; Lasswell, L. D. Adv Free Radical Chem 1975, 5, 27.
18. Flory, P. J. J Am Chem Soc 1937 59, 241.
19. Stickler, M.; Meyerhoff, G. Makromol Chem 1978, 179, 2729.
20. Stickler, M.; Meyerhoff, G. Makromol Chem 1980, 181, 131.
21. Brand, E.; Stickler, M.; Meyerhoff, G. Makromol Chem 1980, 181, 913.
22. Lingnau, J.; Stickler, M.; Meyerhoff, G. Eur Polym J 1980, 16, 785.
23. Stickler, M.; Meyerhoff, G. Polymer 1981, 22, 928.
24. Lingnau, J.; Meyerhoff, G. Polymer 1983, 24, 1473.
25. Lingnau, J.; Meyerhoff, G. Makromol Chem 1984, 185, 587.
26. Lingnau, J.; Meyerhoff, G. Macromolecules 1984, 17, 941.
27. Pryor, P. A.; Lino, M.; Newkome, G. R. J Am Chem Soc 1977, 99, 6003.
28. Creel, H. S. TRIP 1993, 1, 336.
29. Aaserud, D. J.; Simonsick W. J., Jr. Prog Org Coat 1998, 34, 206.
30. Nielsen, M. W. F. Mass Spectrom Rev 1999, 18, 309, and references therein.
31. Gupta, S. N.; Nandi, U. S. J Polym Sci Part A-1: Polym Chem 1970, 8, 1493.
32. Kaim, A. J Polym Sci Polym Lett Ed 1984, 22, 203.
33. Kaim, A.; Kaminski, J.; Kolodziejski, W. Acta Chim Hung 1988, 125, 141.
34. Gadkary, S. D.; Kapur, S. L. D. Makromol Chem 1955, 17, 29.
35. Kirk, A. D. Can J Chem 1965, 43, 2236.
36. Bhanu, V. A.; Kishore, K. Chem Rev 1991, 91, 99.
37. Talpur, M. M. A.; Oracz, P.; Kaim, A. Polymer 1996, 37, 4149.
38. Srinivasan, S.; Lee, M. W.; Grady, M. C.; Soroush, M.; Rappe, A. M. J. Phys Chem A 2009, 110, 10787.