The role of iodine monochloride for the oxidation of elemental mercury

Journal of Hazardous Materials

Volumn 183, Issue 1-3, 2010, Pages 132-137

  Qu, Zan ^a   Yan, Naiqiang ^a   Liu, Ping ^a   Jia, Jinping ^a   Yang, Shijian ^a  

^a SHANGHAI JIAO TONG UNIVERSITY   (China)

Author keywords

Coal fired flue gas; Elemental mercury; Iodine monochloride

Indexed keywords

COAL FIRED FLUE GAS; ELEMENTAL MERCURY; GAS-PHASE REACTIONS; IODINE MONOCHLORIDE; PILOT SCALE TEST; REMOVAL EFFICIENCIES;

COAL; COAL INDUSTRY; FLUE GASES; FLUES; GASES; INDUSTRIAL CHEMICALS; IODINE; MERCURY COMPOUNDS; OXIDATION; PHASE INTERFACES; RATE CONSTANTS; REACTION INTERMEDIATES; REMOVAL;

MERCURY (METAL);

CHLORIDE; IODINE; MERCURY; MERCURY CHLORIDE; OXIDIZING AGENT;

CHLORIDE; COAL-FIRED POWER PLANT; FLY ASH; GAS PHASE REACTION; IODINE; MERCURY (ELEMENT); OXIDANT; OXIDATION; POLLUTANT REMOVAL;

ARTICLE; CHEMICAL REACTION; FLUE GAS; FLY ASH; OXIDATION; PREDICTION;

AIR POLLUTION; CHLORIDES; COAL; GASES; IODIDES; KINETICS; MERCURY; OXIDATION-REDUCTION; POWER PLANTS;

EID: 77956426765     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2010.06.126     Document Type: Article

References (23)

1. Saiz-Lopez A., Plane J.M.C. Novel iodine chemistry in the marine boundary layer. Geophys. Res. Lett. 2004, 31:L04112. doi:10.1029/2003GL019215.
2. Peters C., Pechtl S., Stutz J., Hebestreit K., Honninger G., Heumann K.G., Schwarz A., Winterlik J., Platt U. Reactive and organic halogen species in three different European coastal environments. Atmos. Chem. Phys. 2005, 5:3357-3375.
3. Garland J.A., Curtis H. Emission of iodine from the sea surface in the presence of ozone. J. Geophys. Res. 1981, 86:3183-3186.
4. Huang R.J., Hoffmann T. Development of a coupled diffusion denuder system combined with gas chromatography/mass spectrometry for the separation and quantification of molecular iodine and the activated iodine compounds iodine monochloride and hypoiodous acid in the marine atmosphere. Anal. Chem. 2009, 81:1777-1783.
5. McFiggans G., Cox R.A., Mossinger J.C., Allan B.J., Plane J.M.C. Active chlorine release from marine aerosols: roles for reactive iodine and nitrogen species. J. Geophys. Res. 2002, 107. D154271, ACH10-1-13.
6. Vogt R., Sander R., von Glasow R., Crutzen P.J. Iodine chemistry and its role in halogen activation and ozone loss in the marine boundary layer: a model study. J. Atmos. Chem. 1999, 32:375-395.
7. Schroeder W.H., Anlauf K.G., Barrie L.A., Lu J.Y., Steffen A., Schneeberger D.R., Berg T. Arctic springtime depletion of mercury. Nature 1998, 394:312-331.
8. Lindberg S.E., Brooks S., Lin C.J., Scott K.J., Landis M.S., Stevens R.K., Goodsite M., Richter A. Dynamic oxidation of gaseous mercury in the Arctic troposphere at polar sunrise. Environ. Sci. Technol. 2002, 36:1245-1256.
9. Vogt R., Crutzen P.J., Sander R. A mechanism for halogen release from sea-salt aerosol in the remote marine boundary layer. Nature 1996, 383:327-330.
10. Shepler B.C., Balabanov N.B., Peterson K.A. Ab initio thermochemistry involving heavy atoms: an investigation of the reactions Hg+IX (X=1, Br, Cl, O). J. Phys. Chem. A 2005, 109:10363-10372.
11. Yang H.Q., Xu Z.H., Fan M.H., Bland A.E., Judkins R.R. Adsorbents for capturing mercury in coal-fired boliler flue gas. J. Hazard. Mater. 2007, 146:1-11.
12. Wu Z.B., Jiang B.Q., Liu Y. Effect of transition metals addition on the catalyst of manganese/titania for low-temperature selective catalytic reduction of nitric oxide with ammonia. Appl. Catal. B: Environ. 2008, 79:347-355.
13. 2S. Fuel 2005, 84:1968-1974.
14. 2 catalysts. Environ. Sci. Technol. 2009, 43:1522-1527.
15. Liu S.H., Yan N.Q., Liu Z.R., Qu Z., Wang H.P., Chang S.G., Miller C. Using bromine gas to enhance mercury removal from flue gas of coal-fired power plants. Environ. Sci. Technol. 2007, 41:1405-1412.
16. Chi Y., Yan N.Q., Qu Z., Qiao S.H., Jia J.P. The performance of iodine on the removal of elemental mercury from the simulated coal-fired flue gas. J. Hazard. Mater. 2009, 166:776-781.
17. Sander S.P., Friedl R.R., Golden D.M., Kurylo M.J., Moortgat G.K., Keller-Rudek H., Wine P.H., Ravishankara A.R., Kolb C.E., Molina M.J., Finlayson-Pitts B.J., Huie R.E., Orkin V.L. Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15, JPL Publication 06-2 2006, Jet Propulsion Laboratory, Pasadena.
18. Saiz-lopez A., Saunders R.W., Joseph D.M., Ashworth S.H., Plane J.M.C. Absolute absorption cross-section and photolysis rate of I-2. Atmos. Chem. Phys. 2004, 4:1443-1450.
19. 2 radicals. J. Phys. Chem. 1990, 94:2927-2934.
20. Yan N.Q., Liu S.H., Chang S.G., Miller C. Method for the study of gaseous oxidants for the oxidation of mercury gas. Ind. Eng. Chem. Res. 2005, 44:5567-5574.
21. Donohoue D.L., Bauer D., Cossairt B., Hynes A.J. Temperature and pressure dependent rate coefficients for the reaction of Hg with Br and the reaction of Br with Br: a pulsed laser photolysis-pulsed laser induced fluorescence study. J. Phys. Chem. A 2006, 110:6623-6632.
22. S. Sjostrom, Evaluation of sorbent injection for mercury control. Topical Report for: Sunflower Elecric's Holcomb Station; Report to U.S. DOE/NETL, Cooperative Agreement No. DE-FC26-03NT41986; ADA-ES, 2005.
23. Qu Z., Yan N.Q., Liu P., Guo Y.F., Jia J.P. Oxidation and stabilization of elemental mercury from-coal fired flue gas by sulfur monobromide. Environ. Sci. Technol. 2010, 44:3889-3894.