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Volumn 29, Issue 17, 2010, Pages 3690-3693

Catalytic tail-to-tail selective dimerization of methyl methacrylate promoted by a ruthenium(0) complex

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEX 1; METHYL METHACRYLATES; TRIMERIZATION;

EID: 77956407158     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100646q     Document Type: Article
Times cited : (30)

References (31)
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    • Thermal dimerizations of MMA (ref 5a) and calcium methacrylate followed by treatment of diazomethane were reported (ref 5b).
    • Thermal dimerizations of MMA (ref 5a) and calcium methacrylate followed by treatment of diazomethane were reported (ref 5b). Albisetti, C. J.; England, D. C.; Hogsed, M. J.; Joyce, J. J. Am. Chem. Soc. 1956, 78, 472
    • (1956) J. Am. Chem. Soc. , vol.78 , pp. 472
    • Albisetti, C.J.1    England, D.C.2    Hogsed, M.J.3    Joyce, J.4
  • 17
    • 77956396817 scopus 로고
    • U.S. Patent, 4 451 665.
    • Nugent, W. A. U.S. Patent, 4 451 665, 1984.
    • (1984)
    • Nugent, W.A.1
  • 19
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    • Ger. Patent 3336691.
    • Wilke, G.; Sperling, K. Ger. Patent 3336691, 1985.
    • (1985)
    • Wilke, G.1    Sperling, K.2
  • 22
    • 77956407777 scopus 로고    scopus 로고
    • Abstracts of Papers, the 90th Annual Meeting of the Chemical Society of Japan, Osaka.
    • Matsuoka, S.; Washio, A.; Ohta, Z.; Katada, A.; Ichioka, K.; Takagi, K.; Suzuki, M. Abstracts of Papers, the 90th Annual Meeting of the Chemical Society of Japan, Osaka, 2010; 3F703.
    • (2010)
    • Matsuoka, S.1    Washio, A.2    Ohta, Z.3    Katada, A.4    Ichioka, K.5    Takagi, K.6    Suzuki, M.7
  • 24
    • 77956415235 scopus 로고    scopus 로고
    • The structure of trimer 3x is not clear at present, but 3x is estimated to be two regioisomers of trimer 3a on the basis of the GC-MS analysis. The yield of 3x was calculated on the basis of the GLC analysis with assumption of the same relative intensity as 3a.
    • The structure of trimer 3x is not clear at present, but 3x is estimated to be two regioisomers of trimer 3a on the basis of the GC-MS analysis. The yield of 3x was calculated on the basis of the GLC analysis with assumption of the same relative intensity as 3a.
  • 28
    • 77956415368 scopus 로고    scopus 로고
    • Ph.D. Thesis, Australian National University, Canberra.
    • Lu, Z. Ph.D. Thesis, Australian National University, Canberra, 1998.
    • (1998)
    • Lu, Z.1
  • 29
    • 77956411432 scopus 로고    scopus 로고
    • One of the reviewers mentioned a possibility for the formation of dimers by degradation of the trimer at high temperature because the selectivity of the dimer was increased with increase of the temperature. Because 3a is thermally stable under these conditions, we can rule out this possibility (see SI Figure S8).
    • One of the reviewers mentioned a possibility for the formation of dimers by degradation of the trimer at high temperature because the selectivity of the dimer was increased with increase of the temperature. Because 3a is thermally stable under these conditions, we can rule out this possibility (see SI Figure S8).
  • 30
    • 77956415100 scopus 로고    scopus 로고
    • Characteristic time-yield curves, initial formation of 2a followed by increase of 3a and 2b with decrease of 2a, was observed at 0 °C (see SI Figure S7).
    • Characteristic time-yield curves, initial formation of 2a followed by increase of 3a and 2b with decrease of 2a, was observed at 0 °C (see SI Figure S7).


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