U-Pb dating of calcite-aragonite layers in speleothems from hominin sites in South Africa by MC-ICP-MS

Quaternary Geochronology

Volumn 5, Issue 5, 2010, Pages 544-558

  Pickering, Robyn ^a,b   Kramers, Jan D ^a,c,d   Partridge, Tim ^c   Kodolanyi, Janos ^a   Pettke, Thomas ^a  

^a UNIVERSITY OF BERN   (Switzerland)

^b UNIVERSITY OF MELBOURNE   (Australia)

^c UNIVERSITY OF THE WITWATERSRAND   (South Africa)

^d UNIVERSITY OF JOHANNESBURG   (South Africa)

Author keywords

234U 238U ratios; Beta scanning imagery; Calcite aragonite; Lead isotopes; MC ICP MS; Speleothems; Uranium lead dating

Indexed keywords

ARAGONITE; CALCITE; GEOCHRONOLOGY; INDUCTIVELY COUPLED PLASMA METHOD; LEAD ISOTOPE; MASS SPECTROMETRY; RECRYSTALLIZATION; SPELEOTHEM; URANIUM SERIES DATING; URANIUM-LEAD DATING;

SOUTH AFRICA;

EID: 77956338832     PISSN: 18711014     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.quageo.2009.12.004     Document Type: Article

References (77)

1. 238U by using MC-ICPMS. International Journal of Mass Spectrometry 2004, 237:107-118.
2. Amemiya Y., Miyahara J. Imaging plate illuminates many fields. Nature 1988, 336:89-90.
3. Auler A.S., Pilo L.B., Smart P.L., Wang X.F., Hoffmann D., Richards D.A., Edwards R.L., Neves W.A., Cheng H. U-series dating and taphonomy of Quaternary vertebrates from Brazilian caves. Palaeogeography, Palaeoclimatology, Palaeoecology 2006, 240:508-522.
4. Ayliffe L.K., Marianelli P.C., Moriarty K.C., Wells R.T., McCulloch M.T., Mortimer G.E., Hellstrom J.C. 500 ka precipitation record from southeastern Australia: evidence for interglacial relative aridity. Geology 1998, 26:147-150.
5. Balter V., Blichert-Toft J., Braga J., Telouk P., Thackeray F., Albarede F. U-Pb dating of fossil enamel from the Swartkrans Pleistocene hominid site, South Africa. Earth and Planetary Science Letters 2008, 267:236-246.
6. 238U. Geochimica et Cosmochimica Acta 1993, 57:257-276.
7. Bar-Matthews M., Ayalon A., Kaufman A. Late quaternary paleoclimate in the eastern Mediterranean region from stable isotope analysis of speleothems at Soreq Cave, Israel. Quaternary Research 1997, 47:155-168.
8. Berger L.R., Lacruz R., de Ruiter D.J. Brief communication: Revised age estimates of Australopithecus-bearing deposits at Sterkfontein, South Africa. American Journal of Physical Anthropology 2002, 119:192-197.
9. Bischoff W.D., Fyfe W.S. Catalysis, inhibition, and the calcite-aragonite problem. 1. The aragonite-calcite transformation. American Journal of Science 1968, 266:65-79.
10. Borsato A., Frisia S., Fairchild I.J., Somogyi A., Susini J. Trace element distribution in annual stalagmite laminae mapped by micrometer-resolution X-ray fluorescence: implications for incorporation of environmentally significant species. Geochimica et Cosmochimica Acta 2007, 71:1494-1512.
11. Burton E.A., Walter I.M. Relative precipitation rates of aragonite and Mg calcite from seawater. Temperature or carbonate ion control?. Geology 1987, 15:111-114.
12. Cheng H., Edwards R.L., Hoff J., Gallup C.D., Richards D.A., Asmerom Y. The half-lives of uranium-234 and thorium-230. Chemical Geology 2000, 169:17-33.
13. Clarke R.J. First ever discovery of a well-preserved skull and associated skeleton of Australopithecus. South African Journal of Science 1998, 94:460-463.
14. Cliff R.A. Uranium-lead geochronology of speleothems. Eleventh Annual V.M. Goldschmidt Conference, Abstract #3350, LPI Contribution No. 1088 2001, Lunar and Planetary Science Institute, Houston, (CD-ROM).
15. Cole J.M., Nienstedt J., Spataro G., Rasbury E.T., Lanzirotti A., Celestian A.J., Nilsson M., Hanson G.N. Phosphor imaging as a tool for in situ mapping of ppm levels of uranium and thorium in rocks and minerals. Chemical Geology 2003, 193:127-136.
16. Cole J.M., Rasbury E.T., Hanson G.N., Montanez I.P., Pedone V.A. Using U-Pb ages of Miocene tufa for correlation in a terrestrial succession, Barstow Formation, California. Geological Society of America Bulletin 2005, 117:276-287.
17. Cooke H.B.S. The Pleistocene sequence in South Africa and problems of correlation. Background to Evolution in Africa 1967, 109-122. Chicago University Press, Chicago. W.W. Bishop, J.D. Clark (Eds.).
18. Cooke H.B.S. Plio-Pleistocene deposits and mammalian faunas of eastern and southern Africa. Proceedings of Fifth Congrès Néogène Méditerranéen Memoir 1974, 78:99-108.
19. Delson E. Cercopithecoid biochronology of the African Plio-Pleistocene: correlation among eastern and south hominid-bearing localities. Courier Forschungsinstitut Senckenberg 1984, 69:199-218.
20. Delson E. Chronology of South African Australopiths site units. Evolutionary History of the Robust Australopithecines 1988, 317-325. Aldine de Gruyter, New York. F.E. Grine (Ed.).
21. Fleitmann D., Burns S.J., Mangini A., Mudelsee M., Kramers J., Villa I., Neff U., Al-Subbary A.A., Buettner A., Hippler D., Matter A. Holocene ITCZ and Indian monsoon dynamics recorded in stalagmites from Oman and Yemen (Socotra). Quaternary Science Reviews 2007, 26:170-188.
22. Frisia S., Borsato A., Fairchild I.J., McDermott F. Calcite fabrics, growth mechanisms, and environments of formation in speleothems from the Italian Alps and southwestern Ireland. Journal of Sedimentary Research 2000, 70(5):1183-1196.
23. Frisia S., Borsato A., Fairchild I.J., McDermott F., Selmo E.M. Aragonite-calcite relationships in speleothems (Grotte de Clamouse, France): Environment, fabrics, and carbonate geochemistry. Journal of Sedimentary Research 2002, 72:687-699.
24. Genty D., Blamart D., Ouahdi R., Gilmour M., Baker A., Jouzel J., Van-Exter S. Precise dating of Dansgaard-Oeschger climate oscillations in western Europe from stalagmite data. Nature 2003, 421:833-837.
25. Gutjahr A., Dabringhaus H., Lacmann R. Studies of the growth and dissolution kinetics of the CaCO3 polymorphs calcite and aragonite. 2. The influence of divalent cation additives on the growth and dissolution rates. Journal of Crystal Growth 1996, 158:310-315.
26. Harmon R.S., Atkinson T.C., Atkinson J.L. The mineralogy of Castleguard Cave, Columbia Icefields, Alberta, Canada. Arctic and Alpine Research 1983, 15:503-516.
27. 238U ratios. Earth and Planetary Science Letters 1993, 115:75-83.
28. Herries A.I.R., Adams J.W., Kuykendall K.L., Shaw J. Speleology and magnetobiostratigraphic chronology of the GD 2 locality of the Gondolin hominin-bearing paleocave deposits, North West Province, South Africa. Journal of Human Evolution 2006, 51:617-631.
29. Hoffmann D.L., Richards D.A., Elliott T.R., Smart P.L., Coath C.D., Hawkesworth C.J. Characterisation of secondary electron multiplier nonlinearity using MC-ICPMS. International Journal of Mass Spectrometry 2005, 244:97-108.
30. Hofmann A. Fractionation corrections for mixed-isotope spikes of Sr, K, and Pb. Earth and Planetary Science Letters 1971, 10:397-402.
31. Holmgren K., Lee-Thorp J.A., Cooper G.R.J., Lundblad K., Partridge T.C., Scott L., Sithaldeen R., Talma A.S., Tyson P.D. Persistent millennial-scale climatic variability over the past 25,000 years in Southern Africa. Quaternary Science Reviews 2003, 22:2311-2326.
32. Ivanovich M., Latham A.G., Ku T.-L. Uranium-series disequilibrium applications in geochronology. Uranium Series Disequilibrium: Applications to Earth, Marine and Environmental Sciences 1992, 62-94. Claredon, Oxford. M. Ivanovich, R.S. Harmon (Eds.).
33. Jackson S. LAMTRACE Data Reduction Software for LA-ICP-MS. Mineralogical Association of CanadaShort Course Series 2008, vol. 40:305-307. P. Sylvester (Ed.).
34. 238U. Phys. Rev. C 1971, 4:1889-1906.
35. Kamenov G.D., Mueller P.A., Perfit M.R. Optimization of mixed Pb-Tl solutions for high precision isotopic analyses by MC-ICP-MS. Journal of Analytical Atomic Spectrometry 2004, 19:1262-1267.
36. Kigoshi K. Alpha-Recoil Thorium-234-Dissolution into Water and Uranium-234/Uranium-238 Disequilibrium in Nature. Science 1971, 173.
37. Kramers J.D., Titschack J., Berger L., Rubidge B. Lessons from failed experiments on the U-Pb dating of fossils. Abstract volume Goldschmidt Conference. Geochimica et Cosmochimica Acta 2009, 73(13 Suppl. 1):A695.
38. Latham A.G., Schwarz H.P. Carbonate and sulphate precipitates. Uranium Series Disequilibrium: Applications to Earth, Marine and Environmental Sciences 1992, 423-459. Claredon, Oxford. M. Ivanovich, R.S. Harmon (Eds.).
39. Ludwig K.R. Isoplot/Ex Version 2.2 2000, Berkley Geochronology Centre, Special Publication No.1a.
40. Lugmair G.W., Galer S.J.G. Age and isotopic relationships among the angrites Lewis Cliff 86010 and Angra dos Reis. Geochimica et Cosmochimica Acta 1992, 56:1673-1694.
41. Lundberg J., Ford D.C., Hill C.A. A preliminary U-Pb date on cave spar, Big Canyon, Guadalupe Mountains, New Mexico, USA. Journal of Cave and Karst studies 2000, 62:144-148.
42. McDermott F. Palaeo-climate reconstruction from stable isotope variations in speleothems: a review. Quaternary Science Reviews 2004, 23:901-918.
43. McFadden P.L., Brock A., Partridge T.C. Palaeomagnetism and the age of the Makapansgat hominid site. Earth and Planetary Science Letters 1979, 44(3):373-382.
44. Meldrum F.C., Hyde S.T. Morphological influence of magnesium and organic additives on the precipitation of calcite. Journal of Crystal Growth 2001, 231:544-558.
45. Millard A.R., Hedges R.E.M. A diffusion-adsorption model of uranium uptake by archaeological bone. Geochimica et Cosmochimica Acta 1996, 60:2139-2152.
46. Nesse W.D. Introduction to Optical Mineralogy 1991, Oxford University Press,, New York. second ed.
47. Ordonez-Regil E., Schleiffer J.J., Adloff J.P. Chemical effects of α decay in uranium minerals. Radiochimica Acta 1989, 47:177-185.
48. Ortega R., Maire R., Deves G., Quinif Y. High-resolution mapping of uranium and other trace elements in recrystallized aragonite-calcite speleothems from caves in the Pyrenees (France): implication for U-series dating. Earth and Planetary Science Letters 2005, 237:911-923.
49. Partridge T.C., Watt I.B. The stratigraphy of the Sterkfontein hominid deposit and its relationship to the underground cave system. Palaeontologia Africana 1991, 28:35-40.
50. Partridge T.C., Latham A., Heslop D. Magnetostratigraphy of Makapansgat, Sterkfontein, Taung and Swartkrans. Oxford Monographs on Geology and Geophysics 2000, vol. 40:126-129. Oxford University Press. T.C. Partridge, R.R. Maud (Eds.).
51. Partridge T.C., Shaw J., Heslop D. Note on recent magnetostratigraphic analysis in Member 2 of the Sterkfontein formation. Oxford Monographs on Geology and Geophysics 2000, vol. 40:129-130. Oxford University Press. T.C. Partridge, R.R. Maud (Eds.).
52. Partridge T.C., Shaw J., Heslop D., Clarke R.J. The new hominid skeleton from Sterkfontein, South Africa: age and preliminary assessment. Journal of Quaternary Science 1999, 14:293-298.
53. Partridge T.C., Granger D.E., Caffee M.W., Clarke R.J. Lower Pliocene hominid remains from Sterkfontein. Science 2003, 300:607-612.
54. Pettke T. Analytical protocols for element concentration and isotope ratio measurements in fluid inclusions by LA-(MC)-ICP-MS. Mineralogical Association of Canada 2008, vol. 40:189-218. P. Sylvester (Ed.).
55. Pickering R., Hancox P.J., Lee-Thorp J.A., Grun R., Mortimer G.E., McCulloch M., Berger L.R. Stratigraphy, U-Th chronology, and paleoenvironments at Gladysvale Cave: insights into the climatic control of South African hominin-bearing cave deposits. Journal of Human Evolution 2007, 53:602-619.
56. Pike A.W.G., Hedges R.E.M., Van Calsteren P. U-series dating of bone using the diffusion-adsorption model. Geochimica et Cosmochimica Acta 2002, 66:4273-4286.
57. Polyak V., Hill C., Asmerom Y. Age and evolution of the Grand Canyon revealed by U-Pb dating of water table-type speleothems. Science 2008, 319:1377-1380.
58. Railsback L.B., Brook G.A., Chen J., Kalin R., Fleisher C.J. Environmental controls on the petrology of a late Holocene speleothem from Botswana with annual layers of aragonite and calcite. Journal of Sedimentary Research 1994, A64:147-155.
59. Reeder R.J., Nugent M., Lamble G.M., Tait C.D., Morris D.E. Uranyl incorporation into calcite and aragonite: XAFS and luminescence studies. Environmental Science and Technology 2000, 34:638-644.
60. Richards D.A., Bottrell S.H., Cliff R.A., Strohle K., Rowe P.J. U-Pb dating of a speleothem of Quaternary age. Geochimica et Cosmochimica Acta 1998, 62:3683-3688.
61. Richards D.A., Dorale J.A. U-series chronology of speleothems and paleoclimate. Uranium-series geochemistry. Reviews in Mineralogy and Geochemistry 2003, 52:407-460.
62. Richter S., Goldberg S.A. Improved techniques for high accuracy isotope ratio measurements of nuclear materials using thermal ionization mass spectrometry. International Journal of Mass Spectrometry 2003, 229:181-197.
63. Speer J.A. Crystal chemistry and phase relations of orthorhombic carbonates. Reviews in Mineralogy 11 1990, Mineralogical Society of America. R.J. Reeder (Ed.).
64. Sturchio N.C., Antonio M.R., Saderholm L., Sutton S.R., Brannon J.C. Tetravalent uranium in calcite. Science 1998, 281:971-973.
65. Thirlwall M.F. Inter-laboratory and other errors in Ph isotope analyses investigated using a Pb-207-Pb-204 double spike. Chemical Geology 2000, 163:299-322.
66. Tobias P.V. Implications of the new age estimates if the early South African hominids. Nature 1973, 246:79-83.
67. Tobias P.V. The fossil Hominids. Oxford Monographs on Geology and Geophysics 2000, No. 40:252-276. Oxford University Press. T.C. Partridge, R.R. Maud (Eds.).
68. Vrba, E.S., 1995. The fossil record of African antelopes (Mammalia, Bovidae) in relation to human evolution and paleoclimate. Paleoclimate and Evolution, with Emphasis on Human Origins, 385-424 pp.
69. Vrba E.S. The significance of bovid remains as indicators of environment and predation patterns. Fossils in the Making 1980, University of Chicago Press, Chicago. A.K. Behrensmeyer, A.P. Hill (Eds.).
70. Walker, J., 2005. Uranium-lead dating of Hominid fossil sites in South Africa. Ph.D dissertation, University of Leeds.
71. Walker J., Cliff R.A., Latham A.G. U-Pb isotopic age of the StW 573 hominid from Sterkfontein, South Africa. Science 2006, 314:1592-1594.
72. Wendt I., Carl C. U/Pb dating of discordant 0.1Ma old secondary U minerals. Earth and Planetary Science Letters 1985, 73:278-284.
73. Wilde S.A., Valley J.W., Peck W.H., Graham C.M. Evidence from detrital zircons for the existence of continental crust and oceans on the Earth 4.4 Gyr ago. Nature 2001, 409:175-178.
74. Wilkinson M.J. Geomorphic perspectives on the Sterkfontein Australopithecine breccias. Journal of Archaeological Science 1983, 10:515-529.
75. Wood B., Richmond B.G. Human evolution: taxonomy and paleobiology. Journal of Anatomy 2000, 197:19-60.
76. Woodhead J., Hellstrom J., Maas R., Drysdale R., Zanchetta G., Devine P., Taylor E. U-Pb geochronology of speleothems by MC-ICPMS. Quaternary Geochronology 2006, 1:208-221.
77. Woodhead J.D., Hellstrom J., Hergt J.M., Greig A., Maas R. Isotopic and elemental imaging of geological materials by laser ablation inductively coupled plasma-mass spectrometry. Geostandards and Geoanalytical Research 2007, 31:331-343.