Scandium-catalyzed propargylation of 1,3-diketones with propargyl alcohols bearing sulfur or selenium functional groups: Useful transformation to furans and pyrans

Chemical and Pharmaceutical Bulletin

Volumn 58, Issue 9, 2010, Pages 1180-1186

  Ohta, Katsuki ^a   Kobayashi, Taira ^a   Tanabe, Genzoh ^b   Muraoka, Osamu ^b   Yoshimatsu, Mitsuhiro ^a  

^a GIFU UNIVERSITY   (Japan)

^b KINKI UNIVERSITY   (Japan)

Author keywords

1,3 diketone; C C bond formation; Cyclization; Furan

Indexed keywords

1,3 DIKETONE; 1,3 DIPHENYL 2 [1 (1 NAPHTHYL) 3 (PHENYLSELANYL)PROP 2 YNYL]PROPANEDIONE; 1,3 DIPHENYL 2 [1 (4 CHLOROPHENYL) 3 (PHENYLSULFANYL)PROP 2 YNYL]PROPANEDIONE; 1,3 DIPHENYL 2 [1 (4 FLUOROFHENYL) 3 (PHENYLSELANYL)PROP 2 YNYL]PROPANEDIONE; 1,3 DIPHENYL 2 [1 (4 METHOXYPHENYL)] 3 [(PHENYLSULFANYL)PROP 2 YNYL]PROPANEDIONE; 1,3 DIPHENYL 2 [1 (BENZODIOXOL 5 YL) 3 (PHENYLSELANYL)PROP 2 YNYL]PROPANEDIONE; 1,3 DIPHENYL 2 [4 (METHOXYPHENYL) 3 (PHENYLSELANYL)PROP 2 YNYL]PROPANEDIONE; 2 [1 (1 NAPHTHYL) 3 (PHENYLSULFANYL)PROP 2 YN 1 YL] 1,3 CYCLOHEXANEDIONE; 2 [1 (2,4,6 TRIMETHYLPHENYL) 3 (PHENYLSULFANYL)PROP 2 YN 1 YL] 1,3 CYCLOHEXANEDIONE; 2 [1 (4 METHOXYPHENYL) 3 (PHENYLSULFANYL)PROP 2 YN 1 YL] 1,3 CYCLOHEXANEDIONE; 2 [1 (4 METHOXYPHENYL) 3 (PHENYLSULFANYL)PROP 2 YN 1 YL] 1,3 CYCLOPENTANEDIONE; 2 [1 (4 METHOXYPHENYL) 3 (PHENYLSULFANYL)PROP 2 YN 1 YL] 2 METHYL 1,3 CYCLOHEXANEDIONE; 2 [1 (4 METHOXYPHENYL) 3 (PHENYLSULFANYL)PROP 2 YNYL] 2,4 PENTANEDIONE; 3 (2 THIENYL) 2 (PHENYLSULFANYLMETHYL) 4,5,6,7 TETRAHYDROBENZOFURAN; 3 (4 METHOXYPHENYL) 2 (PHENYLSULFANYLMETHYL) 4,5,6,7 TETRAHYDROBENZOFURAN; 3 BENZOYL 2 PHENYL 5 (PHENYLSELANYLMETHYL) 4 (2 THIENYL)FURAN; 3 BENZOYL 4 (2 FURYL) 2 PHENYL 5 (PHENYLSELANYLMETHYL)FURAN; 3 BENZOYL 4 (3,4 DIMETHOXYPHENYL) 2 PHENYL 5 (PHENYLSULFANYLMETHYL)FURAN; 3 BENZOYL 4 (4 CHLOROPHENYL) 2 PHENYL 5 (PHENYLSULFANYLMETHYL)FURAN; 3 BENZOYL 4 (4 FLUOROPHENYL) 2 PHENYL 5 (PHENYLSELANYLMETHYL)FURAN; 3 BENZOYL 4 (4 METHOXYPHENYL) 2 PHENYL 5 (PHENYLSELANYLMETHYL)FURAN; 3 BENZOYL 4 (BENZODIOXOL 5 YL) 2 PHENYL 5 (PHENYLSULFANYLMETHYL)FURAN; 5 ACETYL 4 (2 THIENYL) 3 (PHENYLSULFANYL) 2 OXABICYCLO[3,3,0]OCTA 3,8 DIENE; 5 ACETYL 4 (4 METHOXYPHENYL) 3 (PHENYLSULFANYL) 2 OXABICYCLO[3,3,0]OCTA 3,8 DIENE; 9 ACETYL 3 (2 THIENYL) 2 (PHENYLSULFANYLMETHYL) 4,5,6,9 TETRAHYDROBENZOFURAN; 9 ACETYL 3 (4 METHOXYPHENYL) 2 (PHENYLSULFANYLMETHYL) 4,5,6,7 TETRAHYDROBENZOFURAN; 9 ACETYL 3 (BENZODIOXOL 5 YL) 2 (PHENYLSULFANYLMETHYL) 4,5,6,9 TETRAHYDROBENZOFURANE; BENZOFURAN DERIVATIVE; FURAN DERIVATIVE; PYRAN DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CYCLIZATION;

ALKYNES; CATALYSIS; CYCLIZATION; FURANS; KETONES; PROPANOLS; PYRANS; SCANDIUM; SELENIUM COMPOUNDS; SULFUR COMPOUNDS;

EID: 77956304897     PISSN: 00092363     EISSN: 13475223     Source Type: Journal    
DOI: 10.1248/cpb.58.1180     Document Type: Article

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