Determination of Fluorine and Chlorine by Pyrohydrolysis and Ion Chromatography: Comparison with Alkaline Fusion Digestion and Ion Chromatography

Geostandards and Geoanalytical Research

Volumn 34, Issue 2, 2010, Pages 175-183

  Wang, Qiaoyun ^a   Makishima, Akio ^a   Nakamura, Eizo ^a  

^a OKAYAMA UNIVERSITY   (Japan)

Author keywords

Alkaline fusion; Chlorine; Fluorine; Ion chromatography; Pyrohydrolysis; Silicate reference materials

Indexed keywords

ALKALINE FUSION; BLANK CORRECTIONS; CL-CONCENTRATIONS; DETECTION LIMITS; DURATION TIME; FUSION METHODS; OXYGEN FLOW; PYROHYDROLYSIS; QUARTZ TUBES; RECOVERY YIELD; REFERENCE MATERIAL; SILICATE MATERIAL; STANDARD SOLUTIONS; ZNO;

CHLORINE; CHROMATOGRAPHY; FLUORINE; IONS; OXYGEN; QUARTZ; SILICATES; SODIUM CHLORIDE; ZINC OXIDE;

ION CHROMATOGRAPHY;

EID: 77956247643     PISSN: 16394488     EISSN: 1751908X     Source Type: Journal    
DOI: 10.1111/j.1751-908X.2010.00043.x     Document Type: Article

References (35)

1. Aiuppa A, Baker DR, Webster JD. Halogens in volcanic systems. Chemical Geology 2009, 263:1-18.
2. Alletti M, Baker DR, Freda C. Halogen diffusion in a basaltic melt. Geochimica et Cosmochimica Acta 2007, 71:3570-3580.
3. Anazawa K, Tomiyasu T, Sakamoto H. Simultaneous determination of fluorine and chlorine in rocks by ion chromatography in combination with alkaline fusion and cation-exchange pretreatment. Analytical Sciences 2001, 17:217-219.
4. Aoki K, Ishiwaka K, Kanisawa S. Fluorine geochemistry of basaltic rocks from continental and oceanic regions and petrogenetic application. Contributions to Mineralogy and Petrology 1981, 76:53-59.
5. Bonifacie M, Jendrzejewski N, Agrinier P, Coleman M, Pineau F, Javoy M. Pyrohydrolysis-IRMS determination of silicate chlorine stable isotope compositions. Application to oceanic crust and meteorite samples. Chemical Geology 2007, 242:187-201.
6. Evans KL, Moore CB. Combustion-ion chromatography determination of chlorine in silicate rocks. Analytical Chemistry 1980, 52:1908-1912.
7. Evans KL, Tarter JG, Moore CB. Pyrohydrolytic-ion chromatography determination of fluoride, chlorine, and sulfur in geological samples. Analytical Chemistry 1981, 53:925-928.
8. Fujitani T, Nakamura N. Determination of chlorine in nine rock reference materials by isotope dilution mass spectrometry. Geostandards and Geoanalytical Research 2006, 30:113-120.
9. Govindaraju K. 1994 compilation of working values and sample description for 383 geostandards. Geostandards Newsletter 1994, 18(Special Issue).
10. Hall GEM, MacLaurin AI, Vaive J. The analysis of geological materials for fluorine, chlorine and sulphur using pyrohydrolysis and ion chromatography. Journal of Geochemical Exploration 1986, 26:177-186.
11. Hauri E, Wang J, Dixon JE, King PL, Mandeville C, Newman S. SIMS analysis of volatiles in silicate glasses. 1. Calibration, matrix effects and comparisons with FTIR. Chemical Geology 2002, 183:99-114.
12. Icenhower JP, London D. Partitioning of fluorine and chlorine between biotite and granitic melt: experimental calibration at 200 MPa H2O. Contributions to Mineralogy and Petrology 1997, 127:17-29.
13. Imai N, Terashima S, Itoh S, Ando A. 1994 compilation of analytical data for minor and trace elements in seventeen GSJ geochemical reference samples, " Igneous Rock Series" Geostandards Newsletter 1995, 19:135-213.
14. Ingram BL. Determination of fluoride in silicate rocks without separation of aluminium using a specific ion electrode. Analytical Chemistry 1970, 42:1825-1827.
15. Itoh M, Watanabe K, Hatakeyama M, Tachibana M. Determination of 36Cl in biological shield concrete using pyrohydrolysis and liquid scintillation counting. The Analyst 2002, 127:964-966.
16. Kanisawa S. Content and behaviour of fluorine in granitic rocks, Kitakami mountains, Northeast Japan. Chemical Geology 1979, 24:57-67.
17. Langenauer M, Krähenbühl U. Determination of fluorine, chlorine, bromine and iodine in seven geochemical reference samples. Geostandards Newsletter 1992, 16:41-44.
18. Loferski PJ, Ayuso RA. Petrography and mineral chemistry of the composite Deboullie pluton, northern Maine, U.S.A.: implications for the genesis of Cu-Mo mineralization. Chemical Geology 1995, 123:89-105.
19. Magenheim AJ, Spivack AJ, Volpe C, Ransom B. Precise determination of stable chlorine isotopic ratios in low-concentration natural samples. Geochimica et Cosmochimica Acta 1994, 58:3117-3121.
20. McDonough WF, Sun SS. The composition of the Earth. Chemical Geology 1995, 120:223-253.
21. Michel A, Villemant B. Determination of halogens (F, Cl, Br, I), sulfur and water in seventeen geological reference materials. Geostandards Newsletter: The Journal of Geostandards and Geoanalysis 2003, 27:163-171.
22. Muramatsu Y, Wedepohl KH. The distribution of iodine in the Earth's crust. Chemical Geology 1998, 147:201-216.
23. Oshima M, Yoshida M. Determination of fluorine and chlorine in GSJ reference samples " igneous rock series" Kazan 2005, 50:243-246. in Japanese with English abstract
24. Portnyagin M, Hoernle K, Plechov P, Mironov N, Khubunaya S. Constraints on mantle melting and composition and nature of slab components in volcanic arcs from volatiles (H2O, S, Cl, F) and trace elements in melt inclusions from the Kamchatka Arc. Earth and Planetary Science Letters 2007, 255:53-69.
25. Rae JE, Malik SA. The determination of iodine in geochemical samples: the use of pyrohydrolytic decomposition. Chemosphere 1996, 33:2121-2128.
26. Rice TD. Determination of fluorine and chlorine in geological materials by induction furnace pyrohydrolysis and standard-addition ion-selective electrode measurement. Analytical Chemistry 1988, 35:173-178.
27. Sano T, Fukuoka T, Hasenaka T. Determination of chlorine contents in Geological Survey of Japan reference materials by prompt gamma neutron activation analysis. Geostandards and Geoanalytical Research 2004, 28:443-448.
28. Schnetger B, Muramatsu Y. Determination of halogens, with special reference to iodine, in geological and biological samples using pyrohydrolysis for preparation and inductively coupled plasma-mass spectrometry and ion chromatography for measurement. The Analyst 1996, 121:1627-1631.
29. Shell HR, Craig RL. Determination of silica and fluoride in fluorsilicates. Analytical Chemistry 1954, 26:996-1001.
30. Shimizu K, Itai T, Kusakabe M. Ion chromatographic determination of fluorine and chlorine in silicate rocks following alkaline fusion. Geostandards and Geoanalytical Research 2006, 30:121-129.
31. Shinonaga T, Ebihara M, Nakahara H, Tomura K, Heumann KG. Cl, Br and I in igneous standard rocks. Chemical Geology 1994, 115:213-225.
32. Villemant B, Boudon G. H2O and halogen (F, Cl, Br) behavior during shallow magma degassing processes. Earth and Planetary Science Letters 1999, 168:271-286.
33. Villemant B, Mouatt J, Michel A. Andesitic magma degassing investigated through H2O vapour-melt partitioning of halogens at Soufriere Hills Volcano, Montserrat (Lesser Antilles). Earth and Planetary Science Letters 2008, 269:212-229.
34. Warf JC, Cline WD, Tevebaugh RD. Pyrohydrolysis in the determination of fluoride and other halides. Analytical Chemistry 1954, 26:342-346.
35. Whitehead D, Thomas JE. Use of a nebulizer in pyrohydrolytic decomposition of silicate materials for determination of fluorine and chlorine. Analytical Chemistry 1985, 57:2421-2423.