Practical methods for the measurement of logP for surfactants

Ecotoxicology and Environmental Safety

Volumn 73, Issue 6, 2010, Pages 1484-1489

  Short, J ^b   Roberts, J ^a   Roberts, D W ^c   Hodges, G ^a   Gutsell, S ^a   Ward, R S ^b  

^a UNILEVER RESEARCH   (United Kingdom)

^b SWANSEA UNIVERSITY   (United Kingdom)

^c LIVERPOOL JOHN MOORES UNIVERSITY   (United Kingdom)

Author keywords

Hydrophobicity; Octanol water partition coefficient; Quantitative structure activity relationships; Sulphobetaines

Indexed keywords

BETAINE DERIVATIVE; OCTANOL; SULPHOBETAINE DERIVATIVE; SURFACTANT; UNCLASSIFIED DRUG; WATER;

HYDROPHOBICITY; LIQUID CHROMATOGRAPHY; PARTITION COEFFICIENT; QUANTITATIVE ANALYSIS; SURFACTANT;

ARTICLE; CHEMICAL STRUCTURE; CONTROLLED STUDY; CRITICAL MICELLE CONCENTRATION; ELECTROSPRAY MASS SPECTROMETRY; HYDROPHOBICITY; MICELLE; PARTITION COEFFICIENT; QUANTITATIVE STRUCTURE ACTIVITY RELATION; REVERSED PHASE HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; ULTRAVIOLET SPECTROSCOPY;

BETAINE; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; HYDROPHOBIC AND HYDROPHILIC INTERACTIONS; MAGNETIC RESONANCE SPECTROSCOPY; QUANTITATIVE STRUCTURE-ACTIVITY RELATIONSHIP; SURFACE-ACTIVE AGENTS;

EID: 77956187295     PISSN: 01476513     EISSN: 10902414     Source Type: Journal    
DOI: 10.1016/j.ecoenv.2010.03.006     Document Type: Article

References (15)

1. Brooke D.N., Dobbs A.J., Williams N. Octanol-water partition coefficients (P)-measurement, estimation and interpretation, particularly for chemicals with P greater than 10(5). Ecotoxicol. Environ. Saf. 1986, 11:251-260.
2. Biobyte Corporation, 1995. ClogP for Windows, Ver 4.0. Claremont, CA, USA.
3. Hansch C., Leo A. Exploring QSAR. Fundamentals and Applications in Chemistry and Biology 1995, American Chemical Society, Washington, DC, USA.
4. Hodges G., Roberts D.W., Marshall S.J., Dearden J.C. The aquatic toxicity of anionic surfactants to daphnia magna-a comparative QSAR study of linear alkylbenzene sulphonates and ester sulphonates. Chemosphere 2006, 63:1443-1450.
5. Hodges G., Roberts D.W., Marshall S.J., Dearden J.C. Defining the toxic mode of action of ester sulphonates using the joint toxicity of mixtures. Chemosphere 2006, 64:17-25.
6. Handbook of Chemistry and Physics 1997-1998, CRC Press, Boca Raton. 78th ed. D.R. Lide (Ed.).
7. Muller M.T., Zehender J.B., Escher B.I. Liposome-water and octanol-water partitioning of alcohol ethoxylates. Environ. Toxicol. Chem. 1999, 18:2191-2198.
8. Organization for Economic Co-operation and Development (OECD), OECD Guidelines for the Testing of Chemicals No. 107: "Partition Coefficient (n-octanol-water): Shake Flask Method", Adopted July 1995.
9. Organization for Economic Co-operation and Development (OECD), OECD Guidelines for the Testing of Chemicals No. 123: "Partition Coefficient (1-octanol/water):Slow Stirring Method", Adopted March 2006.
10. Pauletti G.M., Wunderli-Allenspach H. Partition coefficients in vitro:artificial as a standardised distribution model. Eur. J. Pharm. Sci. 1994, 5:273-282.
11. Roberts D.W., Roberts J.F., Hodges G., Gutsell S., Llewellyn C. Aquatic toxicity of cationic surfactants to daphnia magna. J. Com. Esp. Det. 2009, 153-159.
12. Rosen M.J. Surfactants and Interfacial Phenomena 1989, Wiley, New York. 2nd ed.
13. Tolls, J., 2002. Partition coefficient 1-octanol/water (Pow) slow-stirring method for highly hydrophobic chemicals. Validation Report, RIVM Contract Nos 602730 M602700/01.
14. Ward R.S., Davies J., Hodges G., Roberts D.W. Synthesis of quaternary alkylammonium sulphobetaine. Synthesis 2002, 16:2431-2439.
15. Weers J.G., Rathman J.F., Axe F.U., Crischlow C.A., Foland L.D., Scheuing D.R., Wiersema R.J., Zielske A.G. Effect of the intramolecular charge separation distance on the solution properties of betaines and sulfobetaines. Langmuir 1991, 7:854-867.