Extents of reaction, mass transfer and flow for gas-liquid reaction systems

Industrial and Engineering Chemistry Research

Volumn 49, Issue 17, 2010, Pages 7704-7717

  Bhatt, Nirav ^a   Amrhein, Michael ^a   Bonvin, Dominique ^a  

^a EPFL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINATION OF BUTANOIC ACID; GAS-LIQUID REACTION SYSTEM; LINEAR TRANSFORMATION; MASS TRANSFER RATE; OUTLET FLOWS; REACTOR CONFIGURATION; WITH INLETS;

LINEAR TRANSFORMATIONS; LIQUIDS; MASS TRANSFER;

INLET FLOW;

EID: 77956093076     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie902015t     Document Type: Article

References (38)

1. Croce, A. E. The application of the concept of extent of reaction J. Chem. Educ. 2002, 79, 506
2. Schmitz, G. What is a reaction rate J. Chem. Educ. 2005, 82, 1091
3. Felder, R. M.; Rousseau, R. W. Elementary Principles of Chemical Processes, 3 rd ed.; John Wiley & Sons, Inc.: New York, 2005.
4. Canagaratna, S. The use of extent of reaction in introductory courses J. Chem. Educ. 2000, 77, 52
5. Asbjørnsen, O. A.; Fjeld, M. Response modes of continuous stirred tank reactors Chem. Eng. Sci. 1970, 25, 1627
6. Fjeld, M.; Asbjørnsen, O. A.; Åström, K. J. Reaction invariants and their importance in the analysis of eigenvectors, state observability and controllability of the continuous stirred tank reactor Chem. Eng. Sci. 1974, 29, 1917
7. Asbjørnsen, O. A. Reaction invariants in the control of continuous chemical reactors Chem. Eng. Sci. 1972, 27, 709
8. Srinivasan, B.; Amrhein, M.; Bonvin, D. Reaction and flow variants/invariants in chemical reaction systems with inlet and outlet streams AIChE J. 1998, 44, 1858
9. Amrhein, M.; Bhatt, N.; Srinivasan, B.; Bonvin, D. Extents of reaction and flow for homogeneous reaction systems with inlet and outlet streams. AIChE J. 2010, In press, DOI: 10.1002/aic.12125.
10. Bonvin, D.; Rippin, D. Target factor analysis for the identification of stoichiometric models Chem. Eng. Sci. 1990, 45, 3417
11. Amrhein, M.; Srinivasan, B.; Bonvin, D.; Schumacher, M. M. On the rank deficiency and rank augmentation of the spectral measurement matrix Chemom. Intell. Lab. Syst. 1996, 33, 17
12. Amrhein, M.; Srinivasan, B.; Bonvin, D.; Schumacher, M. M. Calibration of spectral reaction data Chemom. Intell. Lab. Syst. 1999, 46, 249
13. Bardow, A.; Marquardt, W. Incremental and simultaneous identification of reaction kinetics: Methods and comparison Chem. Eng. Sci. 2004, 59, 2673
14. Brendel, M.; Bonvin, D.; Marquardt, W. Incremental identification of kinetic models for homogeneous reaction systems Chem. Eng. Sci. 2006, 61, 5404
15. Vora, N.; Daoutidis, P. Nonlinear model reduction of chemical reaction systems AIChE J. 2001, 47, 2320
16. Gerdtzen, Z. P.; Daoutidis, P.; Hu, W. Nonlinear reduction for kinetic models of metabolic reaction networks Metab. Eng. 2004, 6, 140
17. Glasser, D.; Hildebrandt, D.; Crowe, C. A Geometric approach to steady flow reactors: the attainable region and optimization in concentration space Ind. Eng. Chem. Res. 1987, 26, 1803
18. Glasser, D.; Hildebrandt, D. Reactor and process synthesis Comput. Chem. Eng. 1997, 21, S775
19. Feinberg, M. Recent results in optimal reactor synthesis via attainable region theory Chem. Eng. Sci. 1999, 54, 2535
20. Omtveit, T.; Tanskanen, J.; Lien, K. M. Graphical targeting procedures for reactor systems Comput. Chem. Eng. 1994, 18, S113
21. Groggins, P. H. Unit Processes in Organic Synthesis, 5 th ed.; McGraw-Hill: New York, 1958.
22. van Elk, E. P.; Borman, P.; Kuipers, J.; Versteeg, G. Modelling of gas-liquid reactors - Implementation of the penetration model in dynamic modelling of gas-liquid processes with the presence of a liquid bulk Chem. Eng. J. 2000, 76, 223
23. van Elk, E. P.; Borman, P.; Kuipers, J.; Versteeg, G. Modelling of gas-liquid reactors - Stability and dynamic behaviour of gas-liquid mass transfer accompanied by irreversible reaction Chem. Eng. Sci. 1999, 54, 4869
24. Vas Bhat, R.; van Swaaij, W.; Kuipers, J.; Versteeg, G. Mass transfer with complex chemical reaction in gas-liquid systems - I. Consecutive reversible reactions with equal diffusivities Chem. Eng. Sci. 1999, 54, 121
25. van Swaaij, W.; Versteeg, G. Mass transfer accompanied with complex reversible chemical reactions in gas-liquid systems: An overview Chem. Eng. Sci. 1992, 47, 3181
26. Romanainen, J. J.; Salmi, T. Numerical strategies in solving gas-liquid reactor models - 1. Stagnant films and a steady state CSTR Comput. Chem. Eng. 1991, 15, 769
27. Romanainen, J. J.; Salmi, T. Numerical strategies in solving gas-liquid reactor models - 2. Transient films and dynamic tank reactors Comput. Chem. Eng. 1991, 15, 783
28. Ho, S.; Lee, S. An analysis of complex gas-liquid reactions in an isothermal CSTR Chem. Eng. Sci. 1980, 35, 1139
29. Michalik, C.; Brendel, M.; Marquardt, W. Incremental identification of fluid multi-phase reaction systems AIChE J. 2009, 55, 1009
30. Sherwood, T. K.; Pigford, R. L.; Wilke, C. R. Mass Transfer; McGraw-Hill Kogakushu, Ltd: New York, 1975.
31. Taylor, R.; Krishna, R. Multicomponent Mass Transfer, 1 st ed.; John Wiley & Sons: New York, 1993.
32. Cussler, E. Diffusion: Mass Transfer in Fluid Systems, 3 rd ed.; Cambridge University Press: New York, 2007.
33. Amrhein, M.; Srinivasan, B.; Bonvin, D. Target factor analysis of reaction data: Use of data pre-treatment and reaction-invariant relationships Chem. Eng. Sci. 1999, 54, 579
34. Vogel, C. Computational Methods for Inverse Problems; Society for Industrial and Applied Mathematics: Philadelphia, 2002.
35. Zhang, J.; Smith, R. Design and optimization of batch and semi-batch reactors Chem. Eng. Sci. 2004, 59, 459
36. Romanainen, J. J.; Salmi, T. The effect of reaction kinetics, mass transfer and flow pattern on non-catalytic and homogeneously catalyzed gas-liquid reactions in bubble columns Chem. Eng. Sci. 1992, 47, 2493
37. Wu, H. Phase-plane modeling of a liquid-liquid phase transfer catalyzed reaction Ind. Eng. Chem. Res. 1993, 32, 1323
38. Korchinsky, W. J.; Azimzdeh-khatayloo, S. An improved stagewise model of countercurrent flow liquid-liquid contactors Chem. Eng. Sci. 1976, 31, 871