Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water

Journal of the American Chemical Society

Volumn 132, Issue 34, 2010, Pages 11866-11867

  Fukuzumi, Shunichi ^a,b   Kobayashi, Takeshi ^a,b   Suenobu, Tomoyoshi ^a,b  

^a OSAKA UNIVERSITY   (Japan)

^b Ewha Womans University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

AMBIENT TEMPERATURES; BIPYRIDINES; CYCLOPENTADIENYLS; FOUR-ELECTRON REDUCTION; OXYGEN SCAVENGERS; RUTHENIUM COMPLEXES;

FORMIC ACID; IRIDIUM; IRIDIUM COMPOUNDS; ORGANIC ACIDS; OXYGEN; RUTHENIUM; SCAVENGING;

RUTHENIUM COMPOUNDS;

FORMIC ACID; IRIDIUM COMPLEX; OXYGEN; RUTHENIUM COMPLEX; SCAVENGER; WATER;

ABSORPTION SPECTROSCOPY; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTRON; REDUCTION; TEMPERATURE; ULTRAVIOLET SPECTROSCOPY;

CATALYSIS; ELECTRONS; FORMIC ACIDS; FREE RADICAL SCAVENGERS; IRIDIUM; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; OXYGEN; RUTHENIUM; STEREOISOMERISM; TEMPERATURE; WATER;

EID: 77956092016     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja104486h     Document Type: Article

References (13)

1. Cohen, P. The ASME Handbook on Water Technology for Thermal Power Systems; The American Society of Mechanical Engineers: New York, 1989; p 1291.
2. Gross, M. S., Pisarello, M. L., Pierpauli, K. A., and Querini, C. A. Ind. Eng. Chem. Res. 2010, 49, 81
3. Moon, J.-S., Park, K.-K., Kim, J.-H., and Seo, G. Appl. Catal., A 2000, 201, 81
4. Van der Vaart, R., Hafkamp, B., Koele, P. J., Querreveld, M., Jansen, A. E., Volkov, V. V., Lebedeva, V. I., and Gryaznov, V. M. Ultrapure Water 2001, 18, 27
5. Van der Vaart, R., Lebedeva, V. I., Petrova, I. V., Plyasova, L. M., Rudina, N. A., Kochubey, D. I., Tereshchenko, G. F., Volkov, V. V., and van Erkel, J. J. Membr. Sci. 2007, 299, 38
6. 2 with 1 has been reported: Fukuzumi, S., Kobayashi, T., and Suenobu, T. J. Am. Chem. Soc. 2010, 132, 1496
7. Vaska, L. Science 1963, 140, 809
8. Vaska, L. Acc. Chem. Res. 1976, 9, 175
9. Suardi, G., Cleary, B. P., Duckett, S. B., Sleigh, C., Rau, M., Reed, E. W., Lohman, J. A. B., and Eisenberg, R. J. Am. Chem. Soc. 1997, 119, 7716
10. Williams, D. B., Kaminsky, W., Mayer, J. M., and Goldberg, K. I. Chem. Commun. 2008, 4195
11. Hay-Motherwell, R. S., Wilkinson, G., Hussain-Bates, B., and Hursthouse, M. B. Polyhedron 1993, 12, 2009
12. Jacobi, B. G., Laitar, D. S., Pu, L., Wargocki, M. F., DiPasquale, A. G., Fortner, K. C., Schuck, S. M., and Brown, S. N. Inorg. Chem. 2002, 41, 4815
13. The more definitive assignment of the intermediates is now in progress.