Desorption of metal ions from kraft pulps. Part 1. Chelation of hardwood and softwood kraft pulp with EDTA

BioResources

Volumn 5, Issue 1, 2010, Pages 206-226

  Granholm, Kim ^a   Harju, Leo ^a   Ivaska, Ari ^a  

^a ÅBO AKADEMI UNIVERSITY   (Finland)

Author keywords

Chelation; Desorption; EDTA; Hardwood kraft pulp; Metal ions; Side reaction coefficients; Softwood kraft pulp

Indexed keywords

BLEACHED HARDWOODS; BLEACHED SOFTWOOD PULPS; CONCENTRATION RATIO; EDTA; HARDWOOD KRAFT PULP; HYDROGEN IONS; METAL ION CONCENTRATION; PH RANGE; PH VALUE; SIDE REACTIONS; SOFTWOOD KRAFT PULP; SOFTWOOD KRAFT PULPS;

BLEACHING; CADMIUM; CADMIUM COMPOUNDS; CHELATION; CLEANING; DESORPTION; HARDWOODS; INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY; ION EXCHANGE; KRAFT PROCESS; MAGNESIUM; MANGANESE; MANGANESE COMPOUNDS; METAL ANALYSIS; METAL IONS; METALS; OXYGEN; PH EFFECTS; SOFTWOODS; ZINC;

KRAFT PULP;

BLEACHING; CADMIUM; CHELATION; CLEANING; DESORPTION; HARDWOODS; IONS; KRAFT PULPS; MAGNESIUM; METALS; OXYGEN; PH; SOFTWOODS; ZINC;

EID: 77956085310     PISSN: None     EISSN: 19302126     Source Type: Journal    
DOI: None     Document Type: Article

References (49)

1. Ali, T., McArthur, D., Fairbank, M., and Whiting, P. (1986). "The role of silicate in peroxide brightening of mechanical pulp. 1. The effects of alkalinity, pH, pre-treatment with chelating agent and consistency," J. Pulp Pap. Sci. 12(6), J166-J171.
2. Ant-Wuorinen, O., and Visapää, A. (1965). "The retention of iron by cellulose," Papper och Trä 9, 477-487.
3. th Int. Symp. Wood Pulp. Chem., Appita Vol. 1, Melbourne, 237-244.
4. Basta, J., Holtinger, L., Hermansson, W., Lundgren, P. (1994). "Metal management in TCF/ECF bleaching," Proc. Int. Pulp Bleaching Conf., Paper Presentations, Vancouver, Canada, 29-32.
5. Bouchard, J., Nugent, H.M., and Berry, R.M. (1995). "A comparison between acid treatment and chelation prior to hydrogen peroxide bleaching of kraft pulps," J. Pulp Pap. Sci. 21(6), J203-J208.
6. Brelid, H., Friberg, T., and Simonson, R. (1996). "TCF bleaching of softwood kraft pulp. Part 2. Reducing the need for chelating agent in hydroxide peroxide bleaching of softwood kraft pulp," Nord. Pulp Paper Res. J. 11(2), 105-108.
7. Bryant, P. S., and Edwards, L. L. (1994). "Manganese removal in closed kraft mill bleached plants, "Tappi J. 77(2), 137-148.
8. Bryant, P. S., and Edwards, L.L. (1996). "Cation exchange of metals on kraft pulp," J. Pulp Pap. Sci. 22(1), J37-J42.
9. Buchert, J., Teleman, A., Harjunpää, V., Tenkanen, M., Viikari, L., and Vuorinen, T. (1995). "Effect of cooking and bleaching on the structure of xylan in conventional pine kraft pulp," Tappi J. 78(11), 125-130.
10. Cardona-Barrau, D., Lachenal, D., and Chirat, C. (2001). "Affinity of metal ions for kraft pulps studied by ESR. Inhibition of their catalytic action in oxygen bleaching," J. Wood Chem. Tech. 21(3), 247-261.
11. Carrot, P. J. M, and Carrot, M. M. L. (2007). "Lignin - from natural adsorbent to activated carbon: A review," Bioreces. Technol. 98(15), 2301-2312.
12. Colodette, J. L., Rothenberg, S., and Dence, C. W. (1998). "Factors affecting hydrogen peroxide stability in the brightening of mechanical and chemimechanical pulps. Part 1: Hydrogen peroxide stability in the absence of stabilizing systems," J. Pulp Pap. Sci. 14(6), J126-J.132.
13. Devenyns, J., Desprez, F., Troughton, N., and Plumet, L. (1994). "Metals control in TCF bleaching. Implications for kraft bleaching sequence design," Proceedings of TAPPI Pulping Conference, TAPPI Press, Atlanta, pp. 381-385.
14. th Int. Symp. Wood Pulp. Chem., Montreal, M5-1-M5-4.
15. + ions on unbleached kraft fibres - A kinetics and equilibrium study." J. Colloid Interface. Sci. 301(2), 446-451.
16. Forsskåhl, I. (2000). "Papermaking Science and Technology," Book 3, Forest Products Chemistry, Edited by Stenius, P., Fapet Oy, 279-332.
17. Gilbert, A. F., Pavlovova, E., and Rapson, W. H. (1970). "Mechanism of magnesium retardation of cellulose degradation during oxygen bleaching," Tappi 56(6), 95-99.
18. Granholm, K., Su, P., Harju, L., and Ivaska, A. (2009). "Study on desorption of Mn, Fe and Mg from TMP and evaluation of the complexing strength of different chelation agents using side reaction coefficients," Holzforschung 63(6), 785-790.
19. Gupta, V. N. (1970). "Effect of metal ions on brightness, bleachability and colour reversion of groundwood," Pulp Pap. Can. 71(16), 69-77.
20. Hyvönen, H., Orama, M., Arvelac, R., Henriksson, K., Saarinen, H., Aksela, R., Parene, A., Jäkärä., and Renvall, I. (2006). "Studies on three new environmentally friendly chelating ligands," Appita J. 59(2), 142-149.
21. Kangas, H., Robersten, L., and Vuorinen, T. (2002) "The effect of transition metal ions on the kraft pulping process," Paperi ja Puu. 84(7), 473-477.
22. Karhu, J., Snickars, P., Harju, L., and Ivaska, A. (2002a). "Two-phase equilibria of metal ions in pulping process from impregnation to oxygen delignification. Part I. Metal ion concentrations," Paperi ja Puu 84(8), 519-525.
23. Karhu, J., Snickars, P., Harju, L., and Ivaska, A. (2002b). "Two-phase equilibria of metal ions in pulping process from impregnation to oxygen delignification. Part II. Metal ion balances," Paperi ja Puu 85(1), 37-42.
24. Karhu, J., Snickars, P., Harju, L, and Ivaska, A. (2002C). "Cation exchange of alkali and alkaline earth metal ions on hardwood kraft pulp," Appita J. 55(5), 392-397.
25. Kujala, M., Sillanpää, M., and Rämö, J. (2004). "A method to leach manganese and some other metla cations from pulp matrix to aqueous phase for the subsequent ICP-AES analysis: A potential tool for controlling the metal profile in a pulp bleaching process," J. Clean. Prod. 12(7), 707-712.
26. 2 in kraft pulp delignification," Paperi ja Puu 79(4), 252-256.
27. Lapierre, L., Bouchard, J., Berry, R. M., and Van Lierop, B. (1995). "Chelation prior to hydrogen peroxide bleaching of kraft pulps: An overview," J. Pulp Pap. Sci. 21(8), J268-J273.
28. Lapierre, L., Paleologou, M., Berry, R. M., and Bouchard, J. (1997). "The limits of metal removal from kraft pulp by acid treatment." J. Pulp Pap. Sci. 23(11), J539-J542.
29. Lapierre, L., Berry, R., and Bouchard, J. (2000). "The effects of the order of chemical addition on the peroxide bleaching of an oxygen-delignified softwood kraft pulp." Holzforschung 54(3), 279-286.
30. Lapierre, L., Berry, R., and Bouchard, J. (2003). "The effect of magnesium ions and chelants on peroxide bleaching." Holzforschung 57(6), 627-633.
31. 2 decomposition under bleaching conditions," J. Pulp Pap. Sci. 24(9), 269-276.
32. Lundqvist, F., Brelid, H., Saltberg, A., Gellerstedt, G., and Tomani, P. (2006). "Removal of non-process elements from hardwood chips prior to kraft cooking," Appita J. 59(6), 493-499.
33. Moreira, E., Colodette, J., Gomide J., Oliviera, R., Regazzi, A., and Sacon, V. (2008). "Effect of acid leaching of eucalyptus wood on kraft pulping and pulp bleachibility," J. Wood Chem. Tech. 28(2), 137-152.
34. Norkus, E., Vaičiūnienė, J., Vuorinen, T., and Macalady, D.L. (2004). "Equilibria of Cu(II) in alkaline suspensions od cellulose pulp," Carbohydr. Polym. 55(1), 47-55.
35. Norkus, E., Vaičiūnienė, J., and Vuorinen, T. (2006). "Removal of transition metals from alkaline suspensions of pulp using CDTA as a chelating agent," Carbohydr. Polym. 66(3), 316-320.
36. Perat, C., Ni, Y. (2001). "UV-VIS Spectra of lignin model compounds in the presence of metal ions and chelants," J. Wood Chem. Tech. 21(2), 113-125.
37. Ringbom, A. (1963). Complexation in Analytical Chemistry, Wiley, New York.
38. Saltberg, A., Brelid, H., and Theliander, H. (2006). "Removal of metal ions from wood chips during acidic leaching. 1: Comparison between Scandinavian softwood, birch and eucalyptus," Nord. Pulp Paper Res. J. 21(4), 507-512.
39. Sjöström, E. (1989). "The origin of charge on cellulosic fibers," Nord. Pulp Paper Res. J. 4(2), 90-93.
40. Smith, R. M., and Martell, A. E. (1989). Critical stability constants. Volume 6: Second supplement, Plenium Press, New York.
41. Su, P. (2004). The determination of acid groups in pulp samples by potentiometrictitration and the analysis of metal ions in single fibres by laser ablation coupled plasma mass spectrometry, Master of Science Thesis, Faculty of Technology, Åbo Akademi University, Finland, Turku.
42. nd International Papermaking & Environment Conf., Tianjin, China, Book A. 242-245.
43. Su, P., Granholm, K., Harju, L., and Ivaska, A. (2009). "Study of metal ion binding to unbleached softwood kraft pulp by column chromatography," Appita J. Accepted for publication.
44. Sundén, A., Brelid, H., Rindby, A., and Engström, P. (2000). "Spatial distribution and modes of chemical attachment of metal ions in spruce wood," J. Pulp Pap. Sci 22(1), J37-J42.
45. Södö, M., Su, P., Granholm, K., Harju, L., and Ivaska, I. (2007). "Study on metal ion affinities to oxygen delignified hardwood kraft pulp by a column chromatographic method," Nord. Pulp Paper Res. J. 22(4), 462-467.
46. 13C NMR spectroscopy," Carbohydrate Research 272(1), 55-71.
47. th European Workshop on Lignocellulosics and Pulp, Stockholm, Sweden, Proceedings, p. 336.
48. Tokareva, E. N., Pranovich, A. V., Ek, P., and Holmbom, B. (2009). "Determination of anionic groups in wood by time-of-flight secondary ion mass spectrometry and laser ablation-inductively coupled plasma-mass spectrometry," Holzforschung 63. In Press.
49. Yuan, M., dEntremont, M. D., Ni, Y., and van Heiningen, A. R. P. (1997). "The role of transition metal ions during peracetic acid bleaching of chemical pulps," Pulp Paper Canada 98(11), T408-T413.