Thermodynamics of cesium extraction from acidic media by HCCD and PEG

Solvent Extraction and Ion Exchange

Volumn 28, Issue 5, 2010, Pages 563-578

  Herbst, R Scott ^a   Peterman, Dean R ^a   Zalupski, Peter R ^a,b   Nash, Ken L ^b   Tillotson, Richard D ^a   Delmau, Lætitia H ^c  

^a IDAHO NATIONAL LABORATORY   (United States)

^b WASHINGTON STATE UNIVERSITY   (United States)

^c OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

Cesium; FS 13; HCCD; PEG; Solvent extraction; SXLSQI mode

Indexed keywords

ACIDIC MEDIA; CATION EXCHANGES; CESIUM EXTRACTION; CHLORINATED COBALT DICARBOLLIDE; FS-13; HCCD; NONIDEAL; PEG; PHASE TRANSFER; SOLUTE SPECIES; SXLSQI MODE; SYNERGISTIC EXTRACTION; TRIFLUOROMETHYL; VAN'T HOFF ANALYSIS;

CESIUM; COBALT; SOLVENTS;

SOLVENT EXTRACTION;

EID: 77956069965     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366299.2010.502865     Document Type: Article

References (11)

1. Rais, J. Principles of Extraction of Electrolytes, in Ion Exchange and Solvent Extraction, Vol. 17, Marcus, Y. and SenGupta, A.K., Eds. Marcel Dekker: New York, 2004, 335-385.
2. Rais, J. and Gruner, B. Extraction with Metal Bis(dicarbollide) Anions, In Ion Exchange and Solvent Extraction, Vol. 17; Marcus, Y. and SenGupta, A. K., Eds. Marcel Dekker: New York, 2004, pp. 243-334.
3. Herbst, R.S.; Peterman, D.R.; Tillotson, R.D; Delmau, L.H. Fundamental chemistry of cesium extraction from acidic media by HCCD in FS-13. Solvent Extr. Ion Exch. 2008, 26(2), 163-174.
4. Baes, C.F. Jr. SXLSQI: A Program for Modeling Solvent Extraction Systems, Oak Ridge National Laboratory Report ORNL/TM-13604, Oak Ridge National Laboratory, Oak Ridge, TN, December 1998.
5. Baes, C.F. Jr.;McDowell,W.J.; Bryan, S.A. The interpretation of equilibrium data from synergistic solvent extraction systems. Solvent Extr. Ion Exch. 1987, 5, 1-28.
6. Baes, C.F. Jr.;Moyer, B.A.; Case, G.N.; Case, F.I. SXLSQA: A computer program for including both complex formation and activity effects in the interpretation of solvent extraction data. Sep. Sci. Technol. 1990, 25(13-15), 1675-1688.
7. Herbst, R. S., unpublished data.
8. Zalupski, P.R.; Herbst, R.S.; Delmau, L.H.;Martin, L.R.; Peterman, D.R.; Nash, K.L. Two-phase calorimetry. II. Studies on the thermodynamics of cesium and strontium extraction by mixtures of H+CCD- and PEG-400 in FS-13. Solvent Extr. Ion. Exch. 2010, 28, 161-183.
9. Zalupski, P.R.; Nash, K.L. Two-phase calorimetry. I. Studies on the thermodynamics of lanthanide extraction by bis(2-ethylhexyl) phosphoric acid. Solvent Extr. Ion Exch. 2008, 26, 510-529.
10. Zalupski, P.R.; Nash, K.L. Calorimetric Investigations of Metal Extaction for 2-Phase Systems, Proc. of the International Solvent Extraction Conference, ISEC 2008, Vol. 2, 1111-1118, Moyer, B.A., Ed., Met Soc, Québec, 2008.
11. Herbst, R.S.; Peterman, D.R.; Robinson, T.A. PEG-400 partitioning in the HCCD/PEG process for Cs and Sr recovery. Sep. Sci Technol. 2008, 43(9), 2557-2571.