Kinetics of enzymatic trans-esterification of glycerides for biodiesel production

Bioprocess and Biosystems Engineering

Volumn 33, Issue 6, 2010, Pages 701-710

  Calabrò, Vincenza ^a   Ricca, Emanuele ^a   De Paola, Maria Gabriela ^a   Curcio, Stefano ^a   Iorio, Gabriele ^a  

^a UNIVERSITY OF CALABRIA   (Italy)

Author keywords

Biodiesel; Enzyme; Kinetics; Lipase; Oil trans esterification

Indexed keywords

BIODIESEL PRODUCTION; DESIGN AND OPTIMIZATION; IONIC EXCHANGE; KINETIC ANALYSIS; KINETIC MODELS; MASS-TRANSPORT RESISTANCE; RATE EQUATIONS; REACTION MEDIUM; REACTION PATHS; SPECIFIC SURFACE;

BIODIESEL; ENZYMES; ESTERIFICATION; ETHANOL; HEXANE; ION EXCHANGE; RESINS;

ESTERS;

ACYLGLYCEROL; ALCOHOL; BIODIESEL; HEXANE; RESIN; TRIACYLGLYCEROL LIPASE; BIOFUEL; IMMOBILIZED ENZYME; N-HEXANE;

ARTICLE; BIOCATALYSIS; BIOFUEL PRODUCTION; CHEMICAL REACTION KINETICS; CONCENTRATION RESPONSE; CONTROLLED STUDY; CULTURE MEDIUM; ENZYME IMMOBILIZATION; ION EXCHANGE; NONHUMAN; PRIORITY JOURNAL; REACTION ANALYSIS; REACTOR DESIGN; REACTOR OPTIMIZATION; TEMPERATURE; TRANSESTERIFICATION; CHEMICAL MODEL; ENZYMOLOGY; ESTERIFICATION; KINETICS; METABOLISM; MUCOR; RHIZOMUCOR;

BIOFUELS; ENZYMES, IMMOBILIZED; ESTERIFICATION; ETHANOL; GLYCERIDES; HEXANES; KINETICS; LIPASE; MODELS, CHEMICAL; MUCOR; RHIZOMUCOR;

RHIZOMUCOR MIEHEI;

EID: 77956064099     PISSN: 16157591     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00449-009-0392-z     Document Type: Article

References (32)

1. F Billaud V Dominguez P Broutin C Buston 1995 Production of hydrocarbons by pyrolysis of methyl esters from rapeseed oil J Am Oil Chem Soc 72 1149 1154 10.1007/BF02540981 1:CAS:528:DyaK2MXos1Sitrg%3D
2. M Ziejewski KR Kaufman AW Schwab EH Pryde 1984 Diesel engine evaluation of a nonionic sunflower oil-aqueous ethanol microemulsion J Am Oil Chem Soc 61 1620 1626 10.1007/BF02541646 1:CAS:528:DyaL2cXmtFeqsbs%3D
3. H Fukuda A Kondo H Noda 2001 Biodiesel fuel production by trans-esterification of oils J Biosci Bioeng 92 405 416 10.1263/jbb.92.405 1:CAS:528:DC%2BD38XnvVWitw%3D%3D
4. F Ma MA Hanna 1999 Biodiesel production: a review Bioresource Technol 70 1 15 10.1016/S0960-8524(99)00025-5 1:CAS:528:DyaK1MXjtlGhtb8%3D (Pubitemid 29225069)
5. AW Schwab MO Bagby B Freedman 1987 Preparation and properties of diesel fuels from vegetable oils Fuel 66 1372 1378 10.1016/0016-2361(87)90184-0 1:CAS:528:DyaL2sXmt1SntL0%3D
6. SJ Clark L Wangner MD Schrock PG Piennaar 1984 Methyl and ethyl soybean esters as renewable fuels for diesels engines J Am Oil Chem Soc 61 1632 1638 10.1007/BF02541648 1:CAS:528:DyaL2cXlvFGit7g%3D
7. B Freedman EH Pryde TL Mounts 1984 Variables affecting the yields of fatty esters from trans-esterified vegetable oils J Am Oil Chem Soc 61 1638 1643 10.1007/BF02541649 1:CAS:528:DyaL2MXmtV2rtQ%3D%3D
8. A Srivastava R Prasad 2000 Triglycerides-based diesel fuels Renew Sus Energ Rev 4 111 133 10.1016/S1364-0321(99)00013-1 1:CAS:528:DC%2BD3cXisVCks7o%3D (Pubitemid 30572437)
9. MW Formo 1954 Ester reactions of fatty materials J Am Oil Chem Soc 31 548 559 10.1007/BF02638571 1:CAS:528:DyaG2MXmsFGr
10. HJ Wright JB Segur HV Clark SK Coburn EE Langdon RN DuPuis 1944 A report on ester interchange Oil Soap 21 145 148 10.1007/BF02549470 1:CAS:528: DyaH2cXis1CqsQ%3D%3D
11. EW Eckey 1956 Esterification and interesterification J Am Oil Chem Soc 33 575 579 10.1007/BF02638493
12. B Freedman RO Butterfield EH Pryde 1986 Transesterification kinetics of soybean oil J Am Oil Chem Soc 63 1375 1380 10.1007/BF02679606 1:CAS:528:DyaL28Xmt1yrtbw%3D
13. M Mittelbach 1990 Lipase catalyzed alcoholysis of sunflower oil J Am Oil Chem Soc 67 168 170 10.1007/BF02539619 1:CAS:528:DyaK3cXitlCitL0%3D
14. R Abigor P Uadia T Foglia M Haas K Jones E Okpefa J Obibuzor M Bafor 2000 Lipase-catalyzed production of biodiesel fuel from some Nigerian lauric oils Biochem Soc Trans 28 979 981 10.1042/BST0280979 1:CAS:528:DC%2BD3MXhsVKjsrc%3D
15. Y Shimada A Sugihara H Nakano T Kuramoto T Nagao M Gemba Y Tominaga 1997 Purification of docosahexanoic acid by selective esterification of fatty acids from tuna oil with Rhizopus delemar lipase J Am Oil Chem Soc 74 97 101 10.1007/s11746-997-0151-8 1:CAS:528:DyaK2sXhsVemsrc%3D
16. LA Nelson A Foglia WN Marmer 1996 Lipase-catalyzed production of biodiesel J Am Oil Chem Soc 73 1191 1195 10.1007/BF02523383 1:CAS:528: DyaK28XlslGisr4%3D
17. Y Shimada Y Watanabe T Samukawa A Sugihara H Noda H Fukuda Y Tominaga 2000 Conversion of vegetable oil to biodiesel using immobilized Candida antarctica lipase J Am Oil Chem Soc 77 355 360 10.1007/s11746-000-0058-9
18. Y Shimada Y Watanabe A Sugihara Y Tominaga 2002 Enzymatic alcoholysis for biodiesel fuel production and application of reaction to oil processing J Mol Catal B Enz 17 133 142 10.1016/S1381-1177(02)00020-6 1:CAS:528: DC%2BD38XktVGjt7w%3D (Pubitemid 34556779)
19. T Samukawa M Kaieda T Matsumoto K Ban A Kondo Y Shimada H Noda H Fukuda 2000 Pretreatment of immobilized Candida antarctica lipase for biodiesel fuel production from plant oil Biosci Bioeng 90 180 183 1:CAS:528: DC%2BD3cXntlyjtb0%3D
20. M Kaieda T Samukawa A Kondo H Fukuda 2001 Effect of methanol and water contents on production of biodiesel fuel from plant oil catalyzed by various lipases in a solvent-free system J Biosci Bioeng 91 12 15 10.1263/jbb.91.12 1:CAS:528:DC%2BD3MXhvFSmtrk%3D
21. M Kaieda T Samukawa T Matsumoto K Ban A Kondo Y Shimada H Noda F Nomoto K Ohtsuka E Izumoto H Fukuda 1999 Biodiesel fuel production from plant oil catalyzed by Rhizopus oryzae lipase in a water-containing system without an organic solvent J Biosci Bioeng 88 627 631 10.1016/S1389-1723(00)87091-7 1:CAS:528:DC%2BD3cXhslyhuw%3D%3D (Pubitemid 30046431)
22. V Dossat D Combes A Marty 2002 Lipase-catalysed transesterification of high oleic sunflower oil Enzyme Microb Technol 30 90 94 10.1016/S0141-0229(01) 00453-7 1:CAS:528:DC%2BD38Xit1Kq (Pubitemid 34072935)
23. S Al-Zuhair 2005 Production of biodiesel by lipase-catalyzed transesterification of vegetable oils: a kinetic study Biotechnol Prog 21 1442 1448 10.1021/bp050195k 1:CAS:528:DC%2BD2MXpsFaktbg%3D (Pubitemid 41443000)
24. S Al-Zuhair FW Ling LS Jun 2007 Proposed kinetic mechanism of the production of biodiesel from palm oil using lipase Process Biochem 42 951 960 10.1016/j.procbio.2007.03.002 1:CAS:528:DC%2BD2sXlt1aku7o%3D (Pubitemid 46711255)
25. S Al-Zuhair A Dowaidar H Kamal 2009 Dynamic modeling of biodiesel production from simulated waste cooking oil using immobilized lipase Biochem Eng J 44 256 262 10.1016/j.bej.2009.01.003 1:CAS:528:DC%2BD1MXisl2quro%3D
26. GT Jeong DH Park 2008 Lipase-catalyzed transesterification of rapeseed oil for biodiesel production with tert-butanol Appl Biochem Biotechnol 148 131 139 10.1007/s12010-007-8050-x 1:CAS:528:DC%2BD1MXnsFGrsQ%3D%3D
27. MM Soumanou UT Bornscheuer 2003 Improvement in lipase-catalyzed synthesis of fatty acid methyl esters from sunflower oil Enz Microb Technol 33 97 103 10.1016/S0141-0229(03)00090-5 1:CAS:528:DC%2BD3sXkvVKju7g%3D (Pubitemid 36725059)
28. W Du Y Xu 2005 Study on acyl migration in immobilized Lipozyme TL catalyzed transesterification of soybean oil for biodiesel production J Mol Cat B 37 68 71 10.1016/j.molcatb.2005.09.008 1:CAS:528:DC%2BD2MXht1GnurrO (Pubitemid 41674650)
29. Levenspiel O (1999) Chemical reaction engineering, 3rd edn. Wiley, New York, p 63
30. B Cheirsilp A H-Kittikun S Limkatanyu 2008 Impact of transesterification mechanisms on the kinetic modeling of biodiesel production by immobilized lipase Biochem Eng J 42 261 269 10.1016/j.bej.2008.07.006 1:CAS:528:DC%2BD1cXhtFektrvI
31. Bird RB, Stewart WE, Lightfoot EN (1960) Transport phenomena. Wiley, New York
32. Berben PH, Groen C, Christensen MW, Holm HC (2001) Interesterification with immobilized enzymes. SCI Lecture Paper Series, p 121